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“一体化”共价有机框架光催化二氧化碳还原研究 被引量:1
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作者 宋邓萌 许文华 +5 位作者 李珺 赵佳乐 史晴 李斐 孙旭镯 王宁 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第9期2425-2433,共9页
自工业革命以来,温室气体CO_(2)大量排放使得环境问题日益突出,严重制约了人类的生存和发展.人工光合作用可利用取之不尽的阳光作为驱动力,将CO_(2)还原为可实际应用的化学燃料(CO、HCOOH等).人工光合作用体系通常包括两部分:光敏剂和... 自工业革命以来,温室气体CO_(2)大量排放使得环境问题日益突出,严重制约了人类的生存和发展.人工光合作用可利用取之不尽的阳光作为驱动力,将CO_(2)还原为可实际应用的化学燃料(CO、HCOOH等).人工光合作用体系通常包括两部分:光敏剂和催化剂.光敏剂吸收入射光的能量,电子由基态(价带)跃迁至激发态(导带);处于激发态的光敏剂将电子转移到催化剂上;最终由催化剂实现CO_(2)还原.对光敏剂和催化剂进行合理的调变可以构建更加高效、稳定的人工光合作用体系.共价有机框架(COFs)材料是由轻元素(C,H,O,N,B等)组成的有机小分子构筑单元通过动态共价键组装,所形成的具有预先设计的拓扑结构的一维、二维或三维的晶态有机多孔骨架材料.自从2005年首次报道COFs材料的成功合成以来,COFs逐渐地发展成为了一种具有高潜力和广泛的功能化应用前景的多孔骨架聚合物.特别是二维共价有机框架(2D-COFs).2D-COFs独特的平面扩展共轭π-π结构,使其具有较好的光吸收性能,轴向的π堆叠结构,有利于光生电荷的分离和转移,2D-COFs材料在光催化领域极具应用潜质.本文以四(4-氨基苯基)卟啉和Re(bpy)(CO)_(3)Cl为结构单元,通过希夫碱反应合成了一种集光敏剂和催化剂于一体的2D-COF.所制H_(2)PRebpy-COF不仅继承两种单体与COF的性能特点,并且使三者充分融合、相互促进:(1)卟啉对可见光具有较好的吸收能力,形成COF后扩展了其π-π共轭结构,从而增大了光吸收范围;(2)作为最常见的CO_(2)还原催化剂,大量内置的Re(bpy)(CO)_(3)Cl赋予了H_(2)PRebpy-COF催化CO_(2)还原的能力;(3)通过较为稳定的共价键和配位键将Re(bpy)(CO)_(3)Cl修饰在COF结构中,抑制了其在催化过程中发生的二聚失活.在可见光照射下,H_(2)PRebpy-COF光催化CO_(2)还原的产物为CO和HCOOH,其中CO的产率达到1200μmol g^(−1) h^(−1),选择性为78%.同等条件下,不含Re(bpy)(CO)_(3)Cl催化中心的参比物H_(2)Pbpy-COF则几乎没有催化活性.^(13)C同位素标记实验结果表明CO_(2)还原反应产物中的C来源于反应物CO_(2),而非催化体系中其他物质的分解.经过三次催化循环后,H_(2)PRebpy-COF的扫描电镜、红外光谱图与反应前基本一致,说明结构具有一定的稳定性.最后,结合实验和DFT计算对光催化CO_(2)还原过程提出了一种可能的催化机理:在可见光的驱动下,卟啉吸收光的能量,受激发的电子从卟啉(HOMO中心)转移到Re(bpy)(CO)_(3)Cl(LUMO中心);Re(bpy)(CO)_(3)Cl作为催化活性中心实现CO_(2)还原.综上,从微观到宏观,充分利用各结构的特点,合成具有特定结构的COFs,从而具有更优异的性能. 展开更多
关键词 共价有机框架 光催化二氧化碳还原 卟啉 Re配合物 可见光
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Design and testing of planting unit for rice dry-direct-seeding planter in cold region
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作者 jiale zhao Chengliang Zhang +4 位作者 Yanpeng Wei Mingzhuo Guo Chao Chen Chongqin Zhang Yungan Zhang 《International Journal of Agricultural and Biological Engineering》 SCIE 2023年第4期76-84,共9页
Rice dry-direct-seeding technology is a time-saving,cost-saving and efficient rice cultivation technique that increases the efficiency of seeding.In order to implement the specialization,light simplicity and scale of ... Rice dry-direct-seeding technology is a time-saving,cost-saving and efficient rice cultivation technique that increases the efficiency of seeding.In order to implement the specialization,light simplicity and scale of rice production,improve the level of mechanization of the whole rice production process,and solve the problems of uneven seed furrows,uneven number of seeds sown,shallow mulching and uncompact repression that occur during the promotion and application of dry-direct-seeding for rice in the cold region of northeast China.In this paper,a planting unit for rice dry-direct-seeding planter is designed.The working principles and structural parameters of the furrow opening components,the seeding apparatus and the soil covering-pressing device are described.The mechanical model of the key components of the seeding unit was established,and the forward speed,roller diameter and compacting strength were selected as the test factors.A three-factor,five-level quadratic rotation orthogonal combination test was conducted with the seed breakage rate,seeding depth qualification rate,seeding uniformity coefficient of variation and hole grain count qualification rate as the evaluation indexes.Field performance test and test results show that:at a forward speed of 4 km/h,a roller diameter of 427 mm and a compacting strength of 48.45 kPa,the seed breakage rate was 1.31%,the sowing depth qualification rate was 9.95%,the coefficient of variation of sowing uniformity was 3.75%and the number of holes was 86.75%.This accords with the agronomic requirements of dry-directseeding for rice and implements a combination of superior agronomy and modern farm machinery. 展开更多
关键词 RICE dry-direct-seeding planting unit structural design testing research
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Design and key parameter optimization of an agitated soybean seed metering device with horizontal seed filling 被引量:8
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作者 Honglei Jia Yulong Chen +3 位作者 jiale zhao Mingzhuo Guo Dongyan Huang Jian Zhuang 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2018年第2期76-87,共12页
