Tailoring the separation performance of a carbon nanotube-based mixed matrix membrane decorated with metal–organic framework

Synthesis of mixed matrix membranes(MMM)using carbon nanotubes(CNTs)has shown great prospects for achieving excellent selective separation because of its special structure.Nevertheless,the preparation of highly selective MMM faces challenges,which is attributed to the obstacles encountered by CNTs dispersion in polymer matrix and elimination of interface defects.A novel CNT-based composite decorated with metal–organic framework(MOF)was synthesized and applied to the preparation of MMM.MOF was post modified,and then carboxyl groups were inserted on the outer surface of CNTs.The synthetic MMM(Cu-MOF-en@MWCNT)not only has selective adsorption on dyes,but also has selective photodegradation on dyes.The method of using CNTs to wrap the outside of MOF has great potential in dye separation.The performance of MMM was further improved by decorating MOF on the filler to improve the selectivity to the designated dye.

Error Correction of Lightning Location Data

[ Objective] The study aimed to correct error of lightning location data with small amplitude. [ Method] Using the curve fitting toolbox of matlab mathematical software, the distribution of lightning location data in Chongqing during 1999 -2008 was fitted based on logarithmic normal distribution function, and the specific characters of lightning data with current amplitude from -10 to 10 kA were analyzed. [ Result] During 1999 - 2008, the frequency of lightning with current amplitude from -10 to 10 kA in Chongqing City accounted for 4.93% of total frequency, while the fre- quency of lightning with current amplitude from -5 to 5 kA accounted for only 1.27%, lower than 2%, according with the conventional deletion proportion in China. Lightning data with current amplitude from -5 to 5 kA caused a great disturbance to the fitting effect, so the fitting effect was the best after these lightning data was deleted. After the lightning location system of Chongqing City was upgraded in 2005, the frequency of lightning with current amplitude from -10 to 10 kA decreased, and there were obvious changes in the frequency of lightning with current amplitude from -10 to -5 kA and from 5 to 10 kA, while the frequency of lightning with current amplitude from -5 to 5 kA was small and stable, so these data could be deleted. [Conclusion] The research could provide theoretical references for error correction of lightning location data with small amplitude in Chongqing City.