以湖北省恩施州烟区为例,通过生产调研与数据统计,对烤烟不同生产阶段(育苗期、大田生长期和采后烘烤期)以及整个生产过程的间接碳排放量进行了核算。结果表明:烤烟生产过程中主要碳源的碳排放量表现为烘烤能源>电力>农膜和肥料&...以湖北省恩施州烟区为例,通过生产调研与数据统计,对烤烟不同生产阶段(育苗期、大田生长期和采后烘烤期)以及整个生产过程的间接碳排放量进行了核算。结果表明:烤烟生产过程中主要碳源的碳排放量表现为烘烤能源>电力>农膜和肥料>农药、机械油耗和人工;采后烘烤期的碳排放量最大,大田生长期的次之,育苗期的最小;在大田生长期,不同肥力和不同种植规模烟田的碳排放总量有所差异,其中由肥料产生的碳排放量占总碳排放量的比例最大;按照烤房类型划分,烤烟整个生产过程的间接碳排放量表现为燃煤型烤房(5167.80 kg C/hm^(2))>生物质能源型烤房(2256.75 kg C/hm^(2))。恩施州烤烟生产中间接碳排放的主要影响因素为烘烤能源、电力,其次为农膜和肥料。因此,用生物质燃料全面替代煤炭作为烘烤能源是烤烟生产减少碳排放的重要途径。展开更多
Ti-containing phosphate(Ti-P-O) catalysts with different molar ratios of P to Ti(0—2.0) were synthesized and characterized by XRD, N_ 2 -adsorption/desorption, IR and temperature-programmed desorption(TPD) methods. T...Ti-containing phosphate(Ti-P-O) catalysts with different molar ratios of P to Ti(0—2.0) were synthesized and characterized by XRD, N_ 2 -adsorption/desorption, IR and temperature-programmed desorption(TPD) methods. The catalytic properties of Ti-P-O samples in the vapor-phase O-methylation of catechol with methanol were also studied. The catechol conversion increases with the increase of the molar ratio of P to Ti in a range of 0—0.33, while a further increase in the P content leads to a decrease of the catalytic activity. Meanwhile, the selectivities of the catalysts to the main product(guaiacol) increase gradually with the increase of the molar ratio of P to Ti. The presence of relatively strong Lewis acidic and/or basic sites in the P-free catalyst should be responsible for the formation of C-alkylation products. The weak acid-base characteristics of the catalysts are favourable for the mono-O-methylation of catechol. In comparison with the Lewis acidic sites, the Brnsted acidic sites on the catalysts are more active for the title reaction.展开更多
Various copper promoted Au/ZnO-CuO catalysts with different atomic ratios of Cu to Zn prepared by means of co-precipitation were tested for the low temperature water-gas shift(WGS) reaction. The catalytic activity of ...Various copper promoted Au/ZnO-CuO catalysts with different atomic ratios of Cu to Zn prepared by means of co-precipitation were tested for the low temperature water-gas shift(WGS) reaction. The catalytic activity of the catalyst depends largely on the ratio of Cu to Zn. The addition of an appropriate amount of copper can considerably improve both the catalytic activity and the stability of the catalyst in comparison with those of copper-free Au/ZnO catalysts. The enhanced reducibility of copper oxide in the Au/ZnO-CuO ternary-component catalysts, which was confirmed by H_ 2 -TPR, may be related to the high activity and stability of the catalyst for the low temperature WGS reaction.展开更多
Mesoporous carbon monolith was synthesized by the direct carbonization of compressed sucrose/silica composite,which was prepared by using sol-gel method. The structural and textural properties of the materials were in...Mesoporous carbon monolith was synthesized by the direct carbonization of compressed sucrose/silica composite,which was prepared by using sol-gel method. The structural and textural properties of the materials were investigated by XRD,DRIFT,N2-adsorption and SEM. The characterization study shows that the resultant carbon monolith possesses a relatively high surface area,large pore volume and well interconnected pore system. Addition of a certain amount of citric acid or aluminum nitrate into the sol-gel precursor of sucrose/silica composite could consi-derably change the structure parameters of the carbon monolith.展开更多
文摘以湖北省恩施州烟区为例,通过生产调研与数据统计,对烤烟不同生产阶段(育苗期、大田生长期和采后烘烤期)以及整个生产过程的间接碳排放量进行了核算。结果表明:烤烟生产过程中主要碳源的碳排放量表现为烘烤能源>电力>农膜和肥料>农药、机械油耗和人工;采后烘烤期的碳排放量最大,大田生长期的次之,育苗期的最小;在大田生长期,不同肥力和不同种植规模烟田的碳排放总量有所差异,其中由肥料产生的碳排放量占总碳排放量的比例最大;按照烤房类型划分,烤烟整个生产过程的间接碳排放量表现为燃煤型烤房(5167.80 kg C/hm^(2))>生物质能源型烤房(2256.75 kg C/hm^(2))。恩施州烤烟生产中间接碳排放的主要影响因素为烘烤能源、电力,其次为农膜和肥料。因此,用生物质燃料全面替代煤炭作为烘烤能源是烤烟生产减少碳排放的重要途径。
基金Supported by the Development Project of Science and Technology of Jilin Province(Nos. 20050309-1 and 20040563), the Spe-cialized Research Fund for the Doctoral Program of Higher Education(No.20040183003), CNPC(No.JTGS 20040010), and the Na-tional Natural Science Foundation of China(No.20403006)
文摘Ti-containing phosphate(Ti-P-O) catalysts with different molar ratios of P to Ti(0—2.0) were synthesized and characterized by XRD, N_ 2 -adsorption/desorption, IR and temperature-programmed desorption(TPD) methods. The catalytic properties of Ti-P-O samples in the vapor-phase O-methylation of catechol with methanol were also studied. The catechol conversion increases with the increase of the molar ratio of P to Ti in a range of 0—0.33, while a further increase in the P content leads to a decrease of the catalytic activity. Meanwhile, the selectivities of the catalysts to the main product(guaiacol) increase gradually with the increase of the molar ratio of P to Ti. The presence of relatively strong Lewis acidic and/or basic sites in the P-free catalyst should be responsible for the formation of C-alkylation products. The weak acid-base characteristics of the catalysts are favourable for the mono-O-methylation of catechol. In comparison with the Lewis acidic sites, the Brnsted acidic sites on the catalysts are more active for the title reaction.
文摘Various copper promoted Au/ZnO-CuO catalysts with different atomic ratios of Cu to Zn prepared by means of co-precipitation were tested for the low temperature water-gas shift(WGS) reaction. The catalytic activity of the catalyst depends largely on the ratio of Cu to Zn. The addition of an appropriate amount of copper can considerably improve both the catalytic activity and the stability of the catalyst in comparison with those of copper-free Au/ZnO catalysts. The enhanced reducibility of copper oxide in the Au/ZnO-CuO ternary-component catalysts, which was confirmed by H_ 2 -TPR, may be related to the high activity and stability of the catalyst for the low temperature WGS reaction.
基金Supported by the National Natural Science Foundation of China(Nos.20403006 and 20773050)the State Basic Research Project of China(No.2005CB221405)
文摘Mesoporous carbon monolith was synthesized by the direct carbonization of compressed sucrose/silica composite,which was prepared by using sol-gel method. The structural and textural properties of the materials were investigated by XRD,DRIFT,N2-adsorption and SEM. The characterization study shows that the resultant carbon monolith possesses a relatively high surface area,large pore volume and well interconnected pore system. Addition of a certain amount of citric acid or aluminum nitrate into the sol-gel precursor of sucrose/silica composite could consi-derably change the structure parameters of the carbon monolith.