Since the low seed filling speed of mechanical seed metering devices reduces the low qualified rate of seed spacing during high-speed practices,it is significant to design agitated seed metering devices with horizonta... Since the low seed filling speed of mechanical seed metering devices reduces the low qualified rate of seed spacing during high-speed practices,it is significant to design agitated seed metering devices with horizontal seed filling that are suitable for high-speed practices.The combination of horizontal seed filling and agitated seed filling can accelerate the seed filling of mechanical seed metering devices,and improve the qualified rate of seed spacing during high-speed practices.In this study,theoretical analysis,discrete element method-based simulation and indoor bench test verification were conducted to investigate how key parameters of the agitated seed metering device with horizontal seed filling(angles,installation position and number of agitating plates,diameters of convex spoons)would affect the characteristics of soybean seed movement,seed number and seeding performance(qualified index,multiple index,missing seeding index)under different working speeds.Computer-based simulation,test design and regression analysis were combined to analyze the population moving rules and optimize the design parameters of seed metering devices.Based on the test scheme as designed,simulations were conducted on Fluent EDEM,and the optimal angle of the agitating plates was determined by analyzing the population migrating rules.Regression equations were established through the regression of test results,and used to find out the optimal design parameters(diameter of convex spoon,positions and number of agitating plates)of seed metering devices.Then the optimal parameter combination among different working conditions was determined that the angle,position and number of agitating plates were 30°,24.4 mm,and 13,respectively,and the diameter of convex spoon was 11.0 mm.With the optimal parameter combination and at the seeding speed of 12 km/h,the qualified index,multiple index and missing seeding index were 93.1%,2.1%and 4.8%,respectively.Under high-speed practices,the new seed metering device was not significantly different from the pneumatic seed metering device,but significantly outperformed the mechanical seed metering device. 展开更多
关键词 soybean seed metering device horizontal seed filling agitated seed filling high-speed precision seeding discrete element method
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Design of bionic locust mouthparts stubble cutting device 被引量:4
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作者 jiale zhao Mingzhuo Guo +2 位作者 Yun Lu Dongyan Huang Jian Zhuang 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2020年第1期20-28,共9页
Given the technical problems of low maize stubble breaking efficiency,large cutting torque and high power consumption faced during springtime no-till planting in Northeast China,we designed a high-performance coupling... Given the technical problems of low maize stubble breaking efficiency,large cutting torque and high power consumption faced during springtime no-till planting in Northeast China,we designed a high-performance coupling bionic stubble cutting device capable by integrating the structure(multi-segment and serrate)and cutting mode(isokinetic and symmetrical)of locust mouthparts.Methods of bionic construction,mechanism design,theoretical analysis,parameter optimization,Arduino systems and intelligent control were combined to design a planetary gear mechanism and an intelligent speed control system.In particular,the bionic cutting blade could reconstruct the multi-segment and serrate structure of locust mouthparts,while the planetary gear mechanism and the intelligent speed control system jointly comprised the bionic drive system,which could simulate the isokinetic and symmetrical cutting mode,thereby bionically coupling morphological structures and movement patterns.Analysis of comparative tests showed the coupling bionic cutting device could reduce the cutting torque by 26.6%-31.6%and the power consumption by 21.9%-26.1%.This work confirmed that coupling bionic method can significantly improve the stubble cutting efficiency,which was a valuable contribution to the design of stubble cutting device for no-till planter. 展开更多
关键词 BIONICS locust mouthparts cutting device corn stubble
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Biomimetic earthworm dynamic soil looser for improving soybean emergence rate in cold and arid regions 被引量:1
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作者 jiale zhao Xiaogeng Wang +3 位作者 Yun Lu Yanpeng Wei Mingzhuo Guo Jun Fu 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2021年第3期22-31,共10页
