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Controlling a lithium surface with an alkyl halide nucleophile exchange 被引量:1
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作者 Jung-Hun Lee Thuy Hoai Linh Vuong +2 位作者 Soo Min Hwang jae-hun kim Young-Jun kim 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第11期617-626,I0015,共11页
Despite its high theoretical energy density, lithium metal faces huge challenges in its implementation as an anode for Li secondary batteries because of its uncontrollable dendritic growth and large volume change duri... Despite its high theoretical energy density, lithium metal faces huge challenges in its implementation as an anode for Li secondary batteries because of its uncontrollable dendritic growth and large volume change during plating/stripping processes. These geometric changes cause degradation in a cell’s cycle life and performance and can lead to short-circuits and explosions. Here, we report a new approach to producing a LiF-rich phase on the lithium anode surface by employing a “bi-phase” separator. We fabricated it by coating polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) onto a cellulose separator. The coverage of coating was adjusted by varying its concentration in the coating solution. The combination of cellulose and PVDF-HFP produced a LiF-rich solid-electrolyte interphase layer on the Li metal surface via an alkyl halide nucleophile exchange in contact with the bi-phase separator during plating. Symmetric cell tests show that the bi-phase separator extends the cycle life by more than 300 h, with overpotentials of less than 100 mV under plating/stripping at 2 mA cm^(−2) for a capacity of 2 mAh cm^(−2). The formation mechanism of the LiF-rich phase is suggested from spectroscopic analyses. 展开更多
关键词 Li metal anode PVDF-HFP CELLULOSE LIF Phase inversion
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Computational design of Mg alloys with minimal galvanic corrosion
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作者 Krishnamohan Thekkepat Hyung-Seop Han +7 位作者 Ji-Won Choi Seung-Cheol Lee Eul Sik Yoon Guangzhe Li Hyun-Kwang Seok Yu-Chan kim jae-hun kim Pil-Ryung Cha 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2022年第7期1972-1980,共9页
Formation of galvanic cells between constituent phases is largely responsible for corrosion in Mg-based alloys.We develop a methodology to calculate the electrochemical potentials of intermetallic compounds and alloys... Formation of galvanic cells between constituent phases is largely responsible for corrosion in Mg-based alloys.We develop a methodology to calculate the electrochemical potentials of intermetallic compounds and alloys using a simple model based on the Born-Haber cycle.Calculated electrochemical potentials are used to predict and control the formation of galvanic cells and minimize corrosion.We demonstrate the applicability of our model by minimizing galvanic corrosion in Mg-3wt%Sr-x Zn alloy by tailoring the Zn composition.The methodology proposed in this work is applicable for any general alloy system and will facilitate efficient design of corrosion resistant alloys. 展开更多
关键词 Galvanic corrosion FIRST-PRINCIPLES Cluster expansion THERMODYNAMICS MODELING Magnesium alloys
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Water stable and matrix addressable OLED fiber textiles for wearable displays with large emission area 被引量:2
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作者 Hayoung Song Young Jin Song +5 位作者 Jinwook Hong Ki Suk Kang Sera Yu Ha-Eun Cho jae-hun kim Sung-Min Lee 《npj Flexible Electronics》 SCIE 2022年第1期664-671,共8页
Organic light-emitting diode(OLED)fibers with favorable electroluminescence properties and interconnectable pixel configurations have represented the potential for wearable electronic textile displays.Nevertheless,the... Organic light-emitting diode(OLED)fibers with favorable electroluminescence properties and interconnectable pixel configurations have represented the potential for wearable electronic textile displays.Nevertheless,the current technology of OLED fiber-based textile displays still leaves to be desired due to several challenges,including limited emission area and lack of encapsulation systems.Here we present a fibrous OLED textile display that can attain a large emission area and long-term stability by implementing addressable networks comprised of integrated phosphorescence OLED fibers and by designing multilayer encapsulations.The integrated fiber configuration offers decoupled functional fiber surfaces for an interconnectable 1-dimensional OLED pixel array and a data-addressing conductor.Tailored triadic metal/ultrathin oxide/polymer multilayer enables not only the oxygen/water permeation inhibition but also the controllable conductive channels of dielectric antifuses.Together with reliable bending stability,the long-term operation of OLED textiles in water manifests the feasibility of the present device concept toward water-resistant full-emitting-area fibrous textile displays. 展开更多
关键词 FIBER OLED wear
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