The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,batter...The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization.展开更多
Physics-informed neural networks(PINNs)have become an attractive machine learning framework for obtaining solutions to partial differential equations(PDEs).PINNs embed initial,boundary,and PDE constraints into the los...Physics-informed neural networks(PINNs)have become an attractive machine learning framework for obtaining solutions to partial differential equations(PDEs).PINNs embed initial,boundary,and PDE constraints into the loss function.The performance of PINNs is generally affected by both training and sampling.Specifically,training methods focus on how to overcome the training difficulties caused by the special PDE residual loss of PINNs,and sampling methods are concerned with the location and distribution of the sampling points upon which evaluations of PDE residual loss are accomplished.However,a common problem among these original PINNs is that they omit special temporal information utilization during the training or sampling stages when dealing with an important PDE category,namely,time-dependent PDEs,where temporal information plays a key role in the algorithms used.There is one method,called Causal PINN,that considers temporal causality at the training level but not special temporal utilization at the sampling level.Incorporating temporal knowledge into sampling remains to be studied.To fill this gap,we propose a novel temporal causality-based adaptive sampling method that dynamically determines the sampling ratio according to both PDE residual and temporal causality.By designing a sampling ratio determined by both residual loss and temporal causality to control the number and location of sampled points in each temporal sub-domain,we provide a practical solution by incorporating temporal information into sampling.Numerical experiments of several nonlinear time-dependent PDEs,including the Cahn–Hilliard,Korteweg–de Vries,Allen–Cahn and wave equations,show that our proposed sampling method can improve the performance.We demonstrate that using such a relatively simple sampling method can improve prediction performance by up to two orders of magnitude compared with the results from other methods,especially when points are limited.展开更多
This study involved outcrop,drilling,seismic,gravity,and magnetic data to systematically document the geological records of the subduction process of Proto-South China Sea(PSCS)and establish its evolution model.The re...This study involved outcrop,drilling,seismic,gravity,and magnetic data to systematically document the geological records of the subduction process of Proto-South China Sea(PSCS)and establish its evolution model.The results indicate that a series of arc-shaped ophiolite belts and calcalkaline magmatic rocks are developed in northern Borneo,both of which have the characteristics of gradually changing younger from west to east,and are direct signs of subduction and collision of PSCS.At the same time,the subduction of PSCS led to the formation of three accretion zones from the south to the north in Borneo,the Kuching belt,Sibu belt,and Miri belt.The sedimentary formation of northern Borneo is characterized by a three-layer structure,with the oceanic basement at the bottom,overlying the deep-sea flysch deposits of the Rajang–Crocker group,and the molasse sedimentary sequence that is dominated by river-delta and shallow marine facies at the top,recording the whole subduction–collision–orogeny process of PSCS.Further,seismic reflection and tomography also confirmed the subduction and collision of PSCS.Based on the geological records of the subduction and collision of PSCS,combined with the comprehensive analysis of segmented expansion and key tectonic events in the South China Sea,we establish the“gradual”subduction-collision evolution model of PSCS.During the late Eocene to middle Miocene,the Zengmu,Nansha,and Liyue–Palawan blocks were separated by West Baram Line and Balabac Fault,which collided with the Borneo block and Kagayan Ridge successively from the west to the east,forming several foreland basin systems,and PSCS subducted and closed from the west to the east.The subduction and extinction of PSCS controlled the oil and gas distribution pattern of southern South China Sea(SSCS)mainly in three aspects.First,the“gradual”closure process of PSCS led to the continuous development of many large deltas in SSCS.Second,the deltas formed during the subduction–collision of PSCS controlled the development of source rocks in the basins of SSCS.Macroscopically,the distribution and scale of deltas controlled the distribution and scale of source rocks,forming two types of source rocks,namely,coal measures and terrestrial marine facies.Microscopically,the difference of terrestrial higher plants carried by the delta controlled the proportion of macerals of source rocks.Third,the difference of source rocks mainly controlled the distribution pattern of oil and gas in SSCS.Meanwhile,the difference in the scale of source rocks mainly controlled the difference in the amount of oil and gas discoveries,resulting in a huge amount of oil and gas discoveries in the basin of SSCS.Meanwhile,the difference of macerals of source rocks mainly controlled the difference of oil and gas generation,forming the oil and gas distribution pattern of“nearshore oil and far-shore gas”.展开更多