In cold and arid regions,soil moisture content and accumulated temperature were seriously insufficient during spring sowing,which made it difficult for soybean seedling to emerge.Based on the principle of earthworm op... In cold and arid regions,soil moisture content and accumulated temperature were seriously insufficient during spring sowing,which made it difficult for soybean seedling to emerge.Based on the principle of earthworm optimization and improvement of soil structure,this study innovatively designed a biomimetic earthworm dynamic soil looser through bionic design and theoretical calculation.By highly reducing the movement path and mode of earthworm in the soil,the mechanism could improve the soil temperature(ST)and soil moisture content(SMC),and thus greatly improve the soybean emergence rate(SER).In this study,the effects of biomimetic earthworm dynamic soil looser and its design parameters on soil temperature(ST),soil moisture content(SMC)and soybean emergence rate(SER)were investigated by two-factor test,analysis of variance(ANOVA)and Least significant Difference(LSD).Regression analysis was used to establish the mathematical model between design parameters and soybean emergence rate.MATLAB software was used to optimize the model,and the optimal design parameter combination was obtained.The contrast experiments showed that the biomimetic earthworm dynamic soil looser could construct the soil structure more suitable for the cold and arid regions.Compared with rotary blade(RB)and notched disc harrow(DH),biomimetic earthworm dynamic soil looser could increase soil moisture content by 41.30%and 27.50%,respectively.Compared with the notched disc harrow,the soil temperature could be increased by 7.97%.There was no significant difference between the effect of rotary blade on soil temperature(p>0.05).The soybean emergence rate was increased by 25.40%and 20.70%,respectively,compared with that of notched disc harrow and rotary blade. 展开更多
关键词 BIONICS EARTHWORM TILLAGE soil temperature soil moisture content soybean emergence rate
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Design of bionic mole forelimb intelligent row cleaners 被引量:1
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作者 Honglei Jia Qi Wang +3 位作者 Dongyan Huang Longtu Zhu Mingwei Li jiale zhao 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2019年第3期27-35,共9页
In Northeast China under no-till conditions the amount of maize stubble of the previous year's crop severely limit the quality of sowing operations by unstable operating depth of normal planter row cleaners.Thus,i... In Northeast China under no-till conditions the amount of maize stubble of the previous year's crop severely limit the quality of sowing operations by unstable operating depth of normal planter row cleaners.Thus,in this study,bionic mole forelimb intelligent row cleaners comprising of a cleaning device and a depth intelligent control system were designed.Via theoretical analysis,computer-based simulation,and test optimized design,the mechanism of bionic cleaners that possessed the forelimb motion morphology and the front claw toe structural morphology of moles was studied,the effects of structural parameters of bionic cleaners on the cleaning quality were clarified.Based on a pressure sensor,a depth intelligent control system was designed,which enhanced the depth stability of the cleaning devices.The types of bionic cleaners were identified by simulation on EDEM software.Then regression equations between different parameters and operation evaluation indices were established,and the optimal parameter combination was identified on Design-Expert software with a rotation radius of 150 mm and a motion deflection angle of 15.8°,at which the cleaning rate was 91.3%.Field tests under the optimal parameter combination showed that bionic cleaners outperformed normal planar cleaners,and the depth intelligent control system could efficiently improve the performance of the row cleaners.The straw cleaning rate of the bionic mole forelimb intelligent row cleaners under total straw mulching fields was 90.9%,which was 21.3%higher than that of normal cleaners,and the ground surfaces after operation satisfied the agricultural requirements of maize no-tillage sowing. 展开更多
关键词 bionic mole forelimb intelligent row cleaners intelligent control systems no-till sowing corn production residue management
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Design and test of bionic wide-ridge soybean tilling-sowing machine 被引量:1
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作者 Honglei Jia Mingzhuo Guo +3 位作者 jiale zhao Dongyan Huang Jian Zhuang Jiangtao Qi 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2019年第1期42-51,共10页
