Algorithms and statistical analysis for linear structured weighted total least squares problem

Weighted total least squares(WTLS)have been regarded as the standard tool for the errors-in-variables(EIV)model in which all the elements in the observation vector and the coefficient matrix are contaminated with random errors.However,in many geodetic applications,some elements are error-free and some random observations appear repeatedly in different positions in the augmented coefficient matrix.It is called the linear structured EIV(LSEIV)model.Two kinds of methods are proposed for the LSEIV model from functional and stochastic modifications.On the one hand,the functional part of the LSEIV model is modified into the errors-in-observations(EIO)model.On the other hand,the stochastic model is modified by applying the Moore-Penrose inverse of the cofactor matrix.The algorithms are derived through the Lagrange multipliers method and linear approximation.The estimation principles and iterative formula of the parameters are proven to be consistent.The first-order approximate variance-covariance matrix(VCM)of the parameters is also derived.A numerical example is given to compare the performances of our proposed three algorithms with the STLS approach.Afterwards,the least squares(LS),total least squares(TLS)and linear structured weighted total least squares(LSWTLS)solutions are compared and the accuracy evaluation formula is proven to be feasible and effective.Finally,the LSWTLS is applied to the field of deformation analysis,which yields a better result than the traditional LS and TLS estimations.

Milling degree affects the fermentation properties of rice:perspectives from the composition of nutrients and gut microbiota via in vitro fermentation

Fermentation substrates of rice with different milling degrees(MDs) were prepared and fermented with human feces to compare their fermentation properties and effects on gut microbiota.MD 0s,MD 5s and MD 60s represented brown rice,moderately-milled rice and white rice,respectively.After in vitro fermentation,the MD 5s group showed higher starch utilization,compared with the MD 0s and 60s groups evaluated by Fourier transform infrared spectrometer,and confocal laser scanning microscope.Effects of fermentation substrates of rice with different MDs on gut microbiota were evaluated by 16S rDNA sequencing.All the sample groups reduced the pH and produced short-chain fatty acids(SCFAs) and branched-chain fatty acids.The MD 5s group exhibited higher α-diversity than the MD 0s and 60s groups.Abundances of Phascolarctobacterium,Blautia and norank_f_Ruminococcaceae were higher in the MD 0s and 5s groups,compared with the MD 60s group.These bacteria were also positively correlated with the SCFAs production via Spearman correlation analysis.In vitro culture assay revealed that fermentation substrates of MD 0s and 5s promoted the growth of two probiotics(Akkermansia muciniphila and Bifidobacterium adolescentis).Our results showed that moderate milling might be an appropriate way to produce rice products with richer nutrients and better fermentation properties.

Investigating the causal associations between five anthropometric indicators and nonalcoholic fatty liver disease:Mendelian randomization study

BACKGROUND Although the etiology of nonalcoholic fatty liver disease(NAFLD)has not been thoroughly understood,the emerging roles of anthropometric indicators in assessing and predicting the risk of NAFLD have been highlighted by accumulating evidence.AIM To evaluate the causal relationships between five anthropometric indicators and NAFLD employing Mendelian randomization(MR)design.METHODS The Anthropometric Consortium provided genetic exposure data for five anthropometric indicators,including hip circumference(HC),waist circumference(WC),waist-to-hip ratio(WHR),body mass index(BMI),and body fat percentage(BF).Genetic outcome data for NAFLD were obtained from the United Kingdom Biobank and FinnGen Consortium.Genome-wide significant single nucleotide polymorphisms were chosen as instrumental variables.Univariable MR(UVMR)and multivariable MR(MVMR)designs with analytical approaches,including inverse variance weighted(IVW),MR-Egger,weighted median(WM),and weighted mode methods,were used to assess the causal relationships between anthropometric indicators and NAFLD.RESULTS Causal relationships were revealed by UVMR,indicating that a higher risk of NAFLD was associated with a perunit increase in WC[IVW:odds ratio(OR)=2.67,95%CI:1.42-5.02,P=2.25×10^(−3)],and BF was causally associated with an increased risk of NAFLD(WM:OR=2.23,95%CI:1.07-4.66,P=0.033).The presence of causal effects of WC on the decreased risk of NAFLD was supported by MVMR after adjusting for BMI and smoking.However,no causal association between BF and NAFLD was observed.In addition,other causal relationships of HC,WHR(BMI adjusted),and BMI with the risk of NAFLD were not retained after FDR correction.CONCLUSION This study establishes a causal relationship,indicating that an increase in WC is associated with a higher risk of NAFLD.This demonstrates that a suitable decrease in WC is advantageous for preventing NAFLD.

