Significant challenges are posed by the limitations of gas sensing mechanisms for trace-level detection of ammonia(NH3).In this study,we propose to exploit single-atom catalytic activation and targeted adsorption prop...Significant challenges are posed by the limitations of gas sensing mechanisms for trace-level detection of ammonia(NH3).In this study,we propose to exploit single-atom catalytic activation and targeted adsorption properties to achieve highly sensitive and selective NH3 gas detection.Specifically,Ni singleatom active sites based on N,C coordination(Ni-N-C)were interfacially confined on the surface of two-dimensional(2D)MXene nanosheets(Ni-N-C/Ti_(3)C_(2)Tx),and a fully flexible gas sensor(MNPE-Ni-N-C/Ti_(3)C_(2)Tx)was integrated.The sensor demonstrates a remarkable response value to 5 ppm NH3(27.3%),excellent selectivity for NH3,and a low theoretical detection limit of 12.1 ppb.Simulation analysis by density functional calculation reveals that the Ni single-atom center with N,C coordination exhibits specific targeted adsorption properties for NH3.Additionally,its catalytic activation effect effectively reduces the Gibbs free energy of the sensing elemental reaction,while its electronic structure promotes the spill-over effect of reactive oxygen species at the gas-solid interface.The sensor has a dual-channel sensing mechanism of both chemical and electronic sensitization,which facilitates efficient electron transfer to the 2D MXene conductive network,resulting in the formation of the NH3 gas molecule sensing signal.Furthermore,the passivation of MXene edge defects by a conjugated hydrogen bond network enhances the long-term stability of MXene-based electrodes under high humidity conditions.This work achieves highly sensitive room-temperature NH3 gas detection based on the catalytic mechanism of Ni single-atom active center with N,C coordination,which provides a novel gas sensing mechanism for room-temperature trace gas detection research.展开更多
Stretchable thermoelectrics have recently attracted widespread attention in the field of self-powered wearable electronics due to their unique capability of harvesting body heat.However,it remains challenging to devel...Stretchable thermoelectrics have recently attracted widespread attention in the field of self-powered wearable electronics due to their unique capability of harvesting body heat.However,it remains challenging to develop thermoelectric materials with excellent stretchability,durable thermoelectric properties,wearable comfort,and multifunctional sensing properties simultaneously.Herein,an advanced preparation strategy combining electrospinning and spraying technology is proposed to prepare carbon nanotube(CNT)/polyvinyl pyrrolidone(PVP)/polyurethane(PU)composite thermoelectric fabrics that have high air permeability and stretchability(~250%)close to those of pure PU nanofiber fabrics.Furthermore,PVP can not only improve the dispersion of CNTs but also act as interfacial binders between the CNT and the elastic PU skeleton.Consequently,both the electrical conductivity and the Seebeck coefficient remain unchanged even after bending 1000 times.In addition,self-powered sensors for the mutual conversion of finger temperature and language and detection of the movement of joints to optimize an athlete's movement state were successfully fabricated.This study paves the way for stretchable thermoelectric fabrics with fascinating applications in smart wearable fields such as power generation,health monitoring,and human–computer interaction.展开更多
Real-time rapid detection of toxic gases at room temperature is particularly important for public health and environmental monitoring.Gas sensors based on conventional bulk materials often suffer from their poor surfa...Real-time rapid detection of toxic gases at room temperature is particularly important for public health and environmental monitoring.Gas sensors based on conventional bulk materials often suffer from their poor surface-sensitive sites,leading to a very low gas adsorption ability.Moreover,the charge transportation efficiency is usually inhibited by the low defect density of surface-sensitive area than that in the interior.In this work,a gas sensing structure model based on CuS quantum dots/Bi_(2)S_(3) nanosheets(CuS QDs/Bi_(2)S_(3) NSs)inspired by artificial neuron network is constructed.Simulation analysis by density functional calculation revealed that CuS QDs and Bi_(2)S_(3) NSs can be used as the main adsorption sites and charge transport pathways,respectively.Thus,the high-sensitivity sensing of NO_(2) can be realized by designing the artificial neuron-like sensor.The experimental results showed that the CuS QDs with a size of about 8 nm are highly adsorbable,which can enhance the NO_(2) sensitivity due to the rich sensitive sites and quantum size effect.The Bi_(2)S_(3) NSs can be used as a charge transfer network channel to achieve efficient charge collection and transmission.The neuron-like sensor that simulates biological smell shows a significantly enhanced response value(3.4),excellent responsiveness(18 s)and recovery rate(338 s),low theoretical detection limit of 78 ppb,and excellent selectivity for NO_(2).Furthermore,the developed wearable device can also realize the visual detection of NO2 through real-time signal changes.展开更多