The insufficient accumulated temperature of the plow layer during spring tillage in Northeast China severely restricts soybean root growth and whole-plant development.High regional soil viscosity further complicates t... The insufficient accumulated temperature of the plow layer during spring tillage in Northeast China severely restricts soybean root growth and whole-plant development.High regional soil viscosity further complicates tilling-sowing.In order to seek a solution to these problems,field comparative tests were conducted to investigate the effects of shallow-loosening(SL)and reshaping ridge(RR)on soil temperature and soybean root growth.Compared with conventional tillage(CT),SL and RR significantly increased the soil temperatures within 0-25 cm(p<0.05)and 0-15 cm(p<0.05),respectively.In particular,higher soil temperature within 15-25 cm was established after SL than after RR(p<0.05).Additionally,SL promoted substantially more vigorous soybean development(seedling height)than RR(p<0.05),which in turn led to a significant outperformance over CT(p<0.05).Further,bionics,reverse engineering,and curve fitting were combined to design a hare claw toe bionic shallow-loosening shovel and a pangolin scale bionic ridging shovel with anti-drag functions.Field verification tests confirmed that these two bionic tillage devices outperformed the conventional tillage device in reducing tractive drag by 13%-19%.Based on the results of these tests,a 2BGD-6(110)bionic wide-ridge soybean tilling-sowing machine was designed,which was capable of shallow-loosening,reshaping ridge and sowing.The new machine significantly reduced the tractive drag,efficiently loosened the soil,increased soil temperature,and accelerated soybean root growth.This study can provide a theoretical and practical reference for soybean production in Northeast China. 展开更多
关键词 BIONICS tillage shallow-loosening SOYBEAN reshaping ridge soil temperature
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Design and experiment of a subsoiling variable rate fertilization machine 被引量:1
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作者 Jiangtao Qi Xinliang Tian +4 位作者 Yang Li Xuhui Fan Hongfang Yuan jiale zhao Honglei Jia 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2020年第4期118-124,共7页
In order to improve soil fertility and fertilizer utilization,a subsoiling variable rate fertilization machine based on conservation tillage and precision agriculture was designed and tested.The relationship between s... In order to improve soil fertility and fertilizer utilization,a subsoiling variable rate fertilization machine based on conservation tillage and precision agriculture was designed and tested.The relationship between suspension parameters and penetrating distance was analyzed,and a matching model between fertilizing quantity and penetrating distance was established.The variable rate fertilization control machine was developed based on an Advantech PCM-9363 industrial control mainboard.The machine operates under two patterns:DGPS-based positioning and straight-line path positioning based on a planar coordinate system.This machine can perform on-demand fertilization according to the spatial differences in soil nutrients and the prescription maps pre-set before the operation.Field experiments showed the machine has a subsoiling stability of 92.5%,a soil breaking rate of 61.1%,a maximum positioning relative error of 2.68%and a maximum variable rate fertilization error of 3.89%.The subsoiling performance and variable rate fertilization indices of this machine satisfy the requirements of GB/T24675.2-2009.The tested indices meet the national and industrial standards and satisfy the design requirements.The findings of the research can be used as the structural design of the subsoiling variable rate fertilization machine. 展开更多
关键词 agricultural machinery conservation tillage precision agriculture SUBSOILING variable rate fertilization
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Design and experiment of bionic stubble breaking-deep loosening combined tillage machine 被引量:1
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作者 jiale zhao Yun Lu +2 位作者 Mingzhuo Guo Jun Fu Yijia Wang 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2021年第4期123-134,I0002,共13页
Under the conditions of straw returning operation,there are three major technical bottlenecks in the Phaeozem region of northeast China,namely low stubble breaking rate,poor tillage depth consistency,and high fuel con... Under the conditions of straw returning operation,there are three major technical bottlenecks in the Phaeozem region of northeast China,namely low stubble breaking rate,poor tillage depth consistency,and high fuel consumption.In this research,a bionic stubble-deep loosening combined tillage machine(BSD)was designed through bionic prototype analysis,coupled bionic analysis,coupled bionic design,theoretical analysis and application of intelligent control techniques.It consists of a bionic stubble breaking device and a bionic self-excited vibratory deep loosening device.Based on the unique biting pattern of locust mouthparts on maize rootstocks,the bionic stubble breaking device adopted a new multi-segment serrated bionic structure and a symmetrical rotational motion,which could significantly increase the stubble breaking rate(p<0.05)and reduce the resistance to stubble breaking operations(p<0.05).Based on the unique biology of the hare’s paws,toes and nails,the bionic self-excited vibration deep loosening device adopted a new series-parallel composite bionic