Mixed rare earth concentrate leaching with HCl-AlCl_3 solution

Abstract A method of Baotou mixed rare earth concen- trate leaching was investigated. According to the principle of complex leaching, the quadratic orthogonal regression experiment was used to investigate effect of six factors. An optimal condition of low energy and environment friendly was determined as follows： HCl acidity is 4 mol.L-1, AlCl3 concentration is 2 mol.L-l, reaction temperature is 85 ℃, reaction time is 90 rain, liquid to solid ratio is 35 ml.g-1, and stirring speed is 100 r.min-1. According to this condition, the leaching ratio of mixed rare earth con- centrate is 76.5 %. The analyses of X-ray diffraction shows that bastnasite disappears, and the main peaks of filter residue is monazite and cheralite after leaching of HCl- AlCl3 solution. The result indicates that REFCO3 of the mixed rare earth concentrate can be dissolved, but REPO4 remains in the leaching residue. This method provides a way to separate and extract rare earth.

Establishment of model of visceral pain due to colorectal distension and its behavioral assessment in rats

瞄准：证实内脏的疼痛经由颜色为表面的扩张(CRD ) 建模并且由在老鼠测量腹的屈肌反射(AWR ) 的分数评估 CRD 的行为的回答的效率。方法：称 180-240 g 的 38 只男 SD 老鼠被用来建立内脏的疼痛模型。老鼠与 7 厘米 intra-anally 被插入在醚麻醉下面的长灵活的乳胶汽球，和由与空气使汽球膨胀的表面的扩张在从麻醉恢复以后被成为 30 min 的颜色。五个 AWR 分数(到 AWR4 的 AWR0 ) 被用来估计有害内脏的刺激的紧张。它被认为是最低压(kPa ) 的阀值。因为腹的 flatting 被颜色导致表面的扩张。结果：到下降冒号和直肠的扩张的精力旺盛的 AWR 在 100% 被发现醒着测试的老鼠。越高扩张的压力，越 higher AWR 的分数。0， 2.00， 3.33， 5.33 和 8.00 kPa 的扩张压力生产了不同 AWR 分数(P【0.05 ) 。AWR 的痛觉阈为在起始的终结(第一 1-3 扩张) 以后的多达 80 min 是不变的，吝啬的阀值是 3.69+/-0.35 kPa。吗啡硫酸盐的全身的管理在一个剂量依赖者和 naloxone 提高了内脏的疼痛的阀值可逆举止。结论：在表面的扩张能估计的颜色期间获得 AWR 有害内脏的刺激的紧张。到内脏的痛觉阈清楚、不变、可靠的 CRD 的腹部(AWR 3 ) 的 Flatting。这个疼痛模型和它的行为的评价对关于内脏的疼痛和止痛剂的研究好。

Quantitative evaluation of multi-process collaborative operation in steelmaking–continuous casting sections

The quantitative evaluation of multi-process collaborative operation is of great significance for the improvement of production planning and scheduling in steelmaking–continuous casting sections(SCCSs). However, this evaluation is difficult since it relies on an in-depth understanding of the operating mechanism of SCCSs, and few existing methods can be used to conduct the evaluation, due to the lack of full-scale consideration of the multiple factors related to the production operation. In this study, three quantitative models were developed, and the multiprocess collaborative operation level was evaluated through the laminar-flow operation degree, the process matching degree, and the scheduling strategy availability degree. Based on the evaluation models for the laminar-flow operation and process matching levels, this study investigated the production status of two steelmaking plants, plants A and B, based on actual production data. The average laminar-flow operation(process matching) degrees of SCCSs were obtained as 0.638(0.610) and 1.000(0.759) for plants A and B, respectively, for the period of April to July 2019. Then, a scheduling strategy based on the optimization of the furnace-caster coordinating mode was suggested for plant A. Simulation experiments showed higher availability than the greedy-based and manual strategies. After the proposed scheduling strategy was applied,the average process matching degree of the SCCS of plant A increased by 4.6% for the period of September to November 2019. The multi-process collaborative operation level was improved with fewer adjustments and interruptions in casting.