Quasi-2D perovskites have attracted tremendous interest for application as lightemission layers in light-emitting diodes(LEDs).However,the heterogeneous n phase and non-uniform distribution still severely limit the fu...Quasi-2D perovskites have attracted tremendous interest for application as lightemission layers in light-emitting diodes(LEDs).However,the heterogeneous n phase and non-uniform distribution still severely limit the further development of quasi-2D perovskite LEDs(Pero-LEDs).Meanwhile,the increased defect density caused by the reduced dimension and grain size induces non-radiative recombination and further deteriorates the device performance.Here,we found that a series of molecules containing phosphoryl chloride functional groups have noticeable enhancement effects on the device performance of quasi-2D Pero-LEDs.Then,we studied the modification mechanism by focusing on the bis(2-oxo-3-oxazolidinyl)phosphinic chloride(BOPCl).It is concluded that the BOPCl can not only regulate the phase distribution by decreasing the crystallization rate but also remain in the grain boundaries and passivate the defects.As a result,the corresponding quasi-2D Pero-LEDs obtained a maximum external quantum efficiency(EQE_(max))of 20.82%and an average EQE(EQE_(ave))of around 20%on the optimal 50 devices,proving excellent reproducibility.Our work provides a new selection of molecular types for regulating the crystallization and passivating the defects of quasi-2D perovskite films.展开更多
Electrochemical impedance spectroscopy(EIS) is an effective technique for Lithium-ion battery state of health diagnosis, and the impedance spectrum prediction by battery charging curve is expected to enable battery im...Electrochemical impedance spectroscopy(EIS) is an effective technique for Lithium-ion battery state of health diagnosis, and the impedance spectrum prediction by battery charging curve is expected to enable battery impedance testing during vehicle operation. However, the mechanistic relationship between charging curves and impedance spectrum remains unclear, which hinders the development as well as optimization of EIS-based prediction techniques. In this paper, we predicted the impedance spectrum by the battery charging voltage curve and optimized the input based on electrochemical mechanistic analysis and machine learning. The internal electrochemical relationships between the charging curve,incremental capacity curve, and the impedance spectrum are explored, which improves the physical interpretability for this prediction and helps define the proper partial voltage range for the input for machine learning models. Different machine learning algorithms have been adopted for the verification of the proposed framework based on the sequence-to-sequence predictions. In addition, the predictions with different partial voltage ranges, at different state of charge, and with different training data ratio are evaluated to prove the proposed method have high generalization and robustness. The experimental results show that the proper partial voltage range has high accuracy and converges to the findings of the electrochemical analysis. The predicted errors for impedance spectrum are less than 1.9 mΩ with the proper partial voltage range selected by the corelative analysis of the electrochemical reactions inside the batteries. Even with the voltage range reduced to 3.65–3.75 V, the predictions are still reliable with most RMSEs less than 4 mO.展开更多
Fast charging is considered a promising protocol for raising the charging efficiency of electric vehicles.However,high currents applied to Lithium-ion(Li-ion)batteries inevitably accelerate the degradation and shorten...Fast charging is considered a promising protocol for raising the charging efficiency of electric vehicles.However,high currents applied to Lithium-ion(Li-ion)batteries inevitably accelerate the degradation and shorten their lifetime.This work designs a multi-step fast-charging method to extend the lifetime of LiNi0.5Co0.2Mn0.3O2(NMC)/graphite Li-ion batteries based on the studies of half cells and investigates the aging mechanisms for different charging methods.The degradation has been studied from both full cell behaviour and materials perspectives through a combination of non-destructive diagnostic methods and post-mortem analysis.In the proposed multi-step charging protocol,the state-of-charge(SOC)profile is subdivided into five ranges,and the charging current is