Oxidative dehydrogenation of propane is an attractive route for the synthesis of propylene due to its favorable thermodynamic and kinetic characteristics, however, it is challenging to realize high selectivity towards...Oxidative dehydrogenation of propane is an attractive route for the synthesis of propylene due to its favorable thermodynamic and kinetic characteristics, however, it is challenging to realize high selectivity towards propylene. Recently, it has been discovered that boron nitride (BN) is a promising catalyst that affords superior selectivity towards propylene in oxidative dehydrogenation of propane. Summarizing the progress and unravelling the reaction mechanism of BN in oxidative dehydrogenation of propane are of great significance for the rational design of efficient catalysts in the future. Herein, in this review, the underlying reaction mechanisms of oxidative dehydrogenation of propane over BN are extracted;the developed BN catalysts are classified into pristine BN, functionalized BN, supported BN and others, and the applications of each category of BN catalysts in oxidative dehydrogenation of propane are summarized;the challenges and opportunities on oxidative dehydrogenation of propane over BN are pointed out, aiming to inspire more studies and advance this research field.展开更多
The tether deployment of a tethered satellite system involves the consideration of complex dynamic properties of the tether,such as large deformation,slack,and even rebound,and therefore,the dynamic modelling of the t...The tether deployment of a tethered satellite system involves the consideration of complex dynamic properties of the tether,such as large deformation,slack,and even rebound,and therefore,the dynamic modelling of the tether is necessary for performing a dynamic analysis of the system.For a variablelength tether element,the absolute nodal coordinate formulation(ANCF)in the framework of the arbitrary Lagrange-Euler(ALE)description was used to develop a precise dynamic model of a tethered satellite.The model considered the gravitational gradient force and Coriolis force in the orbital coordinate frame,and it was validated through numerical simulation.In the presence of dynamic constraints,a deployment velocity of the tether was obtained by an optimal procedure.In the simulation,rebound behavior of the tethered satellite system was observed when the ANCF-ALE model was employed.Notably,the rebound behavior cannot be predicted by the traditional dumbbell model.Furthermore,an improved optimal deployment velocity was developed.Simulation results indicated that the rebound phenomenon was eliminated,and smooth deployment as well as a stable state of the station-keeping process were achieved.Additionally,the swing amplitude in the station-keeping phase decreased when a deployment strategy based on the improved optimal deployment velocity was used.展开更多
In addition to sperm,some accessory substances transferred to females during copulation act as nuptial gifts by passing on valuable nutrients in many insect species.The nutritional status of the males can thus have a ...In addition to sperm,some accessory substances transferred to females during copulation act as nuptial gifts by passing on valuable nutrients in many insect species.The nutritional status of the males can thus have a great effect on the mating behavior,fecundity and even the longevity of females.However,little is known about the effect of male nutritional status on the female reproductive traits in migratory insect species,particularly when females experience nutrient shortage and have to choose between reproduction and migration.Here,Cnaphalocrocis medinalis,a migratory rice pest in Asia,was studied to explore this issue.Our results showed that in male moths fed with honey solution,their gonads had higher energy content than gonads of starved males,resulting in increased energy content of the bursa copulatrix of females after mating with fed males.Such females showed increased mating frequency,fecundity and longevity compared to females mating with starved males,indicating that male moths deliver nuptial gifts to females and improve their reproductive performance.However,when females were starved,only about 45%mated,with just a single copulation,regardless of male nutritional status.Starved females showed lower fecundity,and a longer pre-oviposition period(indicating a greater propensity to migrate),compared to fed females.However,copulation still significantly extended their longevity.These results suggest that starved females invest in migration to escape deteriorating habitats,rather than investing the nuptial gift to increased fecundity.Our results further our understanding of the reproductive adaptability of migratory insects under conditions of food stress.展开更多
基金This work received financial support from the National Natural Science Foundation of China(21902116)Scientific Research Foundation of Technology Department of Liaoning province of China(2022-MS-379)Liaoning Revitalization Talents Program(XLYC1902070).
