The development of high-performance and low-cost oxygen reduction and evolution catalysts that can be easily integrated into existing devices is crucial for the wide deployment of energy storage systems that utilize O...The development of high-performance and low-cost oxygen reduction and evolution catalysts that can be easily integrated into existing devices is crucial for the wide deployment of energy storage systems that utilize O2-H2O chemistries, such as regenerative fuel cells and metal-air batteries. Herein, we report an NHB-activated N-doped hierarchical carbon （NHC） catalyst synthesized via a scalable route, and demonstrate its device integration. The NHC catalyst exhibited good performance for both the oxygen reduction reaction （ORR） and the oxygen evolution reaction （OER）, as demonstrated by means of electrochemical studies and evaluation when integrated into the oxygen electrode of a regenerative fuel cell. The activities observed for both the ORR and the OER were comparable to those achieved by state-of-the-art Pt and Ir catalysts in alkaline environments. We have further identified the critical role of carbon defects as active sites for electrochemical activity through density functional theory calculations and high-resolution TEM visualization. This work highlights the potential of NHC to replace commercial precious metals in regenerative fuel cells and possibly metal-air batteries for cost-effective storage of intermittent renewable energy.展开更多
The newly-built single-level rail-cum-road bridge brings the issue of the aerodynamic impact of train-induced wind on road automobiles.This research introduced a validated computational fluid dynamics(CFD)model regard...The newly-built single-level rail-cum-road bridge brings the issue of the aerodynamic impact of train-induced wind on road automobiles.This research introduced a validated computational fluid dynamics(CFD)model regarding this concern.Such an aerodynamic impact mechanism was explored;a relationship between the transverse distance between train and motor-van(hereinfafter referred to as van)and the aerodynamic effects on the van was explored to help the optimization of bridge decks,and the relationship between the automobile speed and aerodynamic variations of a van was fitted to help traffic control.The fitting results are accurate enough for further research.It is noted that the relative speed of the two automobiles is not the only factor that influences the aerodynamic variations of the van,even at a confirmed relative velocity,the aerodynamic variations of the van vary a lot as the velocity proportion changes,and the most unfavorable case shows an increase of over 40%on the aerodynamic variations compared to the standard case.The decay of the aerodynamic effects shows that not all the velocity terms would enhance the aerodynamic variations;the coupled velocity term constrains the variation amplitude of moments and decreases the total amplitude by 20%–40%.展开更多
文摘The development of high-performance and low-cost oxygen reduction and evolution catalysts that can be easily integrated into existing devices is crucial for the wide deployment of energy storage systems that utilize O2-H2O chemistries, such as regenerative fuel cells and metal-air batteries. Herein, we report an NHB-activated N-doped hierarchical carbon （NHC） catalyst synthesized via a scalable route, and demonstrate its device integration. The NHC catalyst exhibited good performance for both the oxygen reduction reaction （ORR） and the oxygen evolution reaction （OER）, as demonstrated by means of electrochemical studies and evaluation when integrated into the oxygen electrode of a regenerative fuel cell. The activities observed for both the ORR and the OER were comparable to those achieved by state-of-the-art Pt and Ir catalysts in alkaline environments. We have further identified the critical role of carbon defects as active sites for electrochemical activity through density functional theory calculations and high-resolution TEM visualization. This work highlights the potential of NHC to replace commercial precious metals in regenerative fuel cells and possibly metal-air batteries for cost-effective storage of intermittent renewable energy.
基金The writers are grateful for the financial support from the National Natural Science Foundation of China(Grant Nos.51778544,51978589)the Fundamental Research Funds for the Central Universities(No.2682021CG014).
文摘The newly-built single-level rail-cum-road bridge brings the issue of the aerodynamic impact of train-induced wind on road automobiles.This research introduced a validated computational fluid dynamics(CFD)model regarding this concern.Such an aerodynamic impact mechanism was explored;a relationship between the transverse distance between train and motor-van(hereinfafter referred to as van)and the aerodynamic effects on the van was explored to help the optimization of bridge decks,and the relationship between the automobile speed and aerodynamic variations of a van was fitted to help traffic control.The fitting results are accurate enough for further research.It is noted that the relative speed of the two automobiles is not the only factor that influences the aerodynamic variations of the van,even at a confirmed relative velocity,the aerodynamic variations of the van vary a lot as the velocity proportion changes,and the most unfavorable case shows an increase of over 40%on the aerodynamic variations compared to the standard case.The decay of the aerodynamic effects shows that not all the velocity terms would enhance the aerodynamic variations;the coupled velocity term constrains the variation amplitude of moments and decreases the total amplitude by 20%–40%.
