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牙膏中可溶性/游离氟化物快速定量分析方法研究
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作者 曹东霞 周雷 +2 位作者 李家宏 林长钦 陈锦玲 《日用化学工业(中英文)》 北大核心 2024年第1期38-44,共7页
有效结合低场核磁共振技术(LF-NMR)和高场固体核磁共振技术(SS-NMR),系统研究了牙膏中氟化物,建立了牙膏中可溶性/游离氟化物的LF-NMR快速定量分析方法。实验结果表明,LF-NMR 6次平行测试的相对标准偏差RSD均在2%以内,精密度高。实际样... 有效结合低场核磁共振技术(LF-NMR)和高场固体核磁共振技术(SS-NMR),系统研究了牙膏中氟化物,建立了牙膏中可溶性/游离氟化物的LF-NMR快速定量分析方法。实验结果表明,LF-NMR 6次平行测试的相对标准偏差RSD均在2%以内,精密度高。实际样品测试中,117款牙膏样品中有110款样品LF-NMR定量分析数据与国标方法氟离子选择电极法测试数据相对偏差在±5%以内;另有7款样品,LF-NMR与国标方法定量数据有较大的差异,结合SS-NMR的氟化物物种及形态分析结果,发现造成差异的主要原因是体系中存在不溶性氟化物物种,影响整个体系的弛豫时间,造成LF-NMR测试结果较国标方法低,但LF-NMR可作为快筛手段及时反映牙膏质量问题。LF-NMR方法前处理简单,牙膏样品无需任何前处理,直接装样测试,整个测试流程5 min左右,是非常快速的定量分析手段,并且,结合SS-NMR技术,进一步明确了LF-NMR定量测试适用体系。 展开更多
关键词 快速定量 牙膏 氟化物 低场核磁共振技术 固体核磁共振技术
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牙膏中不同形态氟化物的固体NMR研究 被引量:1
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作者 周雷 曹东霞 +2 位作者 李家宏 苏哪锋 李文辉 《日用化学工业(中英文)》 CAS 北大核心 2023年第8期963-967,共5页
采用19F固体核磁共振技术(19F SS-NMR)对38款含氟牙膏样品中不同形态氟化物进行了分析研究。牙膏样品经少量淀粉混合固化后直接装样采集,采用hahn-echo回波序列,魔角旋转转速12~14 kHz。结果显示,不同摩擦剂与氟化物匹配的稳定性有较大... 采用19F固体核磁共振技术(19F SS-NMR)对38款含氟牙膏样品中不同形态氟化物进行了分析研究。牙膏样品经少量淀粉混合固化后直接装样采集,采用hahn-echo回波序列,魔角旋转转速12~14 kHz。结果显示,不同摩擦剂与氟化物匹配的稳定性有较大差异,其中摩擦剂水合硅石与氟化物的匹配一般较稳定,氟化物主要以可溶性/游离状态存在于牙膏体系中;部分碳酸钙基质牙膏中,除原料氟化物信号外,还观测到新生成的不可溶性固体氟化钙信号。除摩擦剂的影响外,在一些添加了羟基磷灰石等功效成分的牙膏中,也观测到不可溶性的氟化钙的生成,不可溶性氟化物的生成将降低牙膏中有效氟的含量。对牙膏这种半固体样品,19F SS-NMR具有前处理操作简便、专属性强、灵敏度高等特点,可对含氟牙膏中氟化物进行形态分析,为牙膏配方研发、质量提升提供技术支持。 展开更多
关键词 牙膏 氟化物 固体核磁共振技术
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Visible Light-Driven Catalyst-Free Amination of Indoles Initiated by Electron Donor-Acceptor Complexes 被引量:1
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作者 jiahong Sui Zhonglie Yang +5 位作者 Shuangqiao li Xueqin Chen Xiaobin Zhang Qing Shen Hezhong Jiang jiahong li 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2023年第12期1485-1490,共6页
The visible light-driven C2 or C3 amination of indoles without any additives was initiated via electron donor-acceptor (EDA) complex formed by indole and N-aminopyridinium salt.This method was compatible with a wide r... The visible light-driven C2 or C3 amination of indoles without any additives was initiated via electron donor-acceptor (EDA) complex formed by indole and N-aminopyridinium salt.This method was compatible with a wide range of substrates and could proceed smoothly without the addition of any photocatalysts,transition-metal catalysts,or bases.A variety of studies were carried out to examine the presence of EDA complex. 展开更多
关键词 PHOTOCHEMISTRY AMINATION C-N bond formation Green chemistry N-HETEROCYCLES Donor-acceptor systems
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Utilization threshold of surface water and groundwater based on the system optimization of crop planting structure 被引量:2
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作者 Qiang FU jiahong li +2 位作者 Tianxiao li Dong liU Song CUI 《Frontiers of Agricultural Science and Engineering》 2016年第3期231-240,共10页
Based on the diversity of the agricultural system, this research calculates the planting structures of rice, maize and soybean considering the optimal economic-social-ecological aspects. Then, based on the uncertainty... Based on the diversity of the agricultural system, this research calculates the planting structures of rice, maize and soybean considering the optimal economic-social-ecological aspects. Then, based on the uncertainty and randomness of the water resources system,the interval two-stage stochastic programming method,which introduces the uncertainty of the interval number, is