Recently,a study reported on the use of in situ electron paramagnetic resonance(EPR)spectroscopy to investigate two consecutive single-electron processes in polyimide and directly diagnose typical electrochemical reac...Recently,a study reported on the use of in situ electron paramagnetic resonance(EPR)spectroscopy to investigate two consecutive single-electron processes in polyimide and directly diagnose typical electrochemical reactions of carbonyl-based organic electrode in Li-ion batteries(LIBs).This research offers the important experimental clue for studying specific electron conversion routes of multi-electron transfer reactions in LIB materials[1].展开更多
Molecular qubits are promising as they can benefit from tailoring and versatile design of chemistry.It is essential to reduce the decoherence of molecular qubits caused by their interactions with the environment.Herei...Molecular qubits are promising as they can benefit from tailoring and versatile design of chemistry.It is essential to reduce the decoherence of molecular qubits caused by their interactions with the environment.Herein the dynamical decoupling(DD)technique is utilized to combat such decoherence.The coherence time for a transitionmetal complex(PPh_(4))_(2)[Cu(mnt)_(2)]is prolonged from 6.8μs to 1.4 ms.The ratio of the coherence time and the length ofπ/2 pulse,defined as the single qubit figure of merit(QM),reaches 1.4×10^(5),which is 40 times greater than what previously reported for this molecule.Our results show that molecular qubits,with milliseconds coherence time,are promising candidates for quantum information processing.展开更多
文摘Recently,a study reported on the use of in situ electron paramagnetic resonance(EPR)spectroscopy to investigate two consecutive single-electron processes in polyimide and directly diagnose typical electrochemical reactions of carbonyl-based organic electrode in Li-ion batteries(LIBs).This research offers the important experimental clue for studying specific electron conversion routes of multi-electron transfer reactions in LIB materials[1].
基金Supported by the National Key R&D Program of China(Grant Nos.2018YFA0306600 and 2016YFB0501603)the Chinese Academy of Sciences(Grant Nos.GJJSTD20170001,QYZDY-SSW-SLH004,and QYZDB-SSW-SLH005)+2 种基金Anhui Initiative in Quantum Information Technologies(Grant No.AHY050000)the Youth Innovation Promotion Association of Chinese Academy of Sciences for their supportthe support from Wuhan National High Magnetic Field Center(Grant No.2015KF06)。
文摘Molecular qubits are promising as they can benefit from tailoring and versatile design of chemistry.It is essential to reduce the decoherence of molecular qubits caused by their interactions with the environment.Herein the dynamical decoupling(DD)technique is utilized to combat such decoherence.The coherence time for a transitionmetal complex(PPh_(4))_(2)[Cu(mnt)_(2)]is prolonged from 6.8μs to 1.4 ms.The ratio of the coherence time and the length ofπ/2 pulse,defined as the single qubit figure of merit(QM),reaches 1.4×10^(5),which is 40 times greater than what previously reported for this molecule.Our results show that molecular qubits,with milliseconds coherence time,are promising candidates for quantum information processing.
