An arguable point regarding the Neoarchean and Paleoproterozoic crustal evolution of the North China Craton（NCC）is whether the tectonic setting in the central belt during the mid-Paleoproterozoic（2.35-2.0 Ga）was d...An arguable point regarding the Neoarchean and Paleoproterozoic crustal evolution of the North China Craton（NCC）is whether the tectonic setting in the central belt during the mid-Paleoproterozoic（2.35-2.0 Ga）was dominated by an extensional regime or an oceanic subduction-arc regime.A review of the midPaleoproterozoic magmatism and sedimentation for the Hengshan-Wutai-Fuping region suggests that a back-arc extension regime was dominant in this region.This conclusion is consistent with the observation that the 2.35-2.0 Ga magmatism shows a typical bimodal distribution where the mafic rocks mostly have arc affinities and the acidic rocks mainly comprise highly-fractioned calc-alkaline to alkaline（or A-type）granites,and that this magmatism was coeval with development of extensional basins characteristic of transgressive sequences with volcanic interlayers such as in the Hutuo Group.Although the final amalgamation of the NCC was believed to occur at ～1.85 Ga,recent zircon U-Pb age dating for mica schist in the Wutai Group suggests a collisional event may have occurred at ～1.95 Ga.The metamorphic ages of ～1.85 Ga,obtained mostly from the high-grade rocks using the zircon U-Pb approach,most probably indicate uplifting and cooling of these high-grade terranes.This is because（i）phase modeling suggests that newly-grown zircon grains in highgrade rocks with a melt phase cannot date the age of peak pressure and temperature stages,but the age of melt crystallization in cooling stages;（ii）the metamorphic P-T paths with isobaric cooling under 6-7 kb for the Hengshan and Fuping granulites suggest their prolonged stay in the middle-lower crust;and（iii）the obtained metamorphic age data show a continuous distribution from 1.95 to 1.80 Ga.Thus,an alternative tectonic scenario for the Hengshan-Wutai-Fuping region involves：（i）formation of a proto-NCC at ～2.5 Ga;（ii）back-arc extension during 2.35-2.0 Ga resulting in bimodal magmatism and sedimentation in rifting basins on an Archean basement;（iii）a crustal thickening event in the extended region resulting in a kyanitetype metamorphism at ～1.95 Ga,and（iv） uplifting and cooling of the thickened crust from 1.93 to 1.80 Ga.展开更多
Ultrahigh-temperature(UHT)metamorphism represents an extreme crustal thermal event with peak conditions exceeding 900C at 7–13 kbar.In the modern-style plate tectonic system,records of the UHT metamorphism are relati...Ultrahigh-temperature(UHT)metamorphism represents an extreme crustal thermal event with peak conditions exceeding 900C at 7–13 kbar.In the modern-style plate tectonic system,records of the UHT metamorphism are relatively rare due to the secular cooling of Earth.In the Palu region of Western Sulawesi,we newly discovered a series of HT-UHT metamorphic rocks including amphibolite,granulite,eclogites and gneiss.Of them,two granulite samples(18CS14-2,18CS14-4)with high garnet content(>50 mol%)are chosen for petrographic observation,phase equilibrium modelling,and zircon U-Pb dating.These rocks are characterized by a relic M1 assemblage of Grt+Ky+Bt+Rt and a M2 assemblage of Grt+Sil+Pl+Spl+Crd±Qtz+Ilm+melt.Phase equilibrium modelling based on effective bulk compositions yields UHT conditions of 7.2–8.5 kbar/940–1080C(18CS14-2)and 7.0–7.3 kbar/1000–1040C(18CS14-4).U-Pb analysis reveals two generations of metamorphic zircon with evolving REE content that is intimately related to garnet growth and decomposition.Zircon age of 36–5.3 Ma is ascribed to syn-to post-M1 metamorphism,whereas the young zircon age of 5.1–3.8 Ma is linked to syn-and post-M2 stage.The UHT metamorphism was probably the consequence of the upwelling of asthenospheric mantle triggered by post-collisional delamination of lithosphere in the MiocenePliocene(ca.5 Ma).It could represent the youngest known UHT metamorphism on Earth.展开更多
Ferroelectric barium titanate nanoparticles(BTO NPs)may play critical roles in miniaturized passive electronic devices such as multi-layered ceramic capacitors.While increasing experimental and theoretical understandi...Ferroelectric barium titanate nanoparticles(BTO NPs)may play critical roles in miniaturized passive electronic devices such as multi-layered ceramic capacitors.While increasing experimental and theoretical understandings on the structure of BTO and doped BTO have been developed over the past decade,the majority of the investigation was carried out in thin-film materials;therefore,the doping effect on nanoparticles remains unclear.Especially,doping-induced local composition and structure fluctuation across single nanoparticles have yet to be unveiled.In this work,we use electron microscopy-based techniques including high-angle annular dark-field scanning transmission electron microscopy(HAADF-STEM),integrated differential phase contrast(iDPC)-STEM,and energy dispersive X-ray spectroscopy(EDX)mapping to reveal atomically resolved chemical and crystal structure of BTO and strontium doped BTO nanoparticles.Powder X-ray diffraction(PXRD)results indicate that the increasing strontium doping causes a structural transition from tetragonal to cubic phase,but the microscopic data validate substantial compositional and microstructural inhomogeneities in strontium doped BTO nanoparticles.Our work provides new insights into the structure of doped BTO NPs and will facilitate the materials design for next-generation high-density nano-dielectric devices.展开更多
