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金属-有机分子笼在g-C3N4半导体上的固定以提高光催化产氢性能(英文)
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作者 王原溥 刘靓 +4 位作者 吴东俊 郭靖 石建英 刘军民 苏成勇 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第8期1198-1204,共7页
可见光驱动的光催化水制氢是一种太阳能转化策略,各种异质结半导体和均相分子器件在光催化领域取得了很大的进展.本课题组曾开发了一种含多个吸光中心和催化中心的金属-有机自组装分子笼Pd6(RuL3)8(BF4)28(MOC-16),并研究了其光催化分... 可见光驱动的光催化水制氢是一种太阳能转化策略,各种异质结半导体和均相分子器件在光催化领域取得了很大的进展.本课题组曾开发了一种含多个吸光中心和催化中心的金属-有机自组装分子笼Pd6(RuL3)8(BF4)28(MOC-16),并研究了其光催化分解水产氢性能.尽管该笼子定向电子通过多个独立的通道转移实现了高效制氢,但仍存在均相催化剂的典型缺点,即在光催化过程中,笼子分解后钯纳米颗粒团聚致使催化剂失活.而二维片层结构的石墨相氮化碳(g-C3N4)具有大量的共轭π电子和终止边缘以构成氢键,是构建杂化材料的理想基底.在此基础上,本文采用简单的制备方法将MOC-16分立固定在g-C3N4基质上,得到异质体系MOC-16/g-C3N4,相比其均相组分,该新型催化剂具有更优良的光催化分解水产氢性能.本文设计了空白的催化产氢实验,比较了MOC-16中各部分及分子笼在催化产氢体系中的作用,并采用X射线衍射(XRD),傅里叶红外光谱,透射电镜,紫外可见光谱(UV-Vis),瞬态光电流响应(i-t)、X射线光电子能谱(XPS)等手段研究了MOC-16和g-C3N4之间的相互作用和杂化材料MOC-16/g-C3N4的光催化产氢机理.10 wt% MOC-16/g-C3N4表现出最高的产氢速率2021 μmol g^–1 h^–1,并优于空白对照组的产氢效果,循环15 h时的TON(Pd)为517, TOF(Pd)值约36 h^–1,与MOC-16均相催化剂相比,催化剂MOC-16/g-C3N4在产氢效率和稳定性上有明显提升.形貌结构表征显示, MOC-16不与g-C3N4形成新的共价键,也不改变g-C3N4原有形貌结构, MOC-16以配合物形式均匀分散在g-C3N4基底材料上. UV-Vis结果表明, MOC-16/g-C3N4的紫外-可见吸收峰结合了两种组分的吸收峰,杂化材料的可见光区的吸收峰延伸至700 nm左右.随着MOC-16负载量增大,杂化材料MOC-16/g-C3N4的吸光范围越大. i-t结果进一步表明, MOC-16和g-C3N4之间存在有效的电子转移. XPS结果显示,杂化前后, MOC-16中Pd价态未发生改变,但峰位置发生位移, Pd 3d的电子结合能分别从343.1和338.0移动到342.6和337.3 eV,进一步表明杂化后MOC-16和g-C3N4间存在相互作用.然而经过三轮连续循环产氢后,部分二价钯被还原为零价,表明固定在g-C3N4表面的MOC-16在光催化过程中光生电子不断流向Pd,电子消耗缓慢导致Pd-N键的断裂.我们提出了MOC-16/C3N4复合光催化剂可能的光催化产氢机制. MOC-16的LUMO和HOMO能级分别为–0.95和1.55V (vs.NHE), g-C3N4的导带在–1.09至–1.3 V,价带在1.53至1.4 V之间,所以光生电子从g-C3N4转移到MOC-16在热力学上是可行的.光生电子转移到MOC-16分子的Pd上, Pd作为助催化剂为H2的产生提供活性位点,而TEOA作为牺牲试剂,则在g-C3N4表面消耗光生空穴. 展开更多
关键词 g-C3N4 金属-有机笼 光催化产氢 可见光 稳定性
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Evaluating Reference Crop Evapotranspiration (<i>ETo</i>) in the Centre of Guanzhong Basin—Case of Xingping &Wugong, Shaanxi, China
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作者 Hussein I. Ahmed junmin liu 《Engineering(科研)》 2013年第5期459-468,共10页
In this paper, the Penman-Monteith method was applied to evaluate the reference crop evapotranspiration. A reliable estimation of the reference evapotranspiration (ETo) is of critical importance and required accurate ... In this paper, the Penman-Monteith method was applied to evaluate the reference crop evapotranspiration. A reliable estimation of the reference evapotranspiration (ETo) is of critical importance and required accurate estimates to close the water balance. The aim of this paper is estimating the reference evapotranspiration (ETo) as preliminary to use for groundwater modeling in the area. Based on FAO-Penman-Monteith method, ETo calculator software was applied. Meteorological data within this study were obtained from two gauges stations (Xing ping and Wu gong) and available literatures. The results indicated that the values of ETo for a period (1981-2009)—29 years—in two stations approximately the same. Specifically, is ranged between 0.4 - 6.9 mm /day, 0.4 - 6.7 mm/day and the average value is 2.6 mm/ day, 2.6 mm/day in Xing ping and Wu gong respectively. In addition, the maximum values were occurred in summer season (May, June and July). The result also found that the correlation coefficient ≈ 1. Moreover, “ETo” was increasing by recent years. The reference crop evapotranspiration for some crops were calculated. 展开更多
关键词 Reference EVAPOTRANSPIRATION Part of Baoyang Irrigation Area METEOROLOGICAL Data FAO
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Orbital angular momentum mode logical operation using optical diffractive neural network 被引量:8
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作者 PEIPEI WANG WENJIE XIONG +7 位作者 ZEBIN HUANG YANLIANG HE ZHIQIANG XIE junmin liu HUAPENG YE YING LI DIANYUAN FAN SHUQING CHEN 《Photonics Research》 SCIE EI CAS CSCD 2021年第10期2116-2124,共9页