set differently for different SOC ranges.One of the designed multi-step fast charging protocols is shown to allow for a 200 full equivalent cycles longer lifetime as compared to the standard charging method,while the charging time is reduced by 20%.From the incremental capacity analysis and electrical impedance spectroscopy,the loss of active materials and lithium inventory on the electrodes,as well as an increase in internal resistance for the designed multistep constant-current-constant-voltage(MCCCV)protocol have been found to be significantly lower than for the standard charging method.Post-mortem analysis shows that cells aged by the designed MCCCV fast charging protocol exhibit less graphite exfoliation and crystallization damage,as well as a reduced solid electrolyte interphase(SEI)layer growth on the anode,leading to a lower Rseiresistance and extended lifetime.展开更多
Nordmann's Greenshank(Tringa guttifer)is a globally endangered species that has received little research attention.It is threatened by rapid habitat loss,an incomplete network of protected sites,and lack of long-t...Nordmann's Greenshank(Tringa guttifer)is a globally endangered species that has received little research attention.It is threatened by rapid habitat loss,an incomplete network of protected sites,and lack of long-term data on population dynamics.Citizen science data can be combined with survey data to support population estimation and conservation gap analysis.From 2020 to 2021,Nordmann's Greenshank was surveyed in Tiaozini,Xiaoyangkou,and Dongling on the southern coast of Jiangsu Province,China,and the global population of the species was re-evaluated using the data obtained.We integrated citizen science data from eBird and the China Bird Report from 2000 to 2020 with the survey results to identify important habitats harboring over 1%of its total population,and compared this data with existing protected areas to identify gaps in its global conservation.Our survey found that Tiaozini supported at least 1194 individuals.Consequently,its global population was reestimated to be 1500-2000.Moreover,45 important habitats were identified based on citizen data and survey results.Although 44.4%and 50.0%of the priority sites in the world and China,respectively,are located outside protected areas,the Conservation Effectiveness Index(C)is 68.4%and 71.1%,respectively,showing that the current coverage of protected areas for this part of its range is reasonable.This study presents the most complete and recent population data to date.Tiaozini is the most important migration stopover site for Nordmann's Greenshanks.The species is under threat in terms of breeding,wintering,and stopover sites.Therefore,we suggest improving monitoring,establishing new protected sites to complete the habitat protection network,and improving the effectiveness of existing habitat protection strategies,including further developing high tide roosting sites.展开更多
BACKGROUND Spinocerebellar ataxia recessive type 7(SCAR7)is a rare clinical manifestation beginning in childhood or adolescence.SCAR7 is caused by tripeptidyl peptidase 1(TPP1)gene mutations,and presents with cerebell...BACKGROUND Spinocerebellar ataxia recessive type 7(SCAR7)is a rare clinical manifestation beginning in childhood or adolescence.SCAR7 is caused by tripeptidyl peptidase 1(TPP1)gene mutations,and presents with cerebellar ataxia,pyramidal signs,neurocognitive impairment,deep paresthesia,and cerebellar atrophy.CASE SUMMARY Here,we describe a 25-year-old female patient in China who presented with increasing difficulty walking,falling easily,shaking limbs,instability holding items,slurred speech,coughing when drinking,palpitations,and frequent hunger and overeating.Magnetic resonance imaging showed cerebellar atrophy.Whole exome sequencing detected two compound heterozygous mutations in the TPP1 gene:c.1468G>A p.Glu490Lys and c.1417G>A p.Gly473Arg.Considering the patient’s clinical presentation and genetic test results,we hypothesized that complex heterozygous mutations cause TPP1 enzyme deficiency,which may lead to SCAR7.CONCLUSION We report the first case of SCAR7 from China.We also identify novel compound heterozygous mutations in the TPP1 gene associated with SCAR7,expanding the range of known disease-causing mutations for SCAR7.展开更多
