Ternary sulfide solid solutions have garnered great attention in photocatalytic water splitting due to their tunable electronic property,low cost,and sufficient light-absorption performance.Herein,a series of Mn_(x)Cd...Ternary sulfide solid solutions have garnered great attention in photocatalytic water splitting due to their tunable electronic property,low cost,and sufficient light-absorption performance.Herein,a series of Mn_(x)Cd_(1-x)S samples with different Mn/Cd molar ratios were synthesized by solvothermal method and used for photocatalytic hydrogen production under visible light.The Mn_(0.2)Cd_(0.8)S and Mn_(0.4)Cd_(0.6)S are demonstrated to be the solid so-lutions,while Mn_(0.6)Cd_(0.4)S and Mn_(0.8)Cd_(0.2)S consist of Mn_(x)Cd_(1-x)S solid solution and MnS.In addition,the Mn_(0.4)Cd_(0.6)S exhibits the highest photocatalytic performance with the H_(2) production rate of 185.95μmol·h^(-1),which is 4.7 times higher than that of CdS.Without cocatalyst,the quantum efficiency of Mn_(0.4)Cd_(0.6)S reaches 2.04%at 400 nm.In addition,the Mn_(0.4)Cd_(0.6)S solid solution also shows high stability during the photocatalytic H_(2) production reaction.The effect of Mn/Cd molar ratio on the microstructure,band gap structure,and photo-catalytic hydrogen production performance of Mn_(x)Cd_(1-x)S was revealed systematically.The excellent photo-catalytic H_(2) production performance of Mn_(0.4)Cd_(0.6)S solid solution is mainly due to its enhanced reducing potential and high charge separation efficiency.展开更多
Stereodivergently constructing the designed products having adjacent multi-stereocenters via a given reaction,with excellent control of both absolute and relative configurations,presents one of the substantial hurdles...Stereodivergently constructing the designed products having adjacent multi-stereocenters via a given reaction,with excellent control of both absolute and relative configurations,presents one of the substantial hurdles in asymmetric catalysis.Herein,we report a precisely stereodivergent asymmetric protocol by synergistic combination of phosphonium-involved ion-pair catalysis and base for accessing to chiral phosphorus compounds bearing two adjacent chiral centers particularly containing an acidic protonated enantioenriched carbon atom,having broad functional group compatibility in both dynamic and thermodynamic processes under mild reaction conditions.Two keys for the success in constructing these stereoisomers with high levels of regio-,diastereo-,and enantioselectivities were contained:firstly,the precise stereo-control in providing dynamic products was enabled by bifunctional phosphonium salt catalyst with semi-enclosed cavity;secondly,the readily stereospecific transformation of adducts from dynamic to thermodynamic version was initiated by achiral base.All four stereoisomers could be readily accessed even in gram-scale in high yields with maintaining excellent stereoselectivities,illustrating the potential of this synergistic catalytic methodology in organic synthesis.Moreover,mechanistic studies including density functional theory(DFT)calculations and control experiments provide insights into the mechanism.展开更多
The effects of the rare earth element yttrium(Y) and hot extrusion on the microstructure and mechanical properties of A356 alloy were investigated by mechanical properties testing and microstructure observation. The r...The effects of the rare earth element yttrium(Y) and hot extrusion on the microstructure and mechanical properties of A356 alloy were investigated by mechanical properties testing and microstructure observation. The results indicate that the addition of Y improves the microstructure of the as-cast alloy. The distribution of primary α-Al is uniform and orderly. The long needle-like eutectic Si phases and β-Fe phases turn to strips and short rods. When the content of Y increases to 0.2 wt%, the mean diameter of aAl(40.3 μm) and the aspect ratio of the eutectic Si phase(2.3) reach the minimum values, which are68.9% and 86.1% lower, respectively, than that of the alloy without Y addition. Under extrusion stress, the shape of the eutectic Si phase is changed from long rod-like to near grain-like after solution treatment.The size of the eutectic Si phase is significantly reduced. The needle-like β-Fe phases are squeezed and broken. The mechanical properties of the as-extruded alloy are significantly improved compared to the as-cast alloy. When the rare earth content is 0.2 wt%, the ultimate tensile strength, hardness and elongation of the alloy reach the maximum values, which are 328.2 MPa, 110.4 HV and 21.3%, respectively, and increase by 42.01%, 37.71% and 481.91%, respectively, in comparison to the as-cast alloy without Y addition.展开更多
In trees,stem secondary growth depends on vascular cambium proliferation activity and subsequent cell differentiation,in which an auxin concentration gradient across the cambium area plays a crucial role in regulating...In trees,stem secondary growth depends on vascular cambium proliferation activity and subsequent cell differentiation,in which an auxin concentration gradient across the cambium area plays a crucial role in regulating the process.However,the underlying molecular mechanismfor the establishment of auxin concentration is not fully understood.In this study,we identified two function-unknown MADS-box genes,VCM1 and VCM2,which are expressed specifically in the vascular cambium and modulate the subcellular homeostasis of auxin.Simultaneous knockdown of both VCM1 and VCM2 enhanced vascular cambium proliferation activity and subsequent xylem differentiation.Overexpression of VCM1 suppressed vascular cambium activity and wood formation by regulating PIN5 expression,which tuned the soluble auxin concentration in the vascular cambium area.This study reveals the role of VCM1 and VCM2 in regulating the proliferation activity of the vascular cambium and secondary growth by modulating the subcellular auxin homeostasis in Populus.展开更多
基金supported by the National Natural Science Foundation of China(22208065,22078074)Natural Science Foundation of Guangxi Province(2022GXNSFBA035483,2020GXNSFDA297007)+2 种基金Opening Project of Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology(2021K009)Special Funding for‘Guangxi Bagui Scholars’National College Students'Innovation and Entrepreneurship Training Programs(202210593011).