Research on properties of hollow glass microspheres/epoxy resin composites applied in deep rock in-situ temperature-preserved coring

Deep petroleum resources are in a high-temperature environment.However,the traditional deep rock coring method has no temperature preserved measures and ignores the effect of temperature on rock porosity and permeability,which will lead to the distortion of the petroleum resources reserves assessment.Therefore,the hollow glass microspheres/epoxy resin(HGM/EP)composites were innovatively proposed as temperature preserved materials for in-situ temperature-preserved coring(ITP-Coring),and the physical,mechanical,and temperature preserved properties were evaluated.The results indicated that:As the HGM content increased,the density and mechanical properties of the composites gradually decreased,while the water absorption was deficient without hydrostatic pressure.For composites with 50 vol%HGM,when the hydrostatic pressure reached 60 MPa,the water absorption was above 30.19%,and the physical and mechanical properties of composites were weakened.When the hydrostatic pressure was lower than 40 MPa,the mechanical properties and thermal conductivity of composites were almost unchanged.Therefore,the composites with 50 vol%HGM can be used for ITPCoring operations in deep environments with the highest hydrostatic pressure of 40 MPa.Finally,to further understand the temperature preserved performance of composites in practical applications,the temperature preserved properties were measured.An unsteady-state heat transfer model was established based on the test results,then the theoretical change of the core temperature during the coring process was obtained.The above tests results can provide a research basis for deep rock in-situ temperature preserved corer and support accurate assessment of deep petroleum reserves.

Single nucleotide polymorphisms in the CDH17 gene of colorectal carcinoma

AIM:To investigate the relationship between c.343A>G and c.2216A>C polymorphism sites in the CDH17 gene and colorectal carcinoma.METHODS:Ninety-three non-consanguineous colorectal carcinoma patients admitted to the Department of Oncology at the First Affiliated Hospital of Zhengzhou University were included in this study.Ninety-three peripheral venous blood samples,of approximately one milliliter from each patient,were collected betweenDecember 2009 and August 2010.The genomic DNA of these peripheral venous blood samples were extracted and purified using a Fermentas Genomic DNA Purification Kit(Fermentas,CA) according to the manufacturer' s protocol.The single nucleotide polymorphisms(SNPs) of the liver-intestine cadherin(CDH17) gene c.343A>G and c.2216A>C were determined by the polymerase chain reaction-single strand conformation polymorphism method(PCR-SSCP) in 93 peripheral venous blood samples from patients suffering with colorectal carcinoma.Typical samples that showed different migration bands in SSCP were confirmed by sequencing.Directed DNA sequencing was used to check the correctness of the genotype results from the PCR-SSCP method.RESULTS:There was a significant association between the c.2216 A>C SNPs of the CDH17 gene and the tumor-node-metastasis(TNM) grade,as well as with lymph node status,in 93 peripheral venous blood samples from colorectal carcinoma patients.The genotype frequencies of A/C,A/A,and C/C were 12.90%,33.33% and 53.76%,respectively.There was a significant correlation between lymph node metastasis,TNM grade,and the genotype distribution(P < 0.05).The C/C genotype raised the risk of lymph node metastasis and the TNM grade.There was a significant difference in the TNM grade and lymph node metastasis between the A/A and C/C genotypes(P = 0.003 and P = 0.013,respectively).Patients with colorectal carcinoma carrying the C allele tended to have a higher risk of lymph node metastasis and have a higher TNM grade.The difference between the TNM grades,as well as the lymph node metastasis of the two alleles,was statistically significant(P < 0.01).CONCLUSION:The SNPs of the CDH17 gene c.2216 A>C might be clinically important in the prognosis of colorectal carcinoma.