A large portion of the Loess Plateau of China is characterized as “marginal” with serious land degradation and desertification problems. Consequently, two policies, Grain for Green and Western Development Action wer...A large portion of the Loess Plateau of China is characterized as “marginal” with serious land degradation and desertification problems. Consequently, two policies, Grain for Green and Western Development Action were established by the Chinese government in response to the demand for ecological protection and economic development in the Loess Plateau. These policies are designed to increase forest cover, expand farmlands, and enhance soil and water conservation, while creating sustainable vegetation restoration. Perennial grasses have gained attention as bioenergy feedstocks due to their high biomass yields, low inputs, and greater ecosystem services compared to annual crops. Moreover, perennial grasses limit nutrient runoff and reduce greenhouse gas emissions and soil losses while sequestering carbon. Additionally, perennial grasses can generate economic returns for local farmers through producing bioenergy feedstock or forage on marginal lands. Here, we suggest a United States model energy crop, switchgrass(Panicum virgatum L.) as a model crop to minimize land degradation and desertification and to generate biomass for energy on the Loess Plateau.展开更多
Objective:To investigate the effect of Chaiqinchengqi decoction(CQCQD) on serum amyloid A (SAA) in severe acute pancreatitis(SAP) patients.Methods:Thirty-five participants enrolled and were randomly assigned into eith...Objective:To investigate the effect of Chaiqinchengqi decoction(CQCQD) on serum amyloid A (SAA) in severe acute pancreatitis(SAP) patients.Methods:Thirty-five participants enrolled and were randomly assigned into either a treatment condition(n=17,treated with CQCQD) or a control condition(n=18,treated with placebo) 24 hours following the onset of the disease. No statistical difference was observed in either group at baseline.Upon admission,the Acute Physiology and Chronic Health Evaluation scoreⅡ(APACHEⅡ),SAA,serum C-reactive protein (CRP) and interleukin-6(IL-6) were measured,as well as on the first,3rd and 7lh day and were compared between the two groups.Organ complications,infection,operation rate,mortality and hospital stay were also compared.Results:The duration of acute respiratory distress syndrome, acute hepatitis,acute renal failure,gastrointestinal failure and blood coagulation dysfunction were shorter in the treatment group than in those in the control group(P【0.05).The secondary infection rates and the hospital fees in the treatment group were lower than those in the control group(P【0.05) as well as length of hospital stay(P【0.01).After 3 days of hospitalization,the APACHEⅡ,score SAA levels,serum CRP and IL-6 in the treatment group was lower than those in the control group(P【0.05).SAA was positively correlated with serum CRP(R = 0.346,P = 0.042),Ranson score(R = 0.442,P = 0.008) and serum IL-6(R=0.359,P =0.034).The area under the receiver operating characteristic curve of admission SAA predict pancreatic necrosis(PN) was 0.815(95%CI:0.625-0.954;P =0.006).The best cut-off value of admission SAA was 7.85 mg/L with the sensitivity 84.6%and specificity 68.2%.Conclusions:The CQCQD can reduce the duration of organ damage through lowering the SAA in SAP patients and the SAA can early predict the PN and severity of SAP patients.展开更多
The impacts of nighttime post-anthesis warming on rice productivity and grain quality in East China were evaluated for two cultivars, II You 128, an indica rice, and Wuyunjing 7, a japonica rice. Warming by 3.0 °...The impacts of nighttime post-anthesis warming on rice productivity and grain quality in East China were evaluated for two cultivars, II You 128, an indica rice, and Wuyunjing 7, a japonica rice. Warming by 3.0 °C stimulated the nighttime respiration rate and decreased the photosynthesis rate, resulting in significant decreases of 21.2% and 24.9% in aboveground biomass accumulation for II You 128 and Wuyunjing 7, respectively. Warming significantly reduced the rates of seed setting and grain filling, especially of inferior kernels(those lower in panicles), while the filling rate of superior kernels remained almost unchanged. As a result, 1000-grain weight and grain yield were respectively 3.7% and 30.0% lower for II You 128 and 12.8% and 34.3% for Wuyunjing 7 in warmed plots than in the unwarmed control. Nighttime warming also significantly reduced the grain milling and appearance quality of both varieties. More negative effects of warming on inferior than on superior kernels were found. The above results have important implications for rice variety cultivation in East China.展开更多
基金financially supported by the National Natural Science Foundation of China(NSFC)(52274295)the Natural Science Foundation of Hebei Province(E2020501001,E2021501029,A2021501007,E2022501028,E2022501029)+5 种基金the Natural Science Foundation-Steel,the Iron Foundation of Hebei Province(No.E2022501030)the Performance subsidy fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province(22567627H)the Science and Technology Project of Hebei Education Department(ZD2022158)the Central Guided Local Science and Technology Development Fund Project of Hebei province(226Z4401G)the China Scholarship Council(No.202206080061,202206050119)the 2023 Hebei Provincial Postgraduate Student Innovation Ability training funding project(CXZZSS2023195)。
文摘The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization.
