In recent years, graphene oxide(GO), prepared by the modified Hummers’ method, and its derivatives have become a focus of research owing to their outstanding physical and chemical properties and low cost. Drawing ins...In recent years, graphene oxide(GO), prepared by the modified Hummers’ method, and its derivatives have become a focus of research owing to their outstanding physical and chemical properties and low cost. Drawing inspiration from the mussel protein,a facile and environmentally-friendly method was employed to fabricate superhydrophobic/superoleophilic reduced graphene oxide(rGO) derivative. The preparation comprises two steps: coating GO nanosheets with polydopamine(PDA) and subsequent reaction with 1H,1H,2H,2H-perfluorodecanethiol. Due to the excellent adhesive ability of PDA, the resulting f PDA modified rGO nanosheets(rGO-f PDA) were firmly immobilized onto polyurethane(PU) sponge skeleton by a simple drop-coating method. The as-prepared rGO-f PDA functionalized sponge exhibited superhydrophobic behavior with a water contact angle of 162°±2°, high organic adsorption capacity, recyclability and stable oil/water separation behavior under different acidic/alkaline conditions. Due to its facile fabrication technique and outstanding properties, the superhydrophobic-superoleophilic PU-rGOf PDA sponge holds great promise as an oil adsorbent for cleaning up large-scale pollution of oil and organic solvents, and dehydrating crude oil.展开更多
The Low Earth Orbit(LEO)satellites can be used to efectively speed up Precise Point Positioning(PPP)convergence.In this study,180 LEO satellites with a global distribution are simulated to evaluate their contribution ...The Low Earth Orbit(LEO)satellites can be used to efectively speed up Precise Point Positioning(PPP)convergence.In this study,180 LEO satellites with a global distribution are simulated to evaluate their contribution to the PPP convergence.LEO satellites can give more redundant observations and improve satellite geometric distributions,particularly for a single Global Navigation Satellite System(GNSS).The convergence speed of the PPP foat solution using the Global Positioning System(GPS,G)or BeiDou Navigation Satellite System(BDS,C)single system as well as the G/C/Galileo navigation satellite system(Galileo,E)/GLObal NAvigation Satellite System(GLONASS,R)combined system with LEO satellites added is improved by 90.0%,91.0%,and 90.7%,respectively,with respect to the system without LEO satellites added.We introduced LEO observations to assist GNSS in PPP-AR(Ambiguity Resolution)and PPP-RTK(Real Time Kinematic).The success fx rate of a single system is signifcantly improved,and the Time-To-First-Fix(TTFF)of G and G/C/E is reduced by 86.4%and 82.8%,respectively,for the PPP-AR solution.We analyzed the positioning performance of LEO satellite assisted G/C/E PPP-RTK in the reference networks of diferent scales,namely diferent atmospheric delay interpolation accuracies.The success fx rate of the G/C/E combined system is improved from 86.8 to 94.9%,and the TTFF is reduced by 36.8%,with the addition of LEO satellites in the 57 km reference network.In the 110 km reference network,the success fx rate of the G/C/E combined system is improved from 64.0 to 88.6%,and the TTFF is reduced by 32.1%.GNSS PPP-RTK with adding the LEO satellites in the reference networks of diferent scales shows obvious improvement because the atmospheric correlation decreases with increasing distance from the reference networks.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.51701240&41206063)Key Research and Development Program of Shandong Province(Grant No.2017GGX20123)Fundamental Research Funds for the Central Universities(Grant Nos.19CX05001A,16CX05011A&17CX02063)
文摘In recent years, graphene oxide(GO), prepared by the modified Hummers’ method, and its derivatives have become a focus of research owing to their outstanding physical and chemical properties and low cost. Drawing inspiration from the mussel protein,a facile and environmentally-friendly method was employed to fabricate superhydrophobic/superoleophilic reduced graphene oxide(rGO) derivative. The preparation comprises two steps: coating GO nanosheets with polydopamine(PDA) and subsequent reaction with 1H,1H,2H,2H-perfluorodecanethiol. Due to the excellent adhesive ability of PDA, the resulting f PDA modified rGO nanosheets(rGO-f PDA) were firmly immobilized onto polyurethane(PU) sponge skeleton by a simple drop-coating method. The as-prepared rGO-f PDA functionalized sponge exhibited superhydrophobic behavior with a water contact angle of 162°±2°, high organic adsorption capacity, recyclability and stable oil/water separation behavior under different acidic/alkaline conditions. Due to its facile fabrication technique and outstanding properties, the superhydrophobic-superoleophilic PU-rGOf PDA sponge holds great promise as an oil adsorbent for cleaning up large-scale pollution of oil and organic solvents, and dehydrating crude oil.
基金the program of National Natural Science Foundation of China(Grant Nos.41974032,42274019).
文摘The Low Earth Orbit(LEO)satellites can be used to efectively speed up Precise Point Positioning(PPP)convergence.In this study,180 LEO satellites with a global distribution are simulated to evaluate their contribution to the PPP convergence.LEO satellites can give more redundant observations and improve satellite geometric distributions,particularly for a single Global Navigation Satellite System(GNSS).The convergence speed of the PPP foat solution using the Global Positioning System(GPS,G)or BeiDou Navigation Satellite System(BDS,C)single system as well as the G/C/Galileo navigation satellite system(Galileo,E)/GLObal NAvigation Satellite System(GLONASS,R)combined system with LEO satellites added is improved by 90.0%,91.0%,and 90.7%,respectively,with respect to the system without LEO satellites added.We introduced LEO observations to assist GNSS in PPP-AR(Ambiguity Resolution)and PPP-RTK(Real Time Kinematic).The success fx rate of a single system is signifcantly improved,and the Time-To-First-Fix(TTFF)of G and G/C/E is reduced by 86.4%and 82.8%,respectively,for the PPP-AR solution.We analyzed the positioning performance of LEO satellite assisted G/C/E PPP-RTK in the reference networks of diferent scales,namely diferent atmospheric delay interpolation accuracies.The success fx rate of the G/C/E combined system is improved from 86.8 to 94.9%,and the TTFF is reduced by 36.8%,with the addition of LEO satellites in the 57 km reference network.In the 110 km reference network,the success fx rate of the G/C/E combined system is improved from 64.0 to 88.6%,and the TTFF is reduced by 32.1%.GNSS PPP-RTK with adding the LEO satellites in the reference networks of diferent scales shows obvious improvement because the atmospheric correlation decreases with increasing distance from the reference networks.