Possible Role of DNA Polymerase beta in Protecting Human Bronchial Epithelial Cells Against Cytotoxicity of Hydroquinone

Objective To explore the toxicological mechanism of hydroquinone in human bronchial epithelial cells and to investigate whether DNA polymerase beta is involved in protecting cells from damage caused by hydroquinone. Methods DNA polymerase beta knock-down cell line was established via RNA interference as an experimental group. Normal human bronchial epithelial cells and cells transfected with the empty vector of pEGFP-C1 were used as controls. Cells were treated with different concentrations of hydroquinone （ranged from 10 μmol/L to 120 μmol/L） for 4 hours. MTT assay and Comet assay [single-cell gel electrophoresis （SCGE）] were performed respectively to detect the toxicity of hydroquinone. Results assay showed that DNA polymerase beta knock-down cells treated with different concentrations of hydroquinone had a lower absorbance value at 490 nm than the control cells in a dose-dependant manner. Comet assay revealed that different concentrations of hydroquinone caused more severe DNA damage in DNA polymerase beta knock-down cell line than in control cells and there was no significant difference in the two control groups. Conclusions Hydroquinone has significant toxicity to human bronchial epithelial cells and causes DNA damage. DNA polymerase beta knock-down cell line appears more sensitive to hydroquinone than the control cells. The results suggest that DNA polymerase beta is involved in protecting cells from damage caused by hydroquinone.

Hollow glass microspheres/silicone rubber composite materials toward materials for high performance deep in-situ temperaturepreserved coring

Deep petroleum resources are stored under high temperature and pressure conditions,with the temperature having a significant influence on the properties of rocks.Deep in-situ temperature-preserved coring(ITP-coring)devices were developed to assess deep petroleum reserves accurately.Herein,hollow glass microspheres(HGMs)/silicone rubber(SR)composites that exhibit excellent thermal insulation properties were prepared as thermal insulation materials for deep ITP-coring devices.The mechanism and process of heat transfer in the composites were explored,as well as their other properties.The results show that the HGMs exhibit good compatibility with the SR matrix.When the volume fraction of the HGMs is increased to 50%,the density of the HGMs/SR composites is reduced from 0.97 to 0.56 g/cm^(3).The HGMs filler introduces large voids into the composites,reducing their thermal conductivity to 0.11 W/m·K.The addition of HGMs into the composites further enhances the thermal stability of the SR,wherein the higher the HGMs filler content,the better the thermal stability of the composites.HGMs significantly enhance the mechanical strength of the SR.HGMs increase the compressive strength of the composites by 828%and the tensile strength by 164%.Overall,HGMs improve the thermal insulation,pressure resistance,and thermal stability of HGMs/SR composites.

Flexible and free-standing La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofibers film as a novel high-performance anode for sodium-and potassium-ion batteries

Na superionic conductor(NASICON)-type La_(0.33)Ti_(2)(PO_(4))_(3)(LaTP) is firstly proposed as sodium/potassium storage materials.The density functional theory(DFT) calculations show that LaTP has good electronic character and low Na^(+)/K^(+)migration barriers.The flexible La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofiber film is synthesized via electrostatic spinning and investigated as free-standing electrode applied to sodium-ion batteries(SIBs) and potassiumion batteries(PIBs) in this work.The low band gap and Na^(+)/K^(+) migration barriers of LaTP,unique morphology,and complete conductive carbon net allow the La_(0.33)Ti_(2)(PO_(4))_(3)/C nanofibers film to deliver high capacity(296.3 mAh·g^(-1) for SIBs and 235.8 mAh·g^(-1) for PIBs),excellent rate performance(142.5 mAh·g^(-1) for SIBs and50.5 mAh·g^(-1) for PIBs at 1.00 A·g^(-1)),and superior cyclability above 1000 cycles.The full-cell tests show that the material has a good application prospect,indicating a promising flexible anode material for SIBs and PIBs.