基金Project supported by the Key National Natural Science Foundation of China(Grant No.62136005)the National Natural Science Foundation of China(Grant Nos.61922087,61906201,and 62006238)。
文摘Physics-informed neural networks(PINNs)have become an attractive machine learning framework for obtaining solutions to partial differential equations(PDEs).PINNs embed initial,boundary,and PDE constraints into the loss function.The performance of PINNs is generally affected by both training and sampling.Specifically,training methods focus on how to overcome the training difficulties caused by the special PDE residual loss of PINNs,and sampling methods are concerned with the location and distribution of the sampling points upon which evaluations of PDE residual loss are accomplished.However,a common problem among these original PINNs is that they omit special temporal information utilization during the training or sampling stages when dealing with an important PDE category,namely,time-dependent PDEs,where temporal information plays a key role in the algorithms used.There is one method,called Causal PINN,that considers temporal causality at the training level but not special temporal utilization at the sampling level.Incorporating temporal knowledge into sampling remains to be studied.To fill this gap,we propose a novel temporal causality-based adaptive sampling method that dynamically determines the sampling ratio according to both PDE residual and temporal causality.By designing a sampling ratio determined by both residual loss and temporal causality to control the number and location of sampled points in each temporal sub-domain,we provide a practical solution by incorporating temporal information into sampling.Numerical experiments of several nonlinear time-dependent PDEs,including the Cahn–Hilliard,Korteweg–de Vries,Allen–Cahn and wave equations,show that our proposed sampling method can improve the performance.We demonstrate that using such a relatively simple sampling method can improve prediction performance by up to two orders of magnitude compared with the results from other methods,especially when points are limited.
基金The National Natural Science Foundation of China under contract No.91528303the National Science and Technology Major Project under contract No.2016ZX05026-004the CNOOC Basic Geology and Exploration Strategy of Natural Gas in the South China Sea under contract No.2021-KT-YXKY-05。
文摘This study involved outcrop,drilling,seismic,gravity,and magnetic data to systematically document the geological records of the subduction process of Proto-South China Sea(PSCS)and establish its evolution model.The results indicate that a series of arc-shaped ophiolite belts and calcalkaline magmatic rocks are developed in northern Borneo,both of which have the characteristics of gradually changing younger from west to east,and are direct signs of subduction and collision of PSCS.At the same time,the subduction of PSCS led to the formation of three accretion zones from the south to the north in Borneo,the Kuching belt,Sibu belt,and Miri belt.The sedimentary formation of northern Borneo is characterized by a three-layer structure,with the oceanic basement at the bottom,overlying the deep-sea flysch deposits of the Rajang–Crocker group,and the molasse sedimentary sequence that is dominated by river-delta and shallow marine facies at the top,recording the whole subduction–collision–orogeny process of PSCS.Further,seismic reflection and tomography also confirmed the subduction and collision of PSCS.Based on the geological records of the subduction and collision of PSCS,combined with the comprehensive analysis of segmented expansion and key tectonic events in the South China Sea,we establish the“gradual”subduction-collision evolution model of PSCS.During the late Eocene to middle Miocene,the Zengmu,Nansha,and Liyue–Palawan blocks were separated by West Baram Line and Balabac Fault,which collided with the Borneo block and Kagayan Ridge successively from the west to the east,forming several foreland basin systems,and PSCS subducted and closed from the west to the east.The subduction and extinction of PSCS controlled the oil and gas distribution pattern of southern South China Sea(SSCS)mainly in three aspects.First,the“gradual”closure process of PSCS led to the continuous development of many large deltas in SSCS.Second,the deltas formed during the subduction–collision of PSCS controlled the development of source rocks in the basins of SSCS.Macroscopically,the distribution and scale of deltas controlled the distribution and scale of source rocks,forming two types of source rocks,namely,coal measures and terrestrial marine facies.Microscopically,the difference of terrestrial higher plants carried by the delta controlled the proportion of macerals of source rocks.Third,the difference of source rocks mainly controlled the distribution pattern of oil and gas in SSCS.Meanwhile,the difference in the scale of source rocks mainly controlled the difference in the amount of oil and gas discoveries,resulting in a huge amount of oil and gas discoveries in the basin of SSCS.Meanwhile,the difference of macerals of source rocks mainly controlled the difference of oil and gas generation,forming the oil and gas distribution pattern of“nearshore oil and far-shore gas”.