Optical logical operations demonstrate the key role of optical digital computing,which can perform general-purpose calculations and possess fast processing speed,low crosstalk,and high throughput.The logic states usua... Optical logical operations demonstrate the key role of optical digital computing,which can perform general-purpose calculations and possess fast processing speed,low crosstalk,and high throughput.The logic states usually refer to linear momentums that are distinguished by intensity distributions,which blur the discrimination boundary and limit its sustainable applications.Here,we introduce orbital angular momentum(OAM)mode logical operations performed by optical diffractive neural networks(ODNNs).Using the OAM mode as a logic state not only can improve the parallel processing ability but also enhance the logic distinction and robustness of logical gates owing to the mode infinity and orthogonality.ODNN combining scalar diffraction theory and deep learning technology is designed to independently manipulate the mode and spatial position of multiple OAM modes,which allows for complex multilight modulation functions to respond to logic inputs.We show that few-layer ODNNs successfully implement the logical operations of AND,OR,NOT,NAND,and NOR in simulations.The logic units of XNOR and XOR are obtained by cascading the basic logical gates of AND,OR,and NOT,which can further constitute logical half-adder gates.Our demonstrations may provide a new avenue for optical logical operations and are expected to promote the practical application of optical digital computing. 展开更多
关键词 NETWORK MODE MOMENTUM
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Switchable dual-wavelength Q-switched fiber laser using multilayer black phosphorus as a saturable absorber 被引量:8
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作者 junmin liu Yu CHEN +3 位作者 YING LI HAN ZHANG SHUIQIN ZHENG SHIXIANG Xu 《Photonics Research》 SCIE EI 2018年第3期198-203,共6页
Black phosphorus(BP), with thickness-dependent direct energy bandgaps(0.3–2 eV), shows an enhanced nonlinear optical response at near-and mid-infrared wavelengths. In this paper, we present experimentally multilayer ... Black phosphorus(BP), with thickness-dependent direct energy bandgaps(0.3–2 eV), shows an enhanced nonlinear optical response at near-and mid-infrared wavelengths. In this paper, we present experimentally multilayer BP flakes coated on microfiber(BCM) as a saturable absorber with a modulation depth of 16% and a saturable intensity of 6.8 MW∕cm^2. After inserting BCM into an Er-doped fiber ring laser, a stable dual-wavelength Q-switched state with central wavelengths of 1542.4 nm and 1543.2 nm(with wavelength spacing as small as 0.8 nm) is obtained with the aid of two cascaded fiber Bragg gratings as a coarse wavelength selector.Moreover, single-wavelength Q-switched operation at 1542.4 nm or 1543.2 nm is also realized, which can be switched between the two wavelengths flexibly just by adjusting the intracavity birefringence. These results suggest that BP combined with the cascaded fiber gratings can provide a simple and feasible candidate for a multiwavelength fiber laser. Our fiber laser may have potential applications in terahertz generation, laser radar,and so on. 展开更多
关键词 length Switchable dual-wavelength Q-switched fiber laser using multilayer black phosphorus as a saturable absorber EDF
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Controllable photonic spin Hall effect with phase function construction 被引量:3
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作者 YANLIANG HE ZHIQIANG XIE +7 位作者 BO YANG XUEYU CHEN junmin liu HUAPENG YE XINXING ZHOU YING LI SHUQING CHEN DIANYUAN FAN 《Photonics Research》 SCIE EI CSCD 2020年第6期963-971,共9页
Photonic spin Hall efect(SHE)provides new opportunities for achieving spin-based photonics applications.However,flexibly manipulating the spin-dependent sltting(SDS)of photonic SHE and imposing extra phase modulation ... Photonic spin Hall efect(SHE)provides new opportunities for achieving spin-based photonics applications.However,flexibly manipulating the spin-dependent sltting(SDS)of photonic SHE and imposing extra phase modulation on the two spin components are always a challenge.Here,a controllable SHE mechanism based on phase function construction is reported.It is conduded that the phases with specific functional structures performing a coordinate translation are equivalent to integrating a gradient phase to the original phases.Hence,the original phase can be used for independent