Drop-on-demand (DOD) bioprinting has been widely used in tissue engineering due to its highthroughput efficiency and cost effectiveness. However, this type of bioprinting involves challenges such as satellite generati...Drop-on-demand (DOD) bioprinting has been widely used in tissue engineering due to its highthroughput efficiency and cost effectiveness. However, this type of bioprinting involves challenges such as satellite generation, too-large droplet generation, and too-low droplet speed. These challenges reduce the stability and precision of DOD printing, disorder cell arrays, and hence generate further structural errors. In this paper, a multi-objective optimization (MOO) design method for DOD printing parameters through fully connected neural networks (FCNNs) is proposed in order to solve these challenges. The MOO problem comprises two objective functions: to develop the satellite formation model with FCNNs;and to decrease droplet diameter and increase droplet speed. A hybrid multi-subgradient descent bundle method with an adaptive learning rate algorithm (HMSGDBA), which combines the multisubgradient descent bundle (MSGDB) method with Adam algorithm, is introduced in order to search for the Pareto-optimal set for the MOO problem. The superiority of HMSGDBA is demonstrated through comparative studies with the MSGDB method. The experimental results show that a single droplet can be printed stably and the droplet speed can be increased from 0.88 to 2.08 m·s^-1 after optimization with the proposed method. The proposed method can improve both printing precision and stability, and is useful in realizing precise cell arrays and complex biological functions. Furthermore, it can be used to obtain guidelines for the setup of cell-printing experimental platforms.展开更多
BACKGROUND Hepatocellular carcinoma(HCC) is one of the most common malignant tumors worldwide, and novel methods for early/rapid diagnosis of HCC are needed.Terahertz(THz) spectroscopy is considered to have the potent...BACKGROUND Hepatocellular carcinoma(HCC) is one of the most common malignant tumors worldwide, and novel methods for early/rapid diagnosis of HCC are needed.Terahertz(THz) spectroscopy is considered to have the potential to distinguish between normal liver tissue and HCC tissue; however, there are few reports on it.We conduct this observational study to explore the feasibility of THz imaging for the diagnosis of HCC.AIM To evaluate the feasibility of THz for discriminating between HCC and normal liver tissues using fresh tissue specimens obtained from HCC patients who had undergone surgery.METHODS Normal liver tissue and HCC tissue were cryosectioned into 50 μm-thick slicesand placed on cover glass. Two adjacent tissue sections were separated subjected to histopathological examination by hematoxylin and eosin staining or THz transmission examination, and THz images were compared with pathologically mapped images. We determined the typical tumor and normal liver tissue regions by pathological examination; the corresponding areas of adjacent sections were examined by THz transmission.RESULTS The transmission rate of HCC tissue was 0.15-0.25, and the transmission rate of typical HCC tissue was about 0.2. THz transmittance in normal liver tissue is slightly higher than 0.4, but there were many influencing factors, including the degree of liver cirrhosis, fat components, ice crystals in frozen sections, and apoptosis.CONCLUSION In conclusion, this study shows that THz imaging can detect HCC tissue. Further research will yield more detailed data of the THz transmission rates of HCC tissue with different degrees of differentiation.展开更多