基金supported by the National Natural Science Foundation of China(U21A2078)Natural Science Foundation of Fujian Province(2020J06021,2019J01057,and 2020J01064)Scientific Research Funds of Huaqiao University.
文摘Quasi-2D perovskites have attracted tremendous interest for application as lightemission layers in light-emitting diodes(LEDs).However,the heterogeneous n phase and non-uniform distribution still severely limit the further development of quasi-2D perovskite LEDs(Pero-LEDs).Meanwhile,the increased defect density caused by the reduced dimension and grain size induces non-radiative recombination and further deteriorates the device performance.Here,we found that a series of molecules containing phosphoryl chloride functional groups have noticeable enhancement effects on the device performance of quasi-2D Pero-LEDs.Then,we studied the modification mechanism by focusing on the bis(2-oxo-3-oxazolidinyl)phosphinic chloride(BOPCl).It is concluded that the BOPCl can not only regulate the phase distribution by decreasing the crystallization rate but also remain in the grain boundaries and passivate the defects.As a result,the corresponding quasi-2D Pero-LEDs obtained a maximum external quantum efficiency(EQE_(max))of 20.82%and an average EQE(EQE_(ave))of around 20%on the optimal 50 devices,proving excellent reproducibility.Our work provides a new selection of molecular types for regulating the crystallization and passivating the defects of quasi-2D perovskite films.
基金supported by a grant from the China Scholarship Council (202006370035)a fund from Otto Monsteds Fund (4057941073)。
文摘Electrochemical impedance spectroscopy(EIS) is an effective technique for Lithium-ion battery state of health diagnosis, and the impedance spectrum prediction by battery charging curve is expected to enable battery impedance testing during vehicle operation. However, the mechanistic relationship between charging curves and impedance spectrum remains unclear, which hinders the development as well as optimization of EIS-based prediction techniques. In this paper, we predicted the impedance spectrum by the battery charging voltage curve and optimized the input based on electrochemical mechanistic analysis and machine learning. The internal electrochemical relationships between the charging curve,incremental capacity curve, and the impedance spectrum are explored, which improves the physical interpretability for this prediction and helps define the proper partial voltage range for the input for machine learning models. Different machine learning algorithms have been adopted for the verification of the proposed framework based on the sequence-to-sequence predictions. In addition, the predictions with different partial voltage ranges, at different state of charge, and with different training data ratio are evaluated to prove the proposed method have high generalization and robustness. The experimental results show that the proper partial voltage range has high accuracy and converges to the findings of the electrochemical analysis. The predicted errors for impedance spectrum are less than 1.9 mΩ with the proper partial voltage range selected by the corelative analysis of the electrochemical reactions inside the batteries. Even with the voltage range reduced to 3.65–3.75 V, the predictions are still reliable with most RMSEs less than 4 mO.
