Novel CoAl-LDH Nanosheets/BiPO_(4) nanorods composites for boosting photocatalytic degradation of phenol

Layered double hydroxide(LDH)with special layered structure has been proved to have excellent hole transport capacity and good stability.Herein,we report a high efficient composite photocatalyst of CoAlLDH and BiPO4prepared by hydrothermal and che mical adsorption(denoted as CoAl-LDH/BiPO_(4)).Phenol can be entirely degraded by 1%CoAl-LDH/BiPO_(4)under 30 min ultraviolet(UV)light irradiation,and the degradation rate constants k are 3 times and 39 times higher than that of pure BiPO_(4)and CoAl-LDH,respectively.The enhanced photocatalytic activity can be attributed to effective holes transfer from BiPO4to CoAl-LDH,which hinders the recombination of photo genera ted charge carriers.In addition,the combination of BiPO4and CoAl-LDH avoids the agglomeration of BiPO4and improves the stability of BiPO_(4).Active species capture experiments indicate that superoxide radicals(·O-_(2))are the main active species responsible for the degradation of phenol.This work provides technical approaches and research ideas for solving the photogenerated charge carrier recombination problem of photocatalyst.

Dynamically loading IFC models on a web browser based on spatial semantic partitioning

Industry foundation classes(IFC)is an open and neutral data format specification for building information modeling(BIM)that plays a crucial role in facilitating interoperability.With increases in web-based BIM applications,there is an urgent need for fast loading large IFC models on a web browser.However,the task of fully loading large IFC models typically consumes a large amount of memory of a web browser or even crashes the browser,and this significantly limits further BIM applications.In order to address the issue,a method is proposed for dynamically loading IFC models based on spatial semantic partitioning(SSP).First,the spatial semantic structure of an input IFC model is partitioned via the extraction of story information and establishing a component space index table on the server.Subsequently,based on user interaction,only the model data that a user is interested in is transmitted,loaded,and displayed on the client.The presented method is implemented via Web Graphics Library,and this enables large IFC models to be fast loaded on the web browser without requiring any plug-ins.When compared with conventional methods that load all IFC model data for display purposes,the proposed method significantly reduces memory consumption in a web browser,thereby allowing the loading of large IFC models.When compared with the existing method of spatial partitioning for 3D data,the proposed SSP entirely uses semantic information in the IFC file itself,and thereby provides a better interactive experience for users.