phase modulation,and the gradient phase originating from the co-ordinate translation is capable of manipulating the SDS.A metasurface with Pancharatnam-Berry phase that can impose conjugate phases to the two spin components of light is fabricated to verify this mechanism.By shifing the light position,the SDS is continuously manipulated in the visible region,which is successfully used for detecting the polarization llipticity.The extra phase modulation is also performed with the original phase and thus enables measuring singular beams.It is anticipated that the controllable SHE manipulation method may open new avenues in the fields of spin photonics,optical sensing,optical communications,etc. 展开更多
关键词 mechanism. PHASE FUNCTION
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Undulated 2D Covalent Organic Frameworks Based on Bowl-Shaped Cyclotricatechylene 被引量:2
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作者 Jingru Zhen Sanyuan Ding +4 位作者 Wei Wang junmin liu Junliang Sun Zhitang Huang Qiyu Zheng 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2016年第8期783-787,共5页
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Conjugated Porous Networks Based on Cyclotriveratrylene Building Block for Hydrogen Adsorption
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作者 Xiaona Han Lei Li +2 位作者 Zhitang Huang junmin liu Qiyu Zheng 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2013年第5期617-623,共7页
Macrocyclic CTV-Br3 经由联合生产僵硬多孔的材料 CTV-CMP-1 和 CTV-CMP-2 的反应的铃木和 Sonogashira-Hagihara 与线性 benzene-1,4-diboronic 酸和 1,4-diethynylbenzene 反应了。多孔的材料有好热、化学的稳定性。CTV-CMP-1 和 CTV... Macrocyclic CTV-Br3 经由联合生产僵硬多孔的材料 CTV-CMP-1 和 CTV-CMP-2 的反应的铃木和 Sonogashira-Hagihara 与线性 benzene-1,4-diboronic 酸和 1,4-diethynylbenzene 反应了。多孔的材料有好热、化学的稳定性。CTV-CMP-1 和 CTV-CMP-2 的 Brunauer-Emmet-Teller 特定的表面区域是 314 和 218 展开更多
关键词 氢吸附 多孔网络 积木 氢气 共轭 多孔材料 偶联反应 大环化合物
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Neural network-based surrogate model for inverse design of metasurfaces
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作者 GUOQING JING PEIPEI WANG +7 位作者 HAISHENG WU JIANJUN REN ZHIQIANG XIE junmin liu HUAPENG YE YING LI DIANYUAN FAN SHUQING CHEN 《Photonics Research》 SCIE EI CAS CSCD 2022年第6期1462-1471,共10页
Metasurfaces composed of spatially arranged ultrathin subwavelength elements are promising photonic devices for manipulating optical wavefronts,with potential applications in holography,metalens,and multiplexing commu... Metasurfaces composed of spatially arranged ultrathin subwavelength elements are promising photonic devices for manipulating optical wavefronts,with potential applications in holography,metalens,and multiplexing communications.Finding microstructures that meet light modulation requirements is always a challenge in designing metasurfaces,where parameter sweep,gradient-based inverse design,and topology optimization are the most commonly used design methods in which the massive electromagnetic iterations require the design computational cost and are sometimes prohibitive.Herein,we propose a fast inverse design method that combines a physicsbased neural network surrogate model(NNSM)with an optimization algorithm.The NNSM,which can generate an accurate electromagnetic response from the geometric topologies of the meta-atoms,is constructed for electromagnetic iterations,and the optimization algorithm is used to search for the on-demand meta-atoms from the phase library established by the NNSM to realize an inverse design.This method addresses two important problems in metasurface design:fast and accurate electromagnetic wave phase prediction and inverse design through a single phase-shift value.As a proof-of-concept,we designed an orbital angular momentum(de)multiplexer based on a phase-type metasurface,and 200 Gbit/s quadrature-phase shift-keying signals were successfully transmitted with a bit error rate approaching 1.67×10^(-6).Because the design is mainly based on an optimization algorithm,it can address the“one-to-many”inverse problem in other micro/nano devices such as integrated photonic circuits,waveguides,and nano-antennas. 展开更多
关键词 NETWORK INVERSE OPTIMIZATION
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