基金the support from the China Scholarship Council(202006370035 and 202006220024)the Otto M?nsted Fond(22-70-1620)。
文摘Fast charging is considered a promising protocol for raising the charging efficiency of electric vehicles.However,high currents applied to Lithium-ion(Li-ion)batteries inevitably accelerate the degradation and shorten their lifetime.This work designs a multi-step fast-charging method to extend the lifetime of LiNi0.5Co0.2Mn0.3O2(NMC)/graphite Li-ion batteries based on the studies of half cells and investigates the aging mechanisms for different charging methods.The degradation has been studied from both full cell behaviour and materials perspectives through a combination of non-destructive diagnostic methods and post-mortem analysis.In the proposed multi-step charging protocol,the state-of-charge(SOC)profile is subdivided into five ranges,and the charging current is set differently for different SOC ranges.One of the designed multi-step fast charging protocols is shown to allow for a 200 full equivalent cycles longer lifetime as compared to the standard charging method,while the charging time is reduced by 20%.From the incremental capacity analysis and electrical impedance spectroscopy,the loss of active materials and lithium inventory on the electrodes,as well as an increase in internal resistance for the designed multistep constant-current-constant-voltage(MCCCV)protocol have been found to be significantly lower than for the standard charging method.Post-mortem analysis shows that cells aged by the designed MCCCV fast charging protocol exhibit less graphite exfoliation and crystallization damage,as well as a reduced solid electrolyte interphase(SEI)layer growth on the anode,leading to a lower Rseiresistance and extended lifetime.
基金funded by the National Natural Science Foundation of China(No.31971400)the"Saving Spoon-billed Sandpiper"of Shenzhen Mangrove Wetlands Conservation Foundation(MCF)the Fundamental Research Funds for the Central Universities(No.BLX202144)。
文摘Nordmann's Greenshank(Tringa guttifer)is a globally endangered species that has received little research attention.It is threatened by rapid habitat loss,an incomplete network of protected sites,and lack of long-term data on population dynamics.Citizen science data can be combined with survey data to support population estimation and conservation gap analysis.From 2020 to 2021,Nordmann's Greenshank was surveyed in Tiaozini,Xiaoyangkou,and Dongling on the southern coast of Jiangsu Province,China,and the global population of the species was re-evaluated using the data obtained.We integrated citizen science data from eBird and the China Bird Report from 2000 to 2020 with the survey results to identify important habitats harboring over 1%of its total population,and compared this data with existing protected areas to identify gaps in its global conservation.Our survey found that Tiaozini supported at least 1194 individuals.Consequently,its global population was reestimated to be 1500-2000.Moreover,45 important habitats were identified based on citizen data and survey results.Although 44.4%and 50.0%of the priority sites in the world and China,respectively,are located outside protected areas,the Conservation Effectiveness Index(C)is 68.4%and 71.1%,respectively,showing that the current coverage of protected areas for this part of its range is reasonable.This study presents the most complete and recent population data to date.Tiaozini is the most important migration stopover site for Nordmann's Greenshanks.The species is under threat in terms of breeding,wintering,and stopover sites.Therefore,we suggest improving monitoring,establishing new protected sites to complete the habitat protection network,and improving the effectiveness of existing habitat protection strategies,including further developing high tide roosting sites.
基金Supported by Postdoctoral program of the Affiliated Hospital of Jining Medical University,No.JYFY303573Health Commission of Shandong Province,No.202006010928+1 种基金Academician Lin He New Medicine in Jining Medical University,No.JYHL2018FMS05Affiliated Hospital of Jining Medical University,No.2018-BS-004.
文摘BACKGROUND Spinocerebellar ataxia recessive type 7(SCAR7)is a rare clinical manifestation beginning in childhood or adolescence.SCAR7 is caused by tripeptidyl peptidase 1(TPP1)gene mutations,and presents with cerebellar ataxia,pyramidal signs,neurocognitive impairment,deep paresthesia,and cerebellar atrophy.CASE SUMMARY Here,we describe a 25-year-old female patient in China who presented with increasing difficulty walking,falling easily,shaking limbs,instability holding items,slurred speech,coughing when drinking,palpitations,and frequent hunger and overeating.Magnetic resonance imaging showed cerebellar atrophy.Whole exome sequencing detected two compound heterozygous mutations in the TPP1 gene:c.1468G>A p.Glu490Lys and c.1417G>A p.Gly473Arg.Considering the patient’s clinical presentation and genetic test results,we hypothesized that complex heterozygous mutations cause TPP1 enzyme deficiency,which may lead to SCAR7.CONCLUSION We report the first case of SCAR7 from China.We also identify novel compound heterozygous mutations in the TPP1 gene associated with SCAR7,expanding the range of known disease-causing mutations for SCAR7.