used to calculate the groundwater exploitation and the use efficiency of surface water. The method considers the minimum cost of water as the objective of the uncertainty model for surface water and groundwater joint scheduling optimization for different planting structures. Finally, by calculating harmonious entropy, the optimal exploitation utilization interval of surface water and groundwater is determined for optimal cultivation in the Sanjiang Plain.The optimal matching of the planting structure under the economic system is suitable when the mining ratio of the surface is in 44.13%–45.45% and the exploitation utilization of groundwater is in 54.82%–66.86%, the optimal planting structure under the social system is suitable when surface water mining ratio is in 47.84%–48.04% and the groundwater exploitation threshold is in 67.07%–72.00%. This article optimizes the economicsocial-ecological-water system, which is important for the development of a water- and food-conserving society and providing a more accurate management environment. 展开更多
关键词 economic-social-ecological uncertainty harmonious entropy surface water and groundwater utilization threshold
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Micellar Catalysis:Visible-Light Mediated Imidazo[1,2-a]pyridine C—H Amination with N-Aminopyridinium Salt Accelerated by Surfactant in Water 被引量:1
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作者 Zhonglie Yang Kun Cao +7 位作者 Xiaoyan Peng li lin Danchen Fan Jun-Long li Jingxia Wang Xiaobin Zhang Hezhong Jiang jiahong li 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2021年第12期3347-3352,共6页
A light-promoted metal-free protocol for the amination of imidazo[1,2-a]pyridines with N-aminopyridinium salt by the assistance of surfactants in water was reported,charactering mild and environmentally benign conditi... A light-promoted metal-free protocol for the amination of imidazo[1,2-a]pyridines with N-aminopyridinium salt by the assistance of surfactants in water was reported,charactering mild and environmentally benign conditions,as well as great functional group tolerance.Micelles with negatively charged polar surface and hydrophobic core formed from sodium dodecyl sulfate serve as an ideal medium for visible-light mediated radical reaction of cationic pyridine salt and imidazo[1,2-a]pyridine in aqueous phase.The electrostatic interaction between positively charged N-aminopyridinium and negatively charged surface of micelles is of great significance in this method. 展开更多
关键词 PHOTOCHEMISTRY Water chemistry Micelles N-Aminopyridinium salt Imidazo[1 2-a]pyridine
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A New Empirical Method for Constructing Capillary Pressure Curves from Conventional Logs in Low-Permeability Sandstones 被引量:1
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作者 Cheng Feng Yujiang Shi +3 位作者 jiahong li liang Chang Gaoren li Zhiqiang Mao 《Journal of Earth Science》 SCIE CAS CSCD 2017年第3期516-522,共7页
Pore structure reflected from capillary pressure curves plays an important role in low-permeability formation evaluation. It is a common way to construct capillary pressure curves by Nuclear Magnetic Resonance(NMR) ... Pore structure reflected from capillary pressure curves plays an important role in low-permeability formation evaluation. It is a common way to construct capillary pressure curves by Nuclear Magnetic Resonance(NMR) log. However, the method's efficiency will be severely affected if there is no NMR log data or it cannot reflect pore structure well. Therefore, on the basis of J function and diagenetic facies