In this work, nitrogen doped clews-like carbon materials were successfully fabricated through hydrothermal polymerization method, followed by post treatment that integrated the carbonization,activation and post-nitrog...In this work, nitrogen doped clews-like carbon materials were successfully fabricated through hydrothermal polymerization method, followed by post treatment that integrated the carbonization,activation and post-nitrogen doping into one process. This preparation method can form particular hierarchical porous structure without using any sacrificial templates. The experimental results show that the nitrogen doped clews-like hierarchical porous carbon materials possess a relatively high specific surface area of 815 m^2/g with the nitrogen content of 10.58 at%. The electrochemical properties show that the resulting sample delivers 258 F/g at a 0.5 A/g and excellent capacity retention of 79% at 20 A/g. After conducting 10,000 charge-discharge cycles at 10 A/g, the capacitance retention of 98.3% is achieved.These intriguing results demonstrate that the obtained nitrogen doped clews-like carbon materials will be promising electrode materials for supercapacitor and other energy storage devices.展开更多
Solution process is a key technique for the manufacture of large-area and low-cost semiconducting devices and,thus, attracts a lot of attention from both academia and industry. Herein, we realized solution-processed l...Solution process is a key technique for the manufacture of large-area and low-cost semiconducting devices and,thus, attracts a lot of attention from both academia and industry. Herein, we realized solution-processed lightemitting diodes(excluding a cathode) based on aggregation-induced emission(AIE) molecules of tetraphenylethylene-4Cl(TPE-4Cl) and cadimum-free semiconductor nanocrystals(NCs) for the first time. By mixing Cu-In-Zn-S NCs and TPE-4Cl as an emissive layer, a new type of environmentally friendly white-light-emitting diodes(WLEDs) was prepared through a solution-processed technique. After systematical optimization of the asprepared WLEDs, the corresponding color rendering index can reach up to 87 with a maximum luminance of262 cd/m2. This study may pave a new road to realize AIE-based WLEDs through a solution-processed technique.展开更多
基金supported by the National Natural Science Foundation of China(No. 51802122)the Natural Science Fund of Hubei Province(No.2017CFB155)+4 种基金China Scholarship Council (No. 201808420401)Scientific Research Plan Project of Hubei Education Department(No. B2017269)Scientific Research Initial funding for the Advanced Talent of Jianghan University (No. 1009-06810001)Opening Project of Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, Jianghan University(Nos. JDGD-201702,JDGD-201811)Hubei Provincial Department of Education for the "Chutian Scholar" program
文摘In this work, nitrogen doped clews-like carbon materials were successfully fabricated through hydrothermal polymerization method, followed by post treatment that integrated the carbonization,activation and post-nitrogen doping into one process. This preparation method can form particular hierarchical porous structure without using any sacrificial templates. The experimental results show that the nitrogen doped clews-like hierarchical porous carbon materials possess a relatively high specific surface area of 815 m^2/g with the nitrogen content of 10.58 at%. The electrochemical properties show that the resulting sample delivers 258 F/g at a 0.5 A/g and excellent capacity retention of 79% at 20 A/g. After conducting 10,000 charge-discharge cycles at 10 A/g, the capacitance retention of 98.3% is achieved.These intriguing results demonstrate that the obtained nitrogen doped clews-like carbon materials will be promising electrode materials for supercapacitor and other energy storage devices.
基金National Natural Science Foundation of China(61735004,61974009)。
文摘Solution process is a key technique for the manufacture of large-area and low-cost semiconducting devices and,thus, attracts a lot of attention from both academia and industry. Herein, we realized solution-processed lightemitting diodes(excluding a cathode) based on aggregation-induced emission(AIE) molecules of tetraphenylethylene-4Cl(TPE-4Cl) and cadimum-free semiconductor nanocrystals(NCs) for the first time. By mixing Cu-In-Zn-S NCs and TPE-4Cl as an emissive layer, a new type of environmentally friendly white-light-emitting diodes(WLEDs) was prepared through a solution-processed technique. After systematical optimization of the asprepared WLEDs, the corresponding color rendering index can reach up to 87 with a maximum luminance of262 cd/m2. This study may pave a new road to realize AIE-based WLEDs through a solution-processed technique.
