Polymers grafted from solid surface are being extensively studied with a range of objectives.The most popular living/controlled polymerization used in polymers grafted from solid surfaces is the surface-initiated atom...Polymers grafted from solid surface are being extensively studied with a range of objectives.The most popular living/controlled polymerization used in polymers grafted from solid surfaces is the surface-initiated atom transfer radical polymerization（SI-ATRP）[1,2].An attractive feature of atom transfer radical polymerization（ATRP） is to simultaneously grow chains from multifunctional surface.Thus the grafted polymer with well-defined structures could be designed and controlled.ATRP has proven to be a powerful tool to synthesize homopolymers and copolymers,under easily accessible experimental conditions[3-7].Furthermore it is useful for the functionalization of material surfaces by grafting certain polymers.展开更多
基金Supported by the National Natural Science Foundation of China（Nos.51203015, 51243003）.
文摘Polymers grafted from solid surface are being extensively studied with a range of objectives.The most popular living/controlled polymerization used in polymers grafted from solid surfaces is the surface-initiated atom transfer radical polymerization（SI-ATRP）[1,2].An attractive feature of atom transfer radical polymerization（ATRP） is to simultaneously grow chains from multifunctional surface.Thus the grafted polymer with well-defined structures could be designed and controlled.ATRP has proven to be a powerful tool to synthesize homopolymers and copolymers,under easily accessible experimental conditions[3-7].Furthermore it is useful for the functionalization of material surfaces by grafting certain polymers.