classification, a new empirical model for constructing capillary pressure curves from conventional logs is proposed here as a solution to the problem. This model includes porosity and the relative value of natural gamma rays as independent variables and the saturation of mercury injection as a dependent variable. According to the 51 core experimental data sets of three diagenetic facies from the bottom of the Upper Triassic in the western Ordos Basin, China, the model's parameters in each diagenetic facies are calibrated. Both self-checking and extrapolation tests show a positive effect, which demonstrates the high reliability of the proposed capillary pressure curve construction model. Based on the constructed capillary pressure curves, NMR T_2 spectra under fully brine-saturated conditions are mapped by a piecewise power function. A field study is then presented. Agreement can be seen between the mapped NMR T_2 spectra and the MRIL-Plog data in the location of the major peak, right boundary, distribution characteristics and T_2 logarithmic mean value. In addition, the capillary pressure curve construction model proposed in this paper is not affected by special log data or formation condition. It is of great importance in evaluating pore structure, predicting oil production and identifying oil layers through NMR log data in low-permeability sandstones. 展开更多
关键词 low-permeability conventional logs capillary pressure curve J function NMR T2 spectrum
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早产儿RhE合并Rhc溶血病1例并文献复习
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作者 张霭润 招嘉樑 +5 位作者 李管明 李嘉鸿 陈静蓉 王兰 庄思齐 房晓祎 《中华妇幼临床医学杂志(电子版)》 CAS 2023年第1期93-99,共7页
目的:探讨抗RhE合并抗Rhc抗体导致新生儿溶血病(HDN)的临床特点。方法:选择2019年12月,于中山大学附属第七医院住院治疗的1例RhE合并Rhc溶血病早产儿为研究对象。回顾性分析其临床病例资料。检索国内外数据库中抗RhE合并抗Rhc抗体所致HD... 目的:探讨抗RhE合并抗Rhc抗体导致新生儿溶血病(HDN)的临床特点。方法:选择2019年12月,于中山大学附属第七医院住院治疗的1例RhE合并Rhc溶血病早产儿为研究对象。回顾性分析其临床病例资料。检索国内外数据库中抗RhE合并抗Rhc抗体所致HDN的相关文献,分析该病患儿的临床特点、治疗方案及预后。本研究遵循的程序符合2013年修订的《世界医学协会赫尔辛基宣言》。监护人对本例患儿的诊治均知情同意。结果:①本例患儿临床资料:女性,G5P3,出生胎龄为31+2周。因"未足月胎膜早破19 d,频发胎心减速"剖宫产术娩出,生后14 h出现发热、反应差、黄疸、贫血,血培养结果显示大肠埃希菌(ESBL+),血清总胆红素(TBil)增高达换血阈值。患儿血型为O型Rh(CcDEe)、直接抗人球蛋白试验(DAT)阳性,其母血型为O型Rh(CCDee)。对本例患儿采取换血、输血、强光疗、静脉注射免疫球蛋白(IVIG)及抗感染等治疗,于生后37 d治愈出院。其主要出院诊断为Rh血型不合HDN(RhE合并Rhc),新生儿败血症(宫内感染)等。门诊随访至生后24个月龄,患儿智力、运动发育正常。②文献检索结果:按照本研究检索策略,符合本研究纳入标准的文献共计14篇,涉及14例RhE合并Rhc HDN患儿,出生即存在贫血、黄疸,黄疸进展快,DAT阳性,及时予光疗、换血等治疗后,黄疸消退。对部分患儿的随访结果显示,未发现神经系统后遗症。结论:对于母亲检出血清不规则抗体,新生儿出现贫血、黄疸,并且出现时间早、进展快,需对患儿进行稀有血型不合溶血病筛查。对RhE合并Rhc HDN患儿,若采取早期积极治疗措施,患儿预后良好。 展开更多
关键词 幼红细胞增多症 胎儿 血型不合 Rh同种免疫 高胆红素血症 新生儿 交换输血 全血 婴儿 早产
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静脉生酮治疗GABRB2基因变异致发育性癫痫性脑病一例
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作者 李佳红 邓劼 +2 位作者 陈春红 方方 徐樨巍 《中华儿科杂志》 CAS CSCD 北大核心 2021年第12期1092-1094,共3页
1岁14日龄女性患儿,生后反复抽搐,发作频繁,为药物难治性癫痫,伴有广泛性发育落后,患儿全外显子基因组检测提示GABRB2基因c.734T>C(p.F245S)杂合、错义、新发变异,诊断为发育性癫痫性脑病92型。患儿既往肠道生酮饮食不耐受,因频繁呕... 1岁14日龄女性患儿,生后反复抽搐,发作频繁,为药物难治性癫痫,伴有广泛性发育落后,患儿全外显子基因组检测提示GABRB2基因c.734T>C(p.F245S)杂合、错义、新发变异,诊断为发育性癫痫性脑病92型。患儿既往肠道生酮饮食不耐受,因频繁呕吐及抽搐接受了短期静脉生酮治疗,抽搐发作在一定时间内得到控制,期间未出现严重不良反应,成功过渡至肠内生酮饮食。 展开更多
关键词 抽搐发作 生酮饮食 癫痫性脑病 药物难治性癫痫 发育落后 不耐受 发育性 GAB
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自驾驶中的交互认知 被引量:8
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作者 马楠 高跃 +1 位作者 李佳洪 李德毅 《中国科学:信息科学》 CSCD 北大核心 2018年第8期1083-1096,共14页
近年来,无人驾驶无论Tesla路线、Waymo路线,还是Intel路线等,都重点关注感知、规划和决策等计算认知,而交互认知严重缺失.这一问题不解决,自驾驶车难以被社会接受与认可.本文分析了自驾驶车交互认知的丰富性和实现难度,提出基于自然语... 近年来,无人驾驶无论Tesla路线、Waymo路线,还是Intel路线等,都重点关注感知、规划和决策等计算认知,而交互认知严重缺失.这一问题不解决,自驾驶车难以被社会接受与认可.本文分析了自驾驶车交互认知的丰富性和实现难度,提出基于自然语言交互的车载智能音箱对话、肢体语言交互和车体语言交互3种交互形式.通过智能音箱及互联网实现了自驾驶车与车主、乘员、运维人员、开发人员、远程服务请求等之间的交互;解决了自驾驶车对路边行人和执勤交警的手势识别、理解与应对;攻克了狭路会车和超车并道两种常见车体交互的难题.最后,基于丰富的自驾驶交互认知形式,给出独立于决策总线的交互总线架构设计,并在多类型智能车上开展应用. 展开更多