BACKGROUND Post-transarterial chemoembolization(TACE)liver failure occurs frequently in hepatocellular carcinoma(HCC)patients.The identification of predictors for post-TACE liver failure is of great importance for cli...BACKGROUND Post-transarterial chemoembolization(TACE)liver failure occurs frequently in hepatocellular carcinoma(HCC)patients.The identification of predictors for post-TACE liver failure is of great importance for clinical decision-making in this population.AIM To investigate the occurrence rate and predictive factors of post-TACE liver failure in this retrospective study to provide clues for decision-making regarding TACE procedures in HCC patients.METHODS The clinical records of HCC patients treated with TACE therapy were reviewed.Baseline clinical characteristics and laboratory parameters of these patients were extracted.Logistic models were used to identify candidates to predict post-TACE liver failure.RESULTS A total of 199 HCC patients were enrolled in this study,and 70 patients(35.2%)developed post-TACE liver failure.Univariate and multivariate logistic models indicated that microspheres plus gelatin embolization and main tumor size>5 cm were risk predictors for post-TACE liver failure[odds ratio(OR):4.4,95%confidence interval(CI):1.2-16.3,P=0.027;OR:2.3,95%CI:1.05-5.3,P=0.039,respectively].Conversely,HCC patients who underwent tumor resection surgery before the TACE procedure had a lower risk for post-TACE liver failure(OR:0.4,95%CI:0.2-0.95,P=0.039).CONCLUSION Microspheres plus gelatin embolization and main tumor size might be risk factors for post-TACE liver failure in HCC patients,while prior tumor resection could be a favorable factor reducing the risk of post-TACE liver failure.展开更多
In this work,the influence of CO2 on the structural variation and catalytic performance of Na2WO4/Mn/Si O2 for oxidative coupling of methane to ethylene was investigated. The catalyst was prepared by impregnation meth...In this work,the influence of CO2 on the structural variation and catalytic performance of Na2WO4/Mn/Si O2 for oxidative coupling of methane to ethylene was investigated. The catalyst was prepared by impregnation method and characterized by XRD,Raman and XPS techniques. Appropriate amount of CO2 in the reactant gases enhanced the formation of surface tetrahedral Na2WO4 species and promoted the migration of O in MOx,Na,W from the catalyst bulk to surface,which were favorable for oxidative coupling of methane. When the molar ratio of CH4/O2/CO2 was 3/1/2,enriched surface tetrahedral Na2WO4 species and high surface concentration of O in MOx,Na,W were detected,and then high CH4 conversion of 33.1% and high C2H4 selectivity of 56.2% were obtained. With further increase of CO2 in the reagent gases,the content of active surface tetrahedral Na2WO4 species and surface concentration of O in MOx,Na,W decreased,while that of inactive species(Mn WO4 and Mn2O3) increased dramatically,leading to low CH4 conversion and low C2H4 selectivity. It could be speculated that Na2WO4 crystal was transformed into Mn WO4 crystal with excessive CO2 added under the reaction conditions. Pretreatment of Na2WO4/Mn/Si O2 catalyst by moderate amount of CO2 before OCM also promoted the formation of Na2WO4 species.展开更多
In order to improve the energy efficiency(EE)in the underlay cognitive radio(CR)networks,a power allocation strategy based on an actor-critic reinforcement learning is proposed,where a cluster of cognitive users(CUs)c...In order to improve the energy efficiency(EE)in the underlay cognitive radio(CR)networks,a power allocation strategy based on an actor-critic reinforcement learning is proposed,where a cluster of cognitive users(CUs)can simultaneously access to the same primary spectrum band under the interference constraints of the primary user(PU),by employing the non-orthogonal multiple access(NOMA)technique.In the proposed scheme,the optimization of the power allocation is formulated as a non-convex optimization problem.Additionally,the power allocation for different CUs is based on the actor-critic reinforcement learning model,in which the weighted data rate is set as the reward function,and the generated action strategy(i.e.the power allocation)is iteratively criticized and updated.Both the CU’s spectral efficiency and the PU’s interference constrains are considered in the training of the actor-critic reinforcement learning.Furthermore,the first order Taylor approximation as well as other manipulations are adopted to solve the power allocation optimization problem for the sake of considering the conventional channel conditions.According to the simulation results,we find that our scheme could achieve a higher spectral efficiency for the CUs compared to a benchmark scheme without learning process as well as the existing Q-learning based method,while the resultant interference affecting the PU transmission can be maintained at a given tolerated limit.展开更多