基金supported by the USDA National Institute of Food and Agriculture, Hatch Project (1001878)
文摘A large portion of the Loess Plateau of China is characterized as “marginal” with serious land degradation and desertification problems. Consequently, two policies, Grain for Green and Western Development Action were established by the Chinese government in response to the demand for ecological protection and economic development in the Loess Plateau. These policies are designed to increase forest cover, expand farmlands, and enhance soil and water conservation, while creating sustainable vegetation restoration. Perennial grasses have gained attention as bioenergy feedstocks due to their high biomass yields, low inputs, and greater ecosystem services compared to annual crops. Moreover, perennial grasses limit nutrient runoff and reduce greenhouse gas emissions and soil losses while sequestering carbon. Additionally, perennial grasses can generate economic returns for local farmers through producing bioenergy feedstock or forage on marginal lands. Here, we suggest a United States model energy crop, switchgrass(Panicum virgatum L.) as a model crop to minimize land degradation and desertification and to generate biomass for energy on the Loess Plateau.
基金Supported by National Natural Science Foundation of China(No. 81072910)Science and Technology Supports Program of Sichuan(No.2009SZ0201, 2010SZ0068,2011SZ029)
文摘Objective:To investigate the effect of Chaiqinchengqi decoction(CQCQD) on serum amyloid A (SAA) in severe acute pancreatitis(SAP) patients.Methods:Thirty-five participants enrolled and were randomly assigned into either a treatment condition(n=17,treated with CQCQD) or a control condition(n=18,treated with placebo) 24 hours following the onset of the disease. No statistical difference was observed in either group at baseline.Upon admission,the Acute Physiology and Chronic Health Evaluation scoreⅡ(APACHEⅡ),SAA,serum C-reactive protein (CRP) and interleukin-6(IL-6) were measured,as well as on the first,3rd and 7lh day and were compared between the two groups.Organ complications,infection,operation rate,mortality and hospital stay were also compared.Results:The duration of acute respiratory distress syndrome, acute hepatitis,acute renal failure,gastrointestinal failure and blood coagulation dysfunction were shorter in the treatment group than in those in the control group(P【0.05).The secondary infection rates and the hospital fees in the treatment group were lower than those in the control group(P【0.05) as well as length of hospital stay(P【0.01).After 3 days of hospitalization,the APACHEⅡ,score SAA levels,serum CRP and IL-6 in the treatment group was lower than those in the control group(P【0.05).SAA was positively correlated with serum CRP(R = 0.346,P = 0.042),Ranson score(R = 0.442,P = 0.008) and serum IL-6(R=0.359,P =0.034).The area under the receiver operating characteristic curve of admission SAA predict pancreatic necrosis(PN) was 0.815(95%CI:0.625-0.954;P =0.006).The best cut-off value of admission SAA was 7.85 mg/L with the sensitivity 84.6%and specificity 68.2%.Conclusions:The CQCQD can reduce the duration of organ damage through lowering the SAA in SAP patients and the SAA can early predict the PN and severity of SAP patients.
基金supported by the National Key Technology Support Program of China (2011BAD16B14)the Chinese Natural Science Foundation (30771278)the Program for New Century Excellent Talents in University (NCET-05-0492)
文摘The impacts of nighttime post-anthesis warming on rice productivity and grain quality in East China were evaluated for two cultivars, II You 128, an indica rice, and Wuyunjing 7, a japonica rice. Warming by 3.0 °C stimulated the nighttime respiration rate and decreased the photosynthesis rate, resulting in significant decreases of 21.2% and 24.9% in aboveground biomass accumulation for II You 128 and Wuyunjing 7, respectively. Warming significantly reduced the rates of seed setting and grain filling, especially of inferior kernels(those lower in panicles), while the filling rate of superior kernels remained almost unchanged. As a result, 1000-grain weight and grain yield were respectively 3.7% and 30.0% lower for II You 128 and 12.8% and 34.3% for Wuyunjing 7 in warmed plots than in the unwarmed control. Nighttime warming also significantly reduced the grain milling and appearance quality of both varieties. More negative effects of warming on inferior than on superior kernels were found. The above results have important implications for rice variety cultivation in East China.