基金financially supported by the National Natural Science Foundation of China(Grant Nos.41172055 and 41121062)the China Survey of Geology(1212011121062)
文摘An arguable point regarding the Neoarchean and Paleoproterozoic crustal evolution of the North China Craton（NCC）is whether the tectonic setting in the central belt during the mid-Paleoproterozoic（2.35-2.0 Ga）was dominated by an extensional regime or an oceanic subduction-arc regime.A review of the midPaleoproterozoic magmatism and sedimentation for the Hengshan-Wutai-Fuping region suggests that a back-arc extension regime was dominant in this region.This conclusion is consistent with the observation that the 2.35-2.0 Ga magmatism shows a typical bimodal distribution where the mafic rocks mostly have arc affinities and the acidic rocks mainly comprise highly-fractioned calc-alkaline to alkaline（or A-type）granites,and that this magmatism was coeval with development of extensional basins characteristic of transgressive sequences with volcanic interlayers such as in the Hutuo Group.Although the final amalgamation of the NCC was believed to occur at ～1.85 Ga,recent zircon U-Pb age dating for mica schist in the Wutai Group suggests a collisional event may have occurred at ～1.95 Ga.The metamorphic ages of ～1.85 Ga,obtained mostly from the high-grade rocks using the zircon U-Pb approach,most probably indicate uplifting and cooling of these high-grade terranes.This is because（i）phase modeling suggests that newly-grown zircon grains in highgrade rocks with a melt phase cannot date the age of peak pressure and temperature stages,but the age of melt crystallization in cooling stages;（ii）the metamorphic P-T paths with isobaric cooling under 6-7 kb for the Hengshan and Fuping granulites suggest their prolonged stay in the middle-lower crust;and（iii）the obtained metamorphic age data show a continuous distribution from 1.95 to 1.80 Ga.Thus,an alternative tectonic scenario for the Hengshan-Wutai-Fuping region involves：（i）formation of a proto-NCC at ～2.5 Ga;（ii）back-arc extension during 2.35-2.0 Ga resulting in bimodal magmatism and sedimentation in rifting basins on an Archean basement;（iii）a crustal thickening event in the extended region resulting in a kyanitetype metamorphism at ～1.95 Ga,and（iv） uplifting and cooling of the thickened crust from 1.93 to 1.80 Ga.
基金supported by the National Natural Science Foundation of China[42025204,41890831,41803029,41973025 and 92155306]Guangdong Province Introduced Innovative R&D Team of Geological Processes and Natural Disasters around the South China Sea[2016ZT06N331]HKU Seed Fund for Basic Research[201811159089].
文摘Ultrahigh-temperature(UHT)metamorphism represents an extreme crustal thermal event with peak conditions exceeding 900C at 7–13 kbar.In the modern-style plate tectonic system,records of the UHT metamorphism are relatively rare due to the secular cooling of Earth.In the Palu region of Western Sulawesi,we newly discovered a series of HT-UHT metamorphic rocks including amphibolite,granulite,eclogites and gneiss.Of them,two granulite samples(18CS14-2,18CS14-4)with high garnet content(>50 mol%)are chosen for petrographic observation,phase equilibrium modelling,and zircon U-Pb dating.These rocks are characterized by a relic M1 assemblage of Grt+Ky+Bt+Rt and a M2 assemblage of Grt+Sil+Pl+Spl+Crd±Qtz+Ilm+melt.Phase equilibrium modelling based on effective bulk compositions yields UHT conditions of 7.2–8.5 kbar/940–1080C(18CS14-2)and 7.0–7.3 kbar/1000–1040C(18CS14-4).U-Pb analysis reveals two generations of metamorphic zircon with evolving REE content that is intimately related to garnet growth and decomposition.Zircon age of 36–5.3 Ma is ascribed to syn-to post-M1 metamorphism,whereas the young zircon age of 5.1–3.8 Ma is linked to syn-and post-M2 stage.The UHT metamorphism was probably the consequence of the upwelling of asthenospheric mantle triggered by post-collisional delamination of lithosphere in the MiocenePliocene(ca.5 Ma).It could represent the youngest known UHT metamorphism on Earth.
基金This work was supported by the National Natural Science Foundation of China(Nos.21625304,21872163,21991153,22072090,21991153,and 21991150)L.C.acknowledges the support from the Ministry of Science and Technology(No.2016YFA0200703)P.L.acknowledges the financial support from the Carlsberg Foundation.
文摘Ferroelectric barium titanate nanoparticles(BTO NPs)may play critical roles in miniaturized passive electronic devices such as multi-layered ceramic capacitors.While increasing experimental and theoretical understandings on the structure of BTO and doped BTO have been developed over the past decade,the majority of the investigation was carried out in thin-film materials;therefore,the doping effect on nanoparticles remains unclear.Especially,doping-induced local composition and structure fluctuation across single nanoparticles have yet to be unveiled.In this work,we use electron microscopy-based techniques including high-angle annular dark-field scanning transmission electron microscopy(HAADF-STEM),integrated differential phase contrast(iDPC)-STEM,and energy dispersive X-ray spectroscopy(EDX)mapping to reveal atomically resolved chemical and crystal structure of BTO and strontium doped BTO nanoparticles.Powder X-ray diffraction(PXRD)results indicate that the increasing strontium doping causes a structural transition from tetragonal to cubic phase,but the microscopic data validate substantial compositional and microstructural inhomogeneities in strontium doped BTO nanoparticles.Our work provides new insights into the structure of doped BTO NPs and will facilitate the materials design for next-generation high-density nano-dielectric devices.