Extensive research attentions have been devoted to studying cooperative cognitive radio networks(CCRNs),where secondary users(SU)providing cooperative transmissions can be permitted by primary users(PU)to use spectrum...Extensive research attentions have been devoted to studying cooperative cognitive radio networks(CCRNs),where secondary users(SU)providing cooperative transmissions can be permitted by primary users(PU)to use spectrum.In order to maximize SU’s utility,SU may transmit its own information during the period of cooperative transmission,which stimulates the use of covert transmission against PU’s monitoring.For this sake,this article reviews the motivations of studying covert communications in CCRN.In particular,three intelligent covert transmission approaches are developed for maximizing SU’s utility in CCRNs,namely,intelligent parasitic covert transmission(IPCT),intelligent jammer aided covert transmission(IJCT)and intelligent reflecting surface assisted covert transmission(IRSC).Further,some raw performance evaluations are discussed,and a range of potential research directions are also provided.展开更多
Frequency-hopping(FH) technique is widely used in high-secure communications by exploiting its capabilities of mitigating interference and confidentiality. However, electronic attacks in wireless systems become more a...Frequency-hopping(FH) technique is widely used in high-secure communications by exploiting its capabilities of mitigating interference and confidentiality. However, electronic attacks in wireless systems become more and more rigorous, which poses huge challenges to the use of the number theory based and chaos theory assisted sequences. The structure of the FH sequence directly affects the performance of FH communication systems. In this paper, the novel FH sequence generation scheme is proposed with the aid of the so-called Government Standard(GOST) algorithm, which achieves a promising balance between efficiency and security. Moreover, the security performance of the proposed algorithm is analyzed, which reveals that it is more resistant to impossible differential attacks than the widely-used Data Encryption Standard(DES) algorithm. The numerical results show that the FH sequences generated by the GOST algorithm significantly outperform the ones generated by the DES algorithm and chaotic theory in terms of the randomness and complexity.展开更多
In December 2019,coronavirus disease 2019(COVID-19)caused by a novel coronavirus(SARS-CoV-2)broke out in Wuhan,China,and has spread widely all over the world,reaching the pandemic level.[1]According to the latest WHO ...In December 2019,coronavirus disease 2019(COVID-19)caused by a novel coronavirus(SARS-CoV-2)broke out in Wuhan,China,and has spread widely all over the world,reaching the pandemic level.[1]According to the latest WHO report,693,224 cases of COVID-19 were confirmed globally as of March 30,2020,with more than 33,000 deaths.[2]Because COVID-19 is highly contagious and harmful,it is crucial to determine the predictors of severe infection and death for risk stratification and guiding clinical treatment and intervention.展开更多
基金supported by the National Key Research and Development Program of China(2022YFB3205500)the National Natural Science Foundation of China(62371299,62301314 and 62101329)+2 种基金the China Postdoctoral Science Foundation(2023M732198)the Natural Science Foundation of Shanghai(23ZR1430100)supported by the Center for High-Performance Computing at Shanghai Jiao Tong University.
文摘Significant challenges are posed by the limitations of gas sensing mechanisms for trace-level detection of ammonia(NH3).In this study,we propose to exploit single-atom catalytic activation and targeted adsorption properties to achieve highly sensitive and selective NH3 gas detection.Specifically,Ni singleatom active sites based on N,C coordination(Ni-N-C)were interfacially confined on the surface of two-dimensional(2D)MXene nanosheets(Ni-N-C/Ti_(3)C_(2)Tx),and a fully flexible gas sensor(MNPE-Ni-N-C/Ti_(3)C_(2)Tx)was integrated.The sensor demonstrates a remarkable response value to 5 ppm NH3(27.3%),excellent selectivity for NH3,and a low theoretical detection limit of 12.1 ppb.Simulation analysis by density functional calculation reveals that the Ni single-atom center with N,C coordination exhibits specific targeted adsorption properties for NH3.Additionally,its catalytic activation effect effectively reduces the Gibbs free energy of the sensing elemental reaction,while its electronic structure promotes the spill-over effect of reactive oxygen species at the gas-solid interface.The sensor has a dual-channel sensing mechanism of both chemical and electronic sensitization,which facilitates efficient electron transfer to the 2D MXene conductive network,resulting in the formation of the NH3 gas molecule sensing signal.Furthermore,the passivation of MXene edge defects by a conjugated hydrogen bond network enhances the long-term stability of MXene-based electrodes under high humidity conditions.This work achieves highly sensitive room-temperature NH3 gas detection based on the catalytic mechanism of Ni single-atom active center with N,C coordination,which provides a novel gas sensing mechanism for room-temperature trace gas detection research.