Intercomparison measurements from commonly used precipitation gauges in the Qilian Mountains

Precipitation data is vital fundamental data for climate change.However,obtaining precise gauge-measured precipitation in high-altitude mountains is challenging,and the precipitation obtained from various gauge types at the same station may vary.To understand the differences in precipitation observations among the three commonly used gauges in China(Chinese Standard Precipitation Gauges(CSPG),Total Rain weighing Sensor(TRwS),and Geonor T-200B(T200B))in high-altitude mountains and to recommend a stable and cost-effective weighing gauge,a precipitation intercomparison experiment was conducted at Hulu-1 station in the Qilian Mountains.The wind-induced error in measurement was corrected with the‘universal’transfer function recommended by the Word Meteorological Organization.The comparison results,adjusted for systematic errors,showed that the rain,snow and mixed precipitation of CSPG and TRwS equipped with the same octagonal vertical double fence shields(CSPGDF and TRwSDF)and single-Alter shields(CSPG_(s)and TRwSs)were close,while the precipitation of Tretyakov-shielded T200B was notably higher than that of CSPG_(s)and TRwSs.The average differences in annual and daily precipitation between CSPGDF and TRwSDF from 2017 to 2021 were 12.9 mm and 0.10 mm,respectively.The daily precipitation difference between CSPG_(s)and TRwSs from April 2019–December 2021 was 0.10 mm,while the differences between T200Bs and CSPG_(s)and TRwSs was 0.28 mm and 0.38 mm,respectively.The wind shield performance of Alter and Tretyakov was not much different at Hulu-1 site with low wind speed,thus the measurement principle of T200Bs was the primary cause of the high observations.Taking the corrected CSPGDF measurement as the standard,the dynamic loss of CSPG_(s)was 17.6%,while that of CSPGUn was 55.6%,indicating that the single-Alter shield could effectively reduce the impact of wind on precipitation measurement.Considering the comparison results and the price difference of the instruments,it was recommended to use a single-Alter shielded TRwS gauge for precipitation observation in high-altitude mountains.

Bifurcation of Periodic Orbits and Chaos in Duffing Equation

与第五非线性恢复的力量未击中方程，一个外部强迫；阶段移动被调查。为主要回声的存在的条件，秒顺序，第三顺序的次谐波， morder 次谐波；混乱被使用平均秒的方法给， Melnikov 方法；分叉理论。数字模拟包括分叉图，分叉表面，阶段肖像，不是仅仅表演有理论分析的坚固性，而且展览新动态行为。我们显示出混乱的发作，突然消失到时期轨道的混乱，一个乐队；双乐队混乱，从时期 1 的加倍时期的分叉， 2，；3 条轨道，时期窗户(period-2， 3；5 ) 在混乱区域。

Boron heteroatom-doped silicon-carbon peanut-like composites enables long life lithium-ion batteries

Carbon coated Si core–shell structures have been proposed to solve the adverse effects of Si-based anode.However,designing ideal core–shell architecture with excellent surface and interface properties is still a significant challenge.Herein,a novel peanut-like structure of B-doped silicon/carbon nanoparticle(Si@B-C)synthe-sized by sol–gel process and subsequent thermal reduction is reported.The peanut-like Si@B-C electrode demon-strates a superior cyclability of 534 mAh·g^(-1)after 1000 cycles at high current density of 1000 mA·g^(-1).The exceptional electrochemical performance is attributed to the boric acid-induced highly interconnected peanut-like structure and boron heteroatom framework could provide a continuous electron pathway to reduce the irreversible lithium ion loss during rapid cycling.This work provides insight into the development of the heteroatom-doped Si-based anodes with stable cycling performance for LIBs.

