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Synthesis of Pt and Pt-Fe nanoparticles supported on MWCNTs used as electrocatalysts in the methanol oxidation reaction 被引量:1
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作者 j.r.rodriguez R.M.Félix +4 位作者 E.A.Reynoso Y.Gochi-Ponce Y.Verde Gómez S.Fuentes Moyado G.Alonso-Núez 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2014年第4期483-490,共8页
This work reports a feasible synthesis of highly-dispersed Pt and Pt-Fe nanoparticles supported on multiwall carbon nanotubes (MWCNTs) without Fe and multiwall carbon nanotubes with iron (MWCNTs-Fe) which applied ... This work reports a feasible synthesis of highly-dispersed Pt and Pt-Fe nanoparticles supported on multiwall carbon nanotubes (MWCNTs) without Fe and multiwall carbon nanotubes with iron (MWCNTs-Fe) which applied as electrocatalysts for methanol electrooxidation. A Pt coordination complex salt was synthesized in an aqueous solution and it was used as precursor to prepare Pt/MWCNTs, Pt/MWCNTs-Fe, and Pt-Fe/MWCNTs using FeC12.4H20 as iron source which were named S 1, S2 and S3, respectively. The coordination complex of platinum (TOA)2PtC16 was obtained by the chemical reaction between (NH4)2PtC16 with tetraoctylammonium bromide (TOAB) and it was characterized by FT-IR and TGA. The materials were characterized by Raman spectroscopy, SEM, EDS, XRD, TEM and TGA. The electrocatalytic activity of Pt-based supported on MWCNTs in the methanol oxidation was investigated by cyclic voltammetry (CV) and chronoamperometry (CA). Pt-Fe/MWCNTs electrocatalysts showed the highest electrocatalytic activity and stability among the tested electrocatalysts due to that the addition of "Fe" promotes the OH species adsorption on the electrocatalyst surface at low potentials, thus, enhancing the activity toward the methanol oxidation reaction (MOR). 展开更多
关键词 coordination complex salt MWCNTS nanoparticles CATALYSTS ELECTROOXIDATION
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