Industrial robots are increasingly being used in machining tasks because of their high flexibility and intelligence.However,the low structural stiffness of a robot significantly affects its positional accuracy and the...Industrial robots are increasingly being used in machining tasks because of their high flexibility and intelligence.However,the low structural stiffness of a robot significantly affects its positional accuracy and the machining quality of its operation equipment.Studying robot stiffness characteristics and optimization methods is an effective method of improving the stiffness performance of a robot.Accordingly,aiming at the poor accuracy of stiffness modeling caused by approximating the stiffness of each joint as a constant,a variable stiffness identification method is proposed based on space gridding.Subsequently,a task-oriented axial stiffness evaluation index is proposed to quantitatively assess the stiffness performance in the machining direction.In addition,by analyzing the redundant kinematic characteristics of the robot machining system,a configuration optimization method is further developed to maximize the index.For numerous points or trajectory-processing tasks,a configuration smoothing strategy is proposed to rapidly acquire optimized configurations.Finally,experiments on a KR500 robot were conducted to verify the feasibility and validity of the proposed stiffness identification and configuration optimization methods.展开更多
A photoactive polyoxometalate-based metal-organic framework (POMOF),NiW-DPNDI,was synthesized by combination of Ni(Ⅱ) ions,[ZnW_(12)O_(40)]^(6–)anions,and N,N’-bis(4-pyridylmethyl)naphthalene diimide(DPNDI) molecul...A photoactive polyoxometalate-based metal-organic framework (POMOF),NiW-DPNDI,was synthesized by combination of Ni(Ⅱ) ions,[ZnW_(12)O_(40)]^(6–)anions,and N,N’-bis(4-pyridylmethyl)naphthalene diimide(DPNDI) molecules into one single framework.Ni W-DPNDI displays a three-dimensional structure by the strong anion···π interactions between the trapped[ZnW_(12)O_(40)]^(6–)anions and the electron-deficient naphthalenic ring centroids and theπ-πstacking interactions between DPNDI moieties.Ni W-DPNDI displayed a highly efficient hole-electron separation and ordered electron transfer under irradiation,thus ensuing its excellent photocatalysis in oxidation of styrene to produce benzaldehyde.In addition,it gave a high efficiency for styrene oxide under thermocatalytic conditions.Because the carbonic anhydrase (CA)-mimicking Ni sites and the negative electron-enriched[ZnW_(12)O_(40)]^(6–)anions are well aligned in the pores,it can promote the cycloaddition of CO_(2) with epoxides under mild conditions.展开更多
基金National Natural Science Foundation of China(Grant No.51875287)National Defense Basic Scientific Research Program of China(Grant No.JCKY2018605C002)Jiangsu Provincial Natural Science Foundation of China(Grant No.BK20190417).
文摘Industrial robots are increasingly being used in machining tasks because of their high flexibility and intelligence.However,the low structural stiffness of a robot significantly affects its positional accuracy and the machining quality of its operation equipment.Studying robot stiffness characteristics and optimization methods is an effective method of improving the stiffness performance of a robot.Accordingly,aiming at the poor accuracy of stiffness modeling caused by approximating the stiffness of each joint as a constant,a variable stiffness identification method is proposed based on space gridding.Subsequently,a task-oriented axial stiffness evaluation index is proposed to quantitatively assess the stiffness performance in the machining direction.In addition,by analyzing the redundant kinematic characteristics of the robot machining system,a configuration optimization method is further developed to maximize the index.For numerous points or trajectory-processing tasks,a configuration smoothing strategy is proposed to rapidly acquire optimized configurations.Finally,experiments on a KR500 robot were conducted to verify the feasibility and validity of the proposed stiffness identification and configuration optimization methods.
基金supported by the Natural Science Foundation of Henan (Nos. 202300410043 and 222102230091)the Key Scientific Research Project of Henan Higher Education Institutions (No. 20ZX006)the National Natural Science Foundation of China (No. 21601048)。
文摘A photoactive polyoxometalate-based metal-organic framework (POMOF),NiW-DPNDI,was synthesized by combination of Ni(Ⅱ) ions,[ZnW_(12)O_(40)]^(6–)anions,and N,N’-bis(4-pyridylmethyl)naphthalene diimide(DPNDI) molecules into one single framework.Ni W-DPNDI displays a three-dimensional structure by the strong anion···π interactions between the trapped[ZnW_(12)O_(40)]^(6–)anions and the electron-deficient naphthalenic ring centroids and theπ-πstacking interactions between DPNDI moieties.Ni W-DPNDI displayed a highly efficient hole-electron separation and ordered electron transfer under irradiation,thus ensuing its excellent photocatalysis in oxidation of styrene to produce benzaldehyde.In addition,it gave a high efficiency for styrene oxide under thermocatalytic conditions.Because the carbonic anhydrase (CA)-mimicking Ni sites and the negative electron-enriched[ZnW_(12)O_(40)]^(6–)anions are well aligned in the pores,it can promote the cycloaddition of CO_(2) with epoxides under mild conditions.