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凹土基农药微胶囊的制备及缓释性能研究 被引量:3
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作者 孙国藩 吴东鑫 +6 位作者 代婉婉 肖塍 陈延凯 蔡鹏 金叶玲 陈静 丁师杰 《非金属矿》 CAS CSCD 北大核心 2019年第1期7-10,共4页
以凹凸棒石黏土作为乳化剂,以凹土在水中的分散液作为水相,与含有单体N,N-二乙基氨基甲基丙烯酸乙酯(DEAEMA)、少量甲基丙烯酸甲酯(MMA)单体、交联剂乙二醇二甲基丙烯酸酯(EGDMA)、引发剂2,2-偶氮二异丁腈(AIBN)及甲苯的混合油相乳化,... 以凹凸棒石黏土作为乳化剂,以凹土在水中的分散液作为水相,与含有单体N,N-二乙基氨基甲基丙烯酸乙酯(DEAEMA)、少量甲基丙烯酸甲酯(MMA)单体、交联剂乙二醇二甲基丙烯酸酯(EGDMA)、引发剂2,2-偶氮二异丁腈(AIBN)及甲苯的混合油相乳化,采用高速匀浆机混合打浆制得稳定Pickering乳液,并以此凹土稳定的Pickering乳液为模板聚合制备球形复合微胶囊。采用光学显微镜(OM)对乳液粒径进行分析,利用偏光显微镜(POM)、电子显微镜(SEM)和红外光谱(FTIR)等技术对聚合所得的复合微球进行形貌及结构的表征,研究了包覆模型化合物罗丹明B的复合微球在不同p H值缓冲液中的缓释行为,比较了包覆农药高氯菊酯的复合微球在不同体积分数乙醇的乙醇-水溶液中的缓释性能。 展开更多
关键词 凹凸棒石黏土 Pickering乳液 复合微胶囊 缓释性能
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Relationship between the geochemistry of organic matter and the generation of palygorskite in Jiangsu-Anhui border and Gansu Province,China 被引量:1
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作者 CHEN Chuanping XU Yaping +2 位作者 WANG Xiaotian jin yeling CHEN jing 《Chinese Journal Of Geochemistry》 EI CAS 2012年第3期340-346,共7页
Soluble organic matter had been separated from several palygorskite and bentonite samples in the Ji-angsu-Anhui border area(across Jiangsu Province and Anhui Province) and Linze County in Gansu Province of China and w... Soluble organic matter had been separated from several palygorskite and bentonite samples in the Ji-angsu-Anhui border area(across Jiangsu Province and Anhui Province) and Linze County in Gansu Province of China and was analyzed with the techniques and methods of organic geochemistry.The composition and distribution of hydrocarbons were analyzed by gas chromatography(GC).Organic stable carbon isotopic ratios(δ13C) in typical samples were determined.The abundance of soluble organic matter in all clay samples analyzed was low.In Ji-angsu-Anhui samples,the preservation states of organic matter are different;hydrocarbons in organic matter have some features of aquatic plankton but are short of the input of terrigenous higher plants;organic δ13C in a palygor-skite of Yongxiaoshan in Xuyi County,Jiangsu Province,is-6.72‰.These features may be typical of a sedimentary environment of closed or semi-closed and relatively isolated different waters near coast or seashore.On the contrary,in samples from Gansu,the preservation states of organic matter are good;the GC graphs of hydrocarbons show that the precursors of the organic matter are from a mixed source of aquatic organisms and land-sourced higher plants;organic δ13C of a palygorskite from Yangtai of Gansu is-15.62‰.It indicated that the sedimentary environment may be an inland salty lake.Preliminary results suggest that palygorskite minerals in the Jiangsu-Anhui area may be evolved from rapidly accumulated fine material or volcanic ash,but clays in Gansu Province may be transformed from terrigenous inorganic clastic components carried to the lake through river and then deposited.The generation process of the samples studied in the paper seems to be related to salty water. 展开更多
关键词 有机地球化学 有机物质 苏皖地区 甘肃省 坡缕石 中国 特征和 有机质丰度
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