Composition, source, mass closure of PM_(2.5) aerosols for four forests in eastern China

PM2.5 aerosols were collected in forests along north latitude in boreal-temperate, temperate, subtropical and tropical climatic zones in eastern China, i.e., Changbai Mountain Nature Reserve （CB）, Dongping National Forest Park in Chongming Island （CM）, Dinghu Mountain Nature Reserve （DH）, Jianfengling Nature Reserve in Hainan Island （HN）. The mass concentrations of PM2.5, organic carbon （OC）, elemental carbon （EC）, water soluble organic carbon （WSOC） as well as concentrations of ten inorganic ions （F？, Cl？, NO3？, SO42？, C2O42？, NH4＋, Na＋, K＋, Ca2＋, Mg2＋） were determined. Aerosol chemical mass closures were achieved. The 24-hr average concentrations of PM2.5 were 38.8, 89.2, 30.4, 18 μg/m3 at CB, CM, DH and HN, respectively. Organic matter and EC accounted for 21%–33% and 1.3%–2.3% of PM2.5 mass, respectively. The sum of three dominant secondary ions （SO42-, NO3-, NH4＋） accounted for 44%, 50%, 45% and 16% of local PM2.5 mass at CB, CM, DH and HN, respectively. WSOC comprised 35%–65% of OC. The sources of PM2.5 include especially important regional anthropogenic pollutions at Chinese forest areas.

Polychlorinated biphenyls in the atmosphere of Taizhou,a major e-waste dismantling area in China

PM2.5, total suspended particles （TSP） and gas phase samples were collected at two sites of Talzhou, a major e-waste dismantling area in China. Concentrations, seasonal variations, congener profiles, gas-particle partitioning and size distribution of the atmospheric polychlorinated biphenyls （PCBs） were studied to assess the current state of atmospheric PCBs after the phase out of massive historical dismantling of PCBs containing e-wastes. The average ∑38PCBs concentration in the ambient air （TSP plus gas phase） near the e-waste dismantling area was （12,407 ± 9592） pg/m^3 in winter, which was substantially lower than that found one decade ago. However, the atmospheric PCBs level near the e-waste dismantling area was 54 times of the reference urban site, indicating that the impact of the historical dismantling of PCBs containing e-wastes was still significant. Tri-Penta-CBs were dominant homologues, consisting with their dominant global production. Size distribution of particle-bound PCBs showed that higher chlorinated CBs tended to partition more to the fine particles, facilitating its long range air transportation.

Diurnal variations of polycyclic aromatic hydrocarbons associated with PM_(2.5) in Shanghai, China

Forty-eight daily time interval PM2.5 samples were collected from December 2006 to January 2008 in an urban site in Shanghai, China. Concentrations and compositions of polycyclic aromatic hydrocarbons （PAHs） were analyzed with GC-MS to study the diurnal and seasonal variations and to identify the main emitting sources. The diurnal variation of the PAHs concentrations was greater in the late autumn and winter sampling days, and was greatly influenced by meteorological conditions such as wind speed and ambient temperature. The concentration of PAHs in the mornings （6：30–10：00） increased distinctly, and was high in the late autumn and winter sampling days, indicating the contribution from vehicle emissions during rush hours. The diurnal variation of the high molecular weight PAHs did not seem to be controlled by the shift of gas-particle partitioning due to temperature variation, instead, it could be indicative of the variation in the source. Statistical analyses showed that the concentrations of PAHs were negatively correlated with temperature and wind speed, and positively correlated with relative humidity. Diagnostic ratios of PAHs suggested mixed emission sources of petroleum and coal/biomass combustion for PAHs in the PM2.5 in Shanghai.

Evaluation of regional ionospheric grid model over China from dense GPS observations

The current global or regional ionospheric models have been established for monitoring the ionospheric variations. However, the spatial and temporal resolutions are not enough to describe total electron content（TEC） variations in small scales for China. In this paper, a regional ionospheric grid model（RIGM） with high spatial-temporal resolution（0.5 0.5 and 10-min interval） in China and surrounding areas is established based on spherical harmonics expansion from dense GPS measurements provided by Crustal Movement Observation Network of China（CMONOC） and the International GNSS Service（IGS）. The correlation coefficient between the estimated TEC from GPS and the ionosonde measurements is 0.97, and the root mean square（RMS） with respect to Center for Orbit Determination in Europe（CODE） Global Ionosphere Maps（GIMs） is 4.87 TECU. In addition, the impact of different spherical harmonics orders and degrees on TEC estimations are evaluated and the degree/order 6 is better. Moreover, effective ionospheric shell heights from300 km to 700 km are further assessed and the result indicates that 550 km is the most suitable for regional ionospheric modeling in China at solar maximum.

Water storage variations in the Poyang Lake Basin estimated from GRACE and satellite altimetry

The Gravity Recovery and Climate Experiment（GRACE） satellite mission provides a unique opportunity to quantitatively study terrestrial water storage（TWS） variations. In this paper,the terrestrial water storage variations in the Poyang Lake Basin are recovered from the GRACE gravity data from January 2003 to March 2014 and compared with the Global Land Data Assimilation System（GLDAS） hydrological models and satellite altimetry. Furthermore, the impact of soil moisture content from GLDAS and rainfall from the Tropical Rainfall Measuring Mission（TRMM） on TWS variations are investigated. Our results indicate that the TWS variations from GRACE, GLDAS and satellite altimetry have a general consistency. The TWS trends in the Poyang Lake Basin determined from GRACE, GLDAS and satellite altimetry are increasing at 0.0141 km^3/a, 0.0328 km^3/a and 0.0238 km^3/a,respectively during the investigated time period. The TWS is governed mainly by the soil moisture content and dominated primarily by the precipitation but also modulated by the flood season of the Yangtze River as well as the lake and river exchange water.