文摘Ternary sulfide solid solutions have garnered great attention in photocatalytic water splitting due to their tunable electronic property,low cost,and sufficient light-absorption performance.Herein,a series of Mn_(x)Cd_(1-x)S samples with different Mn/Cd molar ratios were synthesized by solvothermal method and used for photocatalytic hydrogen production under visible light.The Mn_(0.2)Cd_(0.8)S and Mn_(0.4)Cd_(0.6)S are demonstrated to be the solid so-lutions,while Mn_(0.6)Cd_(0.4)S and Mn_(0.8)Cd_(0.2)S consist of Mn_(x)Cd_(1-x)S solid solution and MnS.In addition,the Mn_(0.4)Cd_(0.6)S exhibits the highest photocatalytic performance with the H_(2) production rate of 185.95μmol·h^(-1),which is 4.7 times higher than that of CdS.Without cocatalyst,the quantum efficiency of Mn_(0.4)Cd_(0.6)S reaches 2.04%at 400 nm.In addition,the Mn_(0.4)Cd_(0.6)S solid solution also shows high stability during the photocatalytic H_(2) production reaction.The effect of Mn/Cd molar ratio on the microstructure,band gap structure,and photo-catalytic hydrogen production performance of Mn_(x)Cd_(1-x)S was revealed systematically.The excellent photo-catalytic H_(2) production performance of Mn_(0.4)Cd_(0.6)S solid solution is mainly due to its enhanced reducing potential and high charge separation efficiency.
基金supported by the National Natural Science Foundation of China(21971165,21921002)the National Key R&D Program of China(2018YFA0903500)+3 种基金the“1000-Youth Talents Program”(YJ201702)the Fundamental Research Funds from Sichuan University(2020SCUNL108)Beijing National Laboratory for Molecular Sciences(BNLMS202101)the Fundamental Research Funds for the Central Universities。
文摘Stereodivergently constructing the designed products having adjacent multi-stereocenters via a given reaction,with excellent control of both absolute and relative configurations,presents one of the substantial hurdles in asymmetric catalysis.Herein,we report a precisely stereodivergent asymmetric protocol by synergistic combination of phosphonium-involved ion-pair catalysis and base for accessing to chiral phosphorus compounds bearing two adjacent chiral centers particularly containing an acidic protonated enantioenriched carbon atom,having broad functional group compatibility in both dynamic and thermodynamic processes under mild reaction conditions.Two keys for the success in constructing these stereoisomers with high levels of regio-,diastereo-,and enantioselectivities were contained:firstly,the precise stereo-control in providing dynamic products was enabled by bifunctional phosphonium salt catalyst with semi-enclosed cavity;secondly,the readily stereospecific transformation of adducts from dynamic to thermodynamic version was initiated by achiral base.All four stereoisomers could be readily accessed even in gram-scale in high yields with maintaining excellent stereoselectivities,illustrating the potential of this synergistic catalytic methodology in organic synthesis.Moreover,mechanistic studies including density functional theory(DFT)calculations and control experiments provide insights into the mechanism.
基金Project supported by the Natural Science Foundation of Jiangxi Province(20171BAB206034,20181BAB206026)
文摘The effects of the rare earth element yttrium(Y) and hot extrusion on the microstructure and mechanical properties of A356 alloy were investigated by mechanical properties testing and microstructure observation. The results indicate that the addition of Y improves the microstructure of the as-cast alloy. The distribution of primary α-Al is uniform and orderly. The long needle-like eutectic Si phases and β-Fe phases turn to strips and short rods. When the content of Y increases to 0.2 wt%, the mean diameter of aAl(40.3 μm) and the aspect ratio of the eutectic Si phase(2.3) reach the minimum values, which are68.9% and 86.1% lower, respectively, than that of the alloy without Y addition. Under extrusion stress, the shape of the eutectic Si phase is changed from long rod-like to near grain-like after solution treatment.The size of the eutectic Si phase is significantly reduced. The needle-like β-Fe phases are squeezed and broken. The mechanical properties of the as-extruded alloy are significantly improved compared to the as-cast alloy. When the rare earth content is 0.2 wt%, the ultimate tensile strength, hardness and elongation of the alloy reach the maximum values, which are 328.2 MPa, 110.4 HV and 21.3%, respectively, and increase by 42.01%, 37.71% and 481.91%, respectively, in comparison to the as-cast alloy without Y addition.
基金supported by the Ministry of Science and Technology of the People’s Republic of China(2016YFD0600104)the National Natural Science Foundation of China(31630014)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB27020104).
文摘In trees,stem secondary growth depends on vascular cambium proliferation activity and subsequent cell differentiation,in which an auxin concentration gradient across the cambium area plays a crucial role in regulating the process.However,the underlying molecular mechanismfor the establishment of auxin concentration is not fully understood.In this study,we identified two function-unknown MADS-box genes,VCM1 and VCM2,which are expressed specifically in the vascular cambium and modulate the subcellular homeostasis of auxin.Simultaneous knockdown of both VCM1 and VCM2 enhanced vascular cambium proliferation activity and subsequent xylem differentiation.Overexpression of VCM1 suppressed vascular cambium activity and wood formation by regulating PIN5 expression,which tuned the soluble auxin concentration in the vascular cambium area.This study reveals the role of VCM1 and VCM2 in regulating the proliferation activity of the vascular cambium and secondary growth by modulating the subcellular auxin homeostasis in Populus.