基金Fundamental Research Funds for the Central Universities,Grant/Award Number:2232020A-08National Natural Science Foundation of China,Grant/Award Numbers:51973027,52003044。
文摘Stretchable thermoelectrics have recently attracted widespread attention in the field of self-powered wearable electronics due to their unique capability of harvesting body heat.However,it remains challenging to develop thermoelectric materials with excellent stretchability,durable thermoelectric properties,wearable comfort,and multifunctional sensing properties simultaneously.Herein,an advanced preparation strategy combining electrospinning and spraying technology is proposed to prepare carbon nanotube(CNT)/polyvinyl pyrrolidone(PVP)/polyurethane(PU)composite thermoelectric fabrics that have high air permeability and stretchability(~250%)close to those of pure PU nanofiber fabrics.Furthermore,PVP can not only improve the dispersion of CNTs but also act as interfacial binders between the CNT and the elastic PU skeleton.Consequently,both the electrical conductivity and the Seebeck coefficient remain unchanged even after bending 1000 times.In addition,self-powered sensors for the mutual conversion of finger temperature and language and detection of the movement of joints to optimize an athlete's movement state were successfully fabricated.This study paves the way for stretchable thermoelectric fabrics with fascinating applications in smart wearable fields such as power generation,health monitoring,and human–computer interaction.
基金supported by the National Natural Science Foundation of China(61971284)the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University(SL2020ZD203 and SL2020MS031)+2 种基金Scientific Research Fund of Second Institute of Oceanography,Ministry of Natural Resources of P.R.China(SL2003)Shanghai Sailing Program(21YF1421400)Startup Fund for Youngman Research at Shanghai Jiao Tong University.
文摘Real-time rapid detection of toxic gases at room temperature is particularly important for public health and environmental monitoring.Gas sensors based on conventional bulk materials often suffer from their poor surface-sensitive sites,leading to a very low gas adsorption ability.Moreover,the charge transportation efficiency is usually inhibited by the low defect density of surface-sensitive area than that in the interior.In this work,a gas sensing structure model based on CuS quantum dots/Bi_(2)S_(3) nanosheets(CuS QDs/Bi_(2)S_(3) NSs)inspired by artificial neuron network is constructed.Simulation analysis by density functional calculation revealed that CuS QDs and Bi_(2)S_(3) NSs can be used as the main adsorption sites and charge transport pathways,respectively.Thus,the high-sensitivity sensing of NO_(2) can be realized by designing the artificial neuron-like sensor.The experimental results showed that the CuS QDs with a size of about 8 nm are highly adsorbable,which can enhance the NO_(2) sensitivity due to the rich sensitive sites and quantum size effect.The Bi_(2)S_(3) NSs can be used as a charge transfer network channel to achieve efficient charge collection and transmission.The neuron-like sensor that simulates biological smell shows a significantly enhanced response value(3.4),excellent responsiveness(18 s)and recovery rate(338 s),low theoretical detection limit of 78 ppb,and excellent selectivity for NO_(2).Furthermore,the developed wearable device can also realize the visual detection of NO2 through real-time signal changes.
文摘Drop-on-demand (DOD) bioprinting has been widely used in tissue engineering due to its highthroughput efficiency and cost effectiveness. However, this type of bioprinting involves challenges such as satellite generation, too-large droplet generation, and too-low droplet speed. These challenges reduce the stability and precision of DOD printing, disorder cell arrays, and hence generate further structural errors. In this paper, a multi-objective optimization (MOO) design method for DOD printing parameters through fully connected neural networks (FCNNs) is proposed in order to solve these challenges. The MOO problem comprises two objective functions: to develop the satellite formation model with FCNNs;and to decrease droplet diameter and increase droplet speed. A hybrid multi-subgradient descent bundle method with an adaptive learning rate algorithm (HMSGDBA), which combines the multisubgradient descent bundle (MSGDB) method with Adam algorithm, is introduced in order to search for the Pareto-optimal set for the MOO problem. The superiority of HMSGDBA is demonstrated through comparative studies with the MSGDB method. The experimental results show that a single droplet can be printed stably and the droplet speed can be increased from 0.88 to 2.08 m·s^-1 after optimization with the proposed method. The proposed method can improve both printing precision and stability, and is useful in realizing precise cell arrays and complex biological functions. Furthermore, it can be used to obtain guidelines for the setup of cell-printing experimental platforms.