Bifurcations of Resonant Solutions and Chaos in Physical Pendulum Equation with Suspension Axis Vibrations

This paper is a continuation of ＂Complex Dynamics in Physical Pendulum Equation with Suspension Axis Vibrations＂[1].In this paper,we investigate the existence and the bifurcations of resonant solution for ω0：ω：Ω ≈ 1：1：n,1：2：n,1：3：n,2：1：n and 3：1：n by using second-order averaging method,give a criterion for the existence of resonant solution for ω0：ω：Ω ≈ 1：m：n by using Melnikov＇s method and verify the theoretical analysis by numerical simulations.By numerical simulation,we expose some other interesting dynamical behaviors including the entire invariant torus region,the cascade of invariant torus behaviors,the entire chaos region without periodic windows,chaotic region with complex periodic windows,the entire period-one orbits region;the jumping behaviors including invariant torus behaviors converting to period-one orbits,from chaos to invariant torus behaviors or from invariant torus behaviors to chaos,from period-one to chaos,from invariant torus behaviors to another invariant torus behaviors;the interior crisis;and the different nice invariant torus attractors and chaotic attractors.The numerical results show the difference of dynamical behaviors for the physical pendulum equation with suspension axis vibrations between the cases under the three frequencies resonant condition and under the periodic/quasi-periodic perturbations.It exhibits many invariant torus behaviors under the resonant conditions.We find a lot of chaotic behaviors which are different from those under the periodic/quasi-periodic perturbations.However,we did not find the cascades of period-doubling bifurcation.

Genetic optimization of ladle scheduling in empty-ladle operation stage based on temperature drop control

To optimize ladle scheduling in the empty-ladle operation stage of steel plants,a mathematical scheduling model was established for the empty-ladle operation stage,taking the minimum total waiting time in the empty-ladle operation stage as the optimization goal and setting the equipment assignment uniqueness as the key constraint.An improved genetic algorithm was designed to calculate the mathematical scheduling model.In the operation of the genetic algorithm,the strategy of"ladle temperature drop control"was adopted to solve the problem of equipment conflicts and reduce unreasonable ladle temperature drops to enhance"red-ladle"utilization.Five main production modes operating at 95%capacity in a Chinese steel plant were simulated using the genetic optimization model.The results showed that the genetic optimization model could improve the efficiency of ladle operation and reduce the total waiting time in the empty-ladle operation stage by 868–1147 min.

Multiscale architectures boosting thermoelectric performance of copper sulfide compound

Owing to their high performance and earth abundance,copper sulfides(Cu_(2-x)S)have attracted wide attention as a promising medium-temperature thermoelectric material.Nanostructure and grain-boundary engineering are explored to tune the electrical transport and phonon scattering of Cu_(2-x)S based on the liquid-like copper ion.Here multiscale architecture-engineered Cu_(2-x)S are fabricated by a room-temperature wet chemical synthesis combining mechanical mixing and spark plasma sintering.The observed electrical conductivity in the multiscale architecture-engineered Cu_(2-x)S is four times as much as that of the Cu_(2-x)S sample at 800 K,which is attributed to the potential energy filtering effect at the new grain boundaries.Moreover,the multiscale architecture in the sintered Cu_(2-x)S increases phonon scattering and results in a reduced lattice thermal conductivity of 0.2 W·m^(-1)·K^(-1) and figure of merit(zT)of 1.0 at 800 K.Such a zT value is one of the record values in copper sulfide produced by chemical synthesis.These results suggest that the introduction of nanostructure and formation of new interface are effective strategies for the enhancement of thermoelectric material properties.

Bifurcations and Chaos in Duffng Equation with Damping and External Excitations

Duffing equation with damping and external excitations is investigated. By using Melnikov method and bifurcation theory, the criterions of existence of chaos under periodic perturbations are obtained. By using second-order averaging method, the criterions of existence of chaos in averaged system under quasi-periodic perturbations for Ω = nω ＋ εσ, n = 2,4,6 （where σ is not rational to ω） are investigated. However, the criterions of existence of chaos for n = 1, 3, 5, 7 - 20 can not be given. The numerical simulations verify the theoretical analysis, show the occurrence of chaos in the averaged system and original system under quasi- periodic perturbation for n = 1, 2, 3, 5, and expose some new complex dynamical behaviors which can not be given by theoretical analysis. In particular, the dynamical behaviors under quasi-periodic perturbations are different from that under periodic perturbations, and the period-doubling bifurcations to chaos has not been found under quasi-periodic perturbations.