文摘Oxidative dehydrogenation of propane is an attractive route for the synthesis of propylene due to its favorable thermodynamic and kinetic characteristics, however, it is challenging to realize high selectivity towards propylene. Recently, it has been discovered that boron nitride (BN) is a promising catalyst that affords superior selectivity towards propylene in oxidative dehydrogenation of propane. Summarizing the progress and unravelling the reaction mechanism of BN in oxidative dehydrogenation of propane are of great significance for the rational design of efficient catalysts in the future. Herein, in this review, the underlying reaction mechanisms of oxidative dehydrogenation of propane over BN are extracted;the developed BN catalysts are classified into pristine BN, functionalized BN, supported BN and others, and the applications of each category of BN catalysts in oxidative dehydrogenation of propane are summarized;the challenges and opportunities on oxidative dehydrogenation of propane over BN are pointed out, aiming to inspire more studies and advance this research field.
基金supported by the Natural Science Foundation of Shaanxi Province,China(2020JQ-288)Science and Technology on Space Intelligent Control Laboratory,China(HTKJ2019KL502016)+1 种基金China Scholarship Council(201806120093)National Natural Science Foundation of China(61903289).
文摘The tether deployment of a tethered satellite system involves the consideration of complex dynamic properties of the tether,such as large deformation,slack,and even rebound,and therefore,the dynamic modelling of the tether is necessary for performing a dynamic analysis of the system.For a variablelength tether element,the absolute nodal coordinate formulation(ANCF)in the framework of the arbitrary Lagrange-Euler(ALE)description was used to develop a precise dynamic model of a tethered satellite.The model considered the gravitational gradient force and Coriolis force in the orbital coordinate frame,and it was validated through numerical simulation.In the presence of dynamic constraints,a deployment velocity of the tether was obtained by an optimal procedure.In the simulation,rebound behavior of the tethered satellite system was observed when the ANCF-ALE model was employed.Notably,the rebound behavior cannot be predicted by the traditional dumbbell model.Furthermore,an improved optimal deployment velocity was developed.Simulation results indicated that the rebound phenomenon was eliminated,and smooth deployment as well as a stable state of the station-keeping process were achieved.Additionally,the swing amplitude in the station-keeping phase decreased when a deployment strategy based on the improved optimal deployment velocity was used.
基金Project supported by the National Key Research and Development Project of China(No.2016YFD0200800)the National Natural Science foundation of China(No.41571226)。
基金supported by the National Key Research and Development Program of China(2016YFD0300702)the Fundamental Research Funds for the Central Universities(China)(KJYQ201902,KJJQ201803).
文摘In addition to sperm,some accessory substances transferred to females during copulation act as nuptial gifts by passing on valuable nutrients in many insect species.The nutritional status of the males can thus have a great effect on the mating behavior,fecundity and even the longevity of females.However,little is known about the effect of male nutritional status on the female reproductive traits in migratory insect species,particularly when females experience nutrient shortage and have to choose between reproduction and migration.Here,Cnaphalocrocis medinalis,a migratory rice pest in Asia,was studied to explore this issue.Our results showed that in male moths fed with honey solution,their gonads had higher energy content than gonads of starved males,resulting in increased energy content of the bursa copulatrix of females after mating with fed males.Such females showed increased mating frequency,fecundity and longevity compared to females mating with starved males,indicating that male moths deliver nuptial gifts to females and improve their reproductive performance.However,when females were starved,only about 45%mated,with just a single copulation,regardless of male nutritional status.Starved females showed lower fecundity,and a longer pre-oviposition period(indicating a greater propensity to migrate),compared to fed females.However,copulation still significantly extended their longevity.These results suggest that starved females invest in migration to escape deteriorating habitats,rather than investing the nuptial gift to increased fecundity.Our results further our understanding of the reproductive adaptability of migratory insects under conditions of food stress.