elastic system and an intelligent tilling depth control system with a fuzzy algorithm,which significantly improved the tilling depth consistency(p<0.05).The operational performance of the BSD was verified at different operating speeds through comparative experiments and reveals the mechanism of its excellent performance through theoretical analysis.The final experiment results showed that,at the same operating speed,the BSD improved the stubble breaking rate by 9.62%and 10.67%,reduced the stubble breaking torque by 28 N·m and 33 N·m,reduced the tillage depth coefficient of variation by 12.73%and 13.48%,and reduced the specific fuel consumption by 36 g/km·h and 40 g/km·h compared to the two most common models.The operating performance of the three kinds of machines will decrease with the increase of operating speed,and the BSD has the least decrease. 展开更多
关键词 BIONICS stubble breaking deep loosening combined tillage machine
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Synthesis, structure and electrocatalytic H2-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases
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作者 Dengmeng Song Xuyun Gao +6 位作者 Bo Li Jun Li Xuzhuo Sun Chengbo Li jiale zhao Lin Chen Ning Wang 《Chinese Chemical Letters》 SCIE CAS CSCD 2020年第9期2483-2486,共4页
Structural and functional biomimicking of the active site of [NiFe]-hydrogenases can provide helpful hints for designing bioinspired catalysts to replace the expensive noble metal catalysts for H2 generation and uptak... Structural and functional biomimicking of the active site of [NiFe]-hydrogenases can provide helpful hints for designing bioinspired catalysts to replace the expensive noble metal catalysts for H2 generation and uptake.Treatment of dianion [Ni(phma)]2-[H4 phma=N,N’-1,2-phenylenebis(2-mercaptoacetamide)] with [NiCl2(dppp)](dppp=bis(diphenylphosphino)propane) yielded a dinickel product[Ni(phma)(μ-S,S’)Ni(dppp)](1) as the model complex relevant to the active site of [NiFe]-H2 ases.The structure of complex 1 has been characterized by single-crystal X-ray analysis.From cyclic voltammetry and controlled potential electrolysis studies,complex 1 was found to be a moderate electrocatalyst for the H2-evoluting reaction using ClCH2COOH as the proton source. 展开更多
关键词 HYDROGENASE ELECTROCATALYSIS Hydrogen evolution Nickel complex Metallothiolate ligand
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Screening and impurity removal device to improve the accuracy of moisture content detection device for rice
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作者 Han Tang Changsu Xu +1 位作者 jiale zhao Yijia Wang 《International Journal of Agricultural and Biological Engineering》 SCIE CAS 2022年第6期113-123,共11页
An online detection device that used the capacitance method to detect the moisture content of rice in a combine harvester was designed and found a low detection accuracy because of the high impurity content of the sam... An online detection device that used the capacitance method to detect the moisture content of rice in a combine harvester was designed and found a low detection accuracy because of the high impurity content of the samples.To solve this problem,a screening and impurity removal device was designed in this study,and the structural parameter range of the screw conveyor was the focus of the design.To determine the best structural parameters and operating parameters of the device,models of rice grains and short stems were established by the discrete element method.The Discrete Element Method(DEM)simulation test was carried out according to the Box-Behnken response surface method.When the rotating speed was 300 r/min,the diameter of spiral blade was 146 mm,the pitch was 80 mm,the diameter of rotating shaft was 30.6 mm,and the minimum impurity content was 0.27%.The density distributions and movement characteristics of the rice grains and short stems in the optimized screening and impurity removal device were studied.An experiment was carried out to compare data for the moisture content of rice measured by the online moisture content detection device before and after the installation of the screening and impurity removal device and the results of the 105°C drying method.The results showed that the impurity content of rice ranged from 0.26%to 0.37%,and the maximum effective screening rate was 90.99%after screening.The screening and impurity removal device significantly reduced the error in the moisture content measured by the online detection device,the error range was 0.12%-2.55%.This study provides a method for accurate online detection of moisture content and provides a reference for the design and simulation of related screening devices. 展开更多
关键词 combine harvester parameter optimization RICE motion characteristics discrete element model
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