In this paper,1-butyl-3-methylimidazole tetrafluoroborate([BMIM]BF4)is used as corrosion inhibitor.Polyacrylonitrile(PAN)is used to load the corrosion inhibitor.PAN/[BMIM]BF4 hybrid nanofibers are successfullysynthesi...In this paper,1-butyl-3-methylimidazole tetrafluoroborate([BMIM]BF4)is used as corrosion inhibitor.Polyacrylonitrile(PAN)is used to load the corrosion inhibitor.PAN/[BMIM]BF4 hybrid nanofibers are successfullysynthesized by electrospinning technology.The alkyd varnish is coated on the fiber membrane to prepare a compositecoating,and then a series of tests are carried out on the self-healing and anticorrosive performance of the compositecoating.It is observed by scanning electron microscope that the fiber morphology is stable and there is no bead-likestructure.The composition of the composite fiber is analyzed by Fourier infrared spectroscopy,and it is confirmed thatthe hybrid nanofiber was successfully prepared.3D laser confocal scanning microscope was used to observe thecorrosion morphology and profile of the carbon steel.The composite coating shows good self-healing performance.[BMIM]BF4 can form a protective film on the surface of the bare carbon steel substrate through physical adsorption orchemical adsorption in an alkaline environment.Electrochemical impedance spectroscopy was tested and analyzed.It isfound that the maximum corrosion inhibition efficiency of the coating is 88.5%in 3.5 wt.%alkaline NaCl solution.Compared with the blank coating without nanofibers,the composite fiber varnish composite coating exhibits good selfhealingand anti-corrosion properties.展开更多
某运行高炉煤气余压回收透平发电装置(Blast Furnace Gas Top Pressure Recovery Turbine Unit, TRT)的动叶片是直叶片,机组运行效率不高。在不改变机组进气条件的前提下,通过优化叶型降低流道中的损失,提高TRT涡轮的效率。在给定TRT涡...某运行高炉煤气余压回收透平发电装置(Blast Furnace Gas Top Pressure Recovery Turbine Unit, TRT)的动叶片是直叶片,机组运行效率不高。在不改变机组进气条件的前提下,通过优化叶型降低流道中的损失,提高TRT涡轮的效率。在给定TRT涡轮通流尺寸的基础上优化动叶片的型线,对原始型线进行三维CFD计算,在原型线的基础上进行优化改进,并针对动叶片的叶身部分做了强度校核计算,优化后机组的总效率提高了1.7%,机组的输出功增加了4.2%。展开更多
基金Projects(42076039,42106042)supported by the National Natural Science Foundation of ChinaProject(202165004)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(JC12022106)supported by 2022 Innovation Project for Young Scientific and Technological Talents in Basic Science Research,China。
文摘In this paper,1-butyl-3-methylimidazole tetrafluoroborate([BMIM]BF4)is used as corrosion inhibitor.Polyacrylonitrile(PAN)is used to load the corrosion inhibitor.PAN/[BMIM]BF4 hybrid nanofibers are successfullysynthesized by electrospinning technology.The alkyd varnish is coated on the fiber membrane to prepare a compositecoating,and then a series of tests are carried out on the self-healing and anticorrosive performance of the compositecoating.It is observed by scanning electron microscope that the fiber morphology is stable and there is no bead-likestructure.The composition of the composite fiber is analyzed by Fourier infrared spectroscopy,and it is confirmed thatthe hybrid nanofiber was successfully prepared.3D laser confocal scanning microscope was used to observe thecorrosion morphology and profile of the carbon steel.The composite coating shows good self-healing performance.[BMIM]BF4 can form a protective film on the surface of the bare carbon steel substrate through physical adsorption orchemical adsorption in an alkaline environment.Electrochemical impedance spectroscopy was tested and analyzed.It isfound that the maximum corrosion inhibition efficiency of the coating is 88.5%in 3.5 wt.%alkaline NaCl solution.Compared with the blank coating without nanofibers,the composite fiber varnish composite coating exhibits good selfhealingand anti-corrosion properties.
文摘某运行高炉煤气余压回收透平发电装置(Blast Furnace Gas Top Pressure Recovery Turbine Unit, TRT)的动叶片是直叶片,机组运行效率不高。在不改变机组进气条件的前提下,通过优化叶型降低流道中的损失,提高TRT涡轮的效率。在给定TRT涡轮通流尺寸的基础上优化动叶片的型线,对原始型线进行三维CFD计算,在原型线的基础上进行优化改进,并针对动叶片的叶身部分做了强度校核计算,优化后机组的总效率提高了1.7%,机组的输出功增加了4.2%。
