This paper uses a nonperturbative scattering theory to study photoelectron angular distributions of homonuclear diatomic molecules irradiated by circularly polarized laser fields. This study shows that the nonisotropi...This paper uses a nonperturbative scattering theory to study photoelectron angular distributions of homonuclear diatomic molecules irradiated by circularly polarized laser fields. This study shows that the nonisotropic feature of photoelectron angular distributions is not due to the polarization of the laser field but the internuclear vector of the molecules. It suggests a method to measure the molecular orientation and the internuclear distance of molecules through the measurement of photoelectron angular distributions.展开更多
This paper presents a comprehensive review of modeling of alkali-silica reaction(ASR)in concrete.Such modeling is essential for investigating the chemical expansion mechanism and the subsequent influence on the mechan...This paper presents a comprehensive review of modeling of alkali-silica reaction(ASR)in concrete.Such modeling is essential for investigating the chemical expansion mechanism and the subsequent influence on the mechanical aspects of the material.The concept of ASR and the mechanism of expansion are first outlined,and the stateof-the-art of modeling for ASR,the focus of the paper,is then presented in detail.The modeling includes theoretical approaches,meso-and macroscopic models for ASR analysis.The theoretical approaches dealt with the chemical reaction mechanism and were used for predicting pessimum size of aggregate.Mesoscopic models have attempted to explain the mechanism of mechanical deterioration of ASR-affected concrete at material scale.The macroscopic models,chemomechanical coupling models,have been generally dcveloped by combining the chemical reaction kinetics with linear or nonlinear mechanical constitutive,and were applied to reproduce and predict the long-term behavior of struetures suffering from ASR.Finally,a conclusion and discussion of the modcling are given.展开更多
基金supported by the National Natural Science Foundation of China (Grant No. 10774153)the National Basic Research Program of China (Grant No. 2006CD806000)the Shanghai "Phosphor" Science Foundation, China (Grant No. 08QH1402400)
文摘This paper uses a nonperturbative scattering theory to study photoelectron angular distributions of homonuclear diatomic molecules irradiated by circularly polarized laser fields. This study shows that the nonisotropic feature of photoelectron angular distributions is not due to the polarization of the laser field but the internuclear vector of the molecules. It suggests a method to measure the molecular orientation and the internuclear distance of molecules through the measurement of photoelectron angular distributions.
基金The authors acknowledge the support of the National Key Basic Research Program of China(Nos.2010CB731504 and 2011CB013602)the research funding from the State Key Laboratory of Hydroscience and Engineering,Tsinghua University(No.2010-TC-1).
文摘This paper presents a comprehensive review of modeling of alkali-silica reaction(ASR)in concrete.Such modeling is essential for investigating the chemical expansion mechanism and the subsequent influence on the mechanical aspects of the material.The concept of ASR and the mechanism of expansion are first outlined,and the stateof-the-art of modeling for ASR,the focus of the paper,is then presented in detail.The modeling includes theoretical approaches,meso-and macroscopic models for ASR analysis.The theoretical approaches dealt with the chemical reaction mechanism and were used for predicting pessimum size of aggregate.Mesoscopic models have attempted to explain the mechanism of mechanical deterioration of ASR-affected concrete at material scale.The macroscopic models,chemomechanical coupling models,have been generally dcveloped by combining the chemical reaction kinetics with linear or nonlinear mechanical constitutive,and were applied to reproduce and predict the long-term behavior of struetures suffering from ASR.Finally,a conclusion and discussion of the modcling are given.