基金Supported by the National Natural Science Foundation of China,No.11622542 and No.51677145
文摘BACKGROUND Hepatocellular carcinoma(HCC) is one of the most common malignant tumors worldwide, and novel methods for early/rapid diagnosis of HCC are needed.Terahertz(THz) spectroscopy is considered to have the potential to distinguish between normal liver tissue and HCC tissue; however, there are few reports on it.We conduct this observational study to explore the feasibility of THz imaging for the diagnosis of HCC.AIM To evaluate the feasibility of THz for discriminating between HCC and normal liver tissues using fresh tissue specimens obtained from HCC patients who had undergone surgery.METHODS Normal liver tissue and HCC tissue were cryosectioned into 50 μm-thick slicesand placed on cover glass. Two adjacent tissue sections were separated subjected to histopathological examination by hematoxylin and eosin staining or THz transmission examination, and THz images were compared with pathologically mapped images. We determined the typical tumor and normal liver tissue regions by pathological examination; the corresponding areas of adjacent sections were examined by THz transmission.RESULTS The transmission rate of HCC tissue was 0.15-0.25, and the transmission rate of typical HCC tissue was about 0.2. THz transmittance in normal liver tissue is slightly higher than 0.4, but there were many influencing factors, including the degree of liver cirrhosis, fat components, ice crystals in frozen sections, and apoptosis.CONCLUSION In conclusion, this study shows that THz imaging can detect HCC tissue. Further research will yield more detailed data of the THz transmission rates of HCC tissue with different degrees of differentiation.
基金Supported by Shanghai Science and Technology Committee,No.19401931600Shanghai Municipal Health Commission,No.2020LZ001Health Commission of Pudong New District,Shanghai,No.PDZY-2021-0706.
文摘BACKGROUND Post-transarterial chemoembolization(TACE)liver failure occurs frequently in hepatocellular carcinoma(HCC)patients.The identification of predictors for post-TACE liver failure is of great importance for clinical decision-making in this population.AIM To investigate the occurrence rate and predictive factors of post-TACE liver failure in this retrospective study to provide clues for decision-making regarding TACE procedures in HCC patients.METHODS The clinical records of HCC patients treated with TACE therapy were reviewed.Baseline clinical characteristics and laboratory parameters of these patients were extracted.Logistic models were used to identify candidates to predict post-TACE liver failure.RESULTS A total of 199 HCC patients were enrolled in this study,and 70 patients(35.2%)developed post-TACE liver failure.Univariate and multivariate logistic models indicated that microspheres plus gelatin embolization and main tumor size>5 cm were risk predictors for post-TACE liver failure[odds ratio(OR):4.4,95%confidence interval(CI):1.2-16.3,P=0.027;OR:2.3,95%CI:1.05-5.3,P=0.039,respectively].Conversely,HCC patients who underwent tumor resection surgery before the TACE procedure had a lower risk for post-TACE liver failure(OR:0.4,95%CI:0.2-0.95,P=0.039).CONCLUSION Microspheres plus gelatin embolization and main tumor size might be risk factors for post-TACE liver failure in HCC patients,while prior tumor resection could be a favorable factor reducing the risk of post-TACE liver failure.
基金support from the Ministry of Science and Technology (Nos.2012BAC20B10)the National Natural Science Foundation of China (Nos. 21321061 and 20976109)
文摘In this work,the influence of CO2 on the structural variation and catalytic performance of Na2WO4/Mn/Si O2 for oxidative coupling of methane to ethylene was investigated. The catalyst was prepared by impregnation method and characterized by XRD,Raman and XPS techniques. Appropriate amount of CO2 in the reactant gases enhanced the formation of surface tetrahedral Na2WO4 species and promoted the migration of O in MOx,Na,W from the catalyst bulk to surface,which were favorable for oxidative coupling of methane. When the molar ratio of CH4/O2/CO2 was 3/1/2,enriched surface tetrahedral Na2WO4 species and high surface concentration of O in MOx,Na,W were detected,and then high CH4 conversion of 33.1% and high C2H4 selectivity of 56.2% were obtained. With further increase of CO2 in the reagent gases,the content of active surface tetrahedral Na2WO4 species and surface concentration of O in MOx,Na,W decreased,while that of inactive species(Mn WO4 and Mn2O3) increased dramatically,leading to low CH4 conversion and low C2H4 selectivity. It could be speculated that Na2WO4 crystal was transformed into Mn WO4 crystal with excessive CO2 added under the reaction conditions. Pretreatment of Na2WO4/Mn/Si O2 catalyst by moderate amount of CO2 before OCM also promoted the formation of Na2WO4 species.
