The yield of tar and syngas has been investigated by catalytic pyrolysis of Pingzhuang lignite(PZL)over Ca(OH)2 catalyst in temperature range of 600℃-1000℃in a tube furnace.The results show that the yield of volatil...The yield of tar and syngas has been investigated by catalytic pyrolysis of Pingzhuang lignite(PZL)over Ca(OH)2 catalyst in temperature range of 600℃-1000℃in a tube furnace.The results show that the yield of volatile pyrolysis increases and char decreases with rising temperature for both raw and catalyzed Pingzhuang lignite.The hydrogen fraction(H2)increased from 20%to 40%for the PZL sample;but,for the PZL-Ca(OH)2 sample,H2 fraction fluctuated randomly between 35%to 42%,with the maximum H2 fraction found at 1000℃.The Gaschromatography mass-spectroscopic(GC-MS)analysis revealed that the maximum tar yield at 800℃and 700℃was obtained for PZL and PZL-Ca(OH)2,respectively.The surface morphology of PZL and PZL-Ca(OH)2 chars underwent different transformation in the presence of catalyst as illustrated by SEM/EDX,FTIR,and BET analysis.Furthermore,char sample was investigated for the carbon conversion and reactivity index using TGA analysis under N2 and CO atmosphere.展开更多
基金Supported by the Innovation Reasearch Groups of the National Natural Science Foundation of China(51621005)EPSRC from the UK.
文摘The yield of tar and syngas has been investigated by catalytic pyrolysis of Pingzhuang lignite(PZL)over Ca(OH)2 catalyst in temperature range of 600℃-1000℃in a tube furnace.The results show that the yield of volatile pyrolysis increases and char decreases with rising temperature for both raw and catalyzed Pingzhuang lignite.The hydrogen fraction(H2)increased from 20%to 40%for the PZL sample;but,for the PZL-Ca(OH)2 sample,H2 fraction fluctuated randomly between 35%to 42%,with the maximum H2 fraction found at 1000℃.The Gaschromatography mass-spectroscopic(GC-MS)analysis revealed that the maximum tar yield at 800℃and 700℃was obtained for PZL and PZL-Ca(OH)2,respectively.The surface morphology of PZL and PZL-Ca(OH)2 chars underwent different transformation in the presence of catalyst as illustrated by SEM/EDX,FTIR,and BET analysis.Furthermore,char sample was investigated for the carbon conversion and reactivity index using TGA analysis under N2 and CO atmosphere.
