Both enantiomers R-1 and S-1 of a chiral C60 derivative were synthesized by the reactions of C60 with 1, 1'-bi-2-naphthol bis(azidoacetates) and characterized by FD-MS, fT-IR,1H NMR, 13C NMR, UV-VIS, CD spectra.
A diazafulleroid derivative with adjacent 5-6 junctions has been synthesized by the regioselective addition of 1,2-di(azidomethyl) benzene to [60]fullerene. Reaction of [60]fullerene with 1,4-di(azidomethyl) benzene i...A diazafulleroid derivative with adjacent 5-6 junctions has been synthesized by the regioselective addition of 1,2-di(azidomethyl) benzene to [60]fullerene. Reaction of [60]fullerene with 1,4-di(azidomethyl) benzene in refluxing chlorobenzene gave a copolymer.展开更多
文摘Both enantiomers R-1 and S-1 of a chiral C60 derivative were synthesized by the reactions of C60 with 1, 1'-bi-2-naphthol bis(azidoacetates) and characterized by FD-MS, fT-IR,1H NMR, 13C NMR, UV-VIS, CD spectra.
文摘A diazafulleroid derivative with adjacent 5-6 junctions has been synthesized by the regioselective addition of 1,2-di(azidomethyl) benzene to [60]fullerene. Reaction of [60]fullerene with 1,4-di(azidomethyl) benzene in refluxing chlorobenzene gave a copolymer.