基金The work was supported by the Fundamental Research Funds for the Central Universities Grant3102018QD096in part by the Natural Science Basic Research Plan in Shaanxi Province of China under Grant 2019JQ-075 and Grant 2019JQ-253,and in part by the National Natural Science Foundation of China under Grant 61901379,Grant 61901327,Grant 61825104 and Grant 61631015.
文摘In order to improve the energy efficiency(EE)in the underlay cognitive radio(CR)networks,a power allocation strategy based on an actor-critic reinforcement learning is proposed,where a cluster of cognitive users(CUs)can simultaneously access to the same primary spectrum band under the interference constraints of the primary user(PU),by employing the non-orthogonal multiple access(NOMA)technique.In the proposed scheme,the optimization of the power allocation is formulated as a non-convex optimization problem.Additionally,the power allocation for different CUs is based on the actor-critic reinforcement learning model,in which the weighted data rate is set as the reward function,and the generated action strategy(i.e.the power allocation)is iteratively criticized and updated.Both the CU’s spectral efficiency and the PU’s interference constrains are considered in the training of the actor-critic reinforcement learning.Furthermore,the first order Taylor approximation as well as other manipulations are adopted to solve the power allocation optimization problem for the sake of considering the conventional channel conditions.According to the simulation results,we find that our scheme could achieve a higher spectral efficiency for the CUs compared to a benchmark scheme without learning process as well as the existing Q-learning based method,while the resultant interference affecting the PU transmission can be maintained at a given tolerated limit.
基金supported by the National Natural Science Foundation of China under Grant 61825104, in part by the National Natural Science Foundation of China under Grants 61801518, 62201582in part by the National Key R&D Program of China under Grant 2022YFC3301300+3 种基金in part by the Key Research and Development Program of Shaanxi under Grant 2022KW-03in part by the Young Talent fund of University Association for Science and Technology in Shaanxi under Grant 20210111in part by the Natural Science Basic Research Program of Shaanxi under Grant 2022JQ-632in part by Innovative Cultivation Project of School of Information and Communication of National University of Defense Technology under Grant YJKT-ZD-2202
文摘Extensive research attentions have been devoted to studying cooperative cognitive radio networks(CCRNs),where secondary users(SU)providing cooperative transmissions can be permitted by primary users(PU)to use spectrum.In order to maximize SU’s utility,SU may transmit its own information during the period of cooperative transmission,which stimulates the use of covert transmission against PU’s monitoring.For this sake,this article reviews the motivations of studying covert communications in CCRN.In particular,three intelligent covert transmission approaches are developed for maximizing SU’s utility in CCRNs,namely,intelligent parasitic covert transmission(IPCT),intelligent jammer aided covert transmission(IJCT)and intelligent reflecting surface assisted covert transmission(IRSC).Further,some raw performance evaluations are discussed,and a range of potential research directions are also provided.
基金supported in part by the National Natural Science Foundation of China (No.61631015 and 61501354)
文摘Frequency-hopping(FH) technique is widely used in high-secure communications by exploiting its capabilities of mitigating interference and confidentiality. However, electronic attacks in wireless systems become more and more rigorous, which poses huge challenges to the use of the number theory based and chaos theory assisted sequences. The structure of the FH sequence directly affects the performance of FH communication systems. In this paper, the novel FH sequence generation scheme is proposed with the aid of the so-called Government Standard(GOST) algorithm, which achieves a promising balance between efficiency and security. Moreover, the security performance of the proposed algorithm is analyzed, which reveals that it is more resistant to impossible differential attacks than the widely-used Data Encryption Standard(DES) algorithm. The numerical results show that the FH sequences generated by the GOST algorithm significantly outperform the ones generated by the DES algorithm and chaotic theory in terms of the randomness and complexity.
文摘In December 2019,coronavirus disease 2019(COVID-19)caused by a novel coronavirus(SARS-CoV-2)broke out in Wuhan,China,and has spread widely all over the world,reaching the pandemic level.[1]According to the latest WHO report,693,224 cases of COVID-19 were confirmed globally as of March 30,2020,with more than 33,000 deaths.[2]Because COVID-19 is highly contagious and harmful,it is crucial to determine the predictors of severe infection and death for risk stratification and guiding clinical treatment and intervention.