关键词 拟人驾驶 多总线架构设计 车载智能音箱 手势识别与理解 车体交互
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Survey of Pedestrian Action Recognition Techniques for Autonomous Driving 被引量:4
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作者 li Chen Nan Ma +4 位作者 Patrick Wang jiahong li Pengfei Wang Guilin Pang Xiaojun Shi 《Tsinghua Science and Technology》 SCIE EI CAS CSCD 2020年第4期458-470,共13页
The development of autonomous driving has brought with it requirements for intelligence,safety,and stability.One example of this is the need to construct effective forms of interactive cognition between pedestrians an... The development of autonomous driving has brought with it requirements for intelligence,safety,and stability.One example of this is the need to construct effective forms of interactive cognition between pedestrians and vehicles in dynamic,complex,and uncertain environments.Pedestrian action detection is a form of interactive cognition that is fundamental to the success of autonomous driving technologies.Specifically,vehicles need to detect pedestrians,recognize their limb movements,and understand the meaning of their actions before making appropriate decisions in response.In this survey,we present a detailed description of the architecture for pedestrian action recognition in autonomous driving,and compare the existing mainstream pedestrian action recognition techniques.We also introduce several commonly used datasets used in pedestrian motion recognition.Finally,we present several suggestions for future research directions. 展开更多
关键词 AUTONOMOUS driving PEDESTRIAN action RECOGNITION action datasets two-stream network
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A Survey of Human Action Recognition and Posture Prediction 被引量:3
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作者 Nan Ma Zhixuan Wu +4 位作者 Yiu-ming Cheung Yuchen Guo Yue Gao jiahong li Beiyan Jiang 《Tsinghua Science and Technology》 SCIE EI CAS CSCD 2022年第6期973-1001,共29页
Human action recognition and posture prediction aim to recognize and predict respectively the action and postures of persons in videos.They are both active research topics in computer vision community,which have attra... Human action recognition and posture prediction aim to recognize and predict respectively the action and postures of persons in videos.They are both active research topics in computer vision community,which have attracted considerable attention from academia and industry.They are also the precondition for intelligent interaction and human-computer cooperation,and they help the machine perceive the external environment.In the past decade,tremendous progress has been made in the field,especially after the emergence of deep learning technologies.Hence,it is necessary to make a comprehensive review of recent developments.In this paper,firstly,we attempt to present the background,and then discuss research progresses.Secondly,we introduce datasets,various typical feature representation methods,and explore advanced human action recognition and posture prediction algorithms.Finally,facing the challenges in the field,this paper puts forward the research focus,and introduces the importance of action recognition and posture prediction by taking interactive cognition in self-driving vehicle as an example. 展开更多
关键词 human action recognition posture prediction computer vision human-computer cooperation interactive cognition
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