The Advantages and Disadvantages of Skin Staple Suture Compared with Traditional Suture in Brain Surgery in Primary Hospital:A Randomized Controlled Study

Objective:This paper aims to compare the effect of skin staple suture and traditional silk suture in scalp suture surgery.Methods:A total of 80 craniocerebral surgery patients were included in this study,and the patients were randomly divided into observation group and control group,with 40 cases in each group.The observation group used disposable skin stapler to suture the scalp incision,and the control group used conventional silk suture to suture the incision.Statistical analysis was carried out on 6 indicators including suturing speed,healing under-scab,incision necrosis,incision cerebrospinal fluid(CSF)leakage,incision infection,and postoperative“centipede-shaped”scar incidence rate of the two suture methods.Results:There was no significant difference between the groups in terms of postoperative healing under-scab,incision necrosis,incision CSF leakage,and intracranial infection(P>0.05).The suturing speed in the observation group was 15.2±0.7 cm/min,which was significantly faster than 7.4±0.3 cm/min in the control group(P<0.05).The incidence of“centipede-shaped”scars in the observation group was significantly lower than that in the control group at 1 to 6 months after operation(P<0.05).Conclusion:Compared with traditional silk suture,skin staple suture has obvious advantages in suture speed and cosmetic effect.

Controlled synthesis of nanosized Si by magnesiothermic reduction from diatomite as anode material for Li-ion batteries

Li-ion batteries(LIBs)have demonstrated great promise in electric vehicles and hybrid electric vehicles.However,commercial graphite materials,the current predominant anodes in LIBs,have a low theoretical capacity of only 372 mAh·g?1,which cannot meet the everincreasing demand of LIBs for high energy density.Nanoscale Si is considered an ideal form of Si for the fabrication of LIB anodes as Si–C composites.Synthesis of nanoscale Si in a facile,cost-effective way,however,still poses a great challenge.In this work,nanoscale Si was prepared by a controlled magnesiothermic reaction using diatomite as the Si source.It was found that the nanoscale Si prepared under optimized conditions(800°C,10 h)can deliver a high initial specific capacity(3053 mAh·g?1 on discharge,2519 mAh·g?1 on charge)with a high first coulombic efficiency(82.5%).When using sand-milled diatomite as a precursor,the obtained nanoscale Si exhibited a well-dispersed morphology and had a higher first coulombic efficiency(85.6%).The Si–C(Si:graphite=1:7 in weight)composite using Si from the sand-milled diatomite demonstrated a high specific capacity(over 700 mAh·g?1 at 100 mA·g?1),good rate capability(587 mAh·g?1 at 500 mA·g?1),and a long cycle life(480 mAh·g?1 after 200 cycles at 500 mA·g?1).This work gives a facile method to synthesize nanoscale Si with both high capacity and high first coulombic efficiency.

Graphene-immobilized flower-like Ni3S2 nanoflakes as a stable binder-free anode material for sodium-ion batteries

A binder-free Ni3S2 electrode was prepared directly on a graphene-coated Ni foam （G/Ni） substrate through surface sulfiding of substrate using thiourea as the sulfur source in this work. The Ni3S2 showed a flower-like morphology and was uniformly distributed on the G/Ni surface. The flower-like Ni3S2 was composed of cross-arrayed nanoflakes with a diameter and a thickness of 1-2 μm and -50 nm, re- spectively. The free space in the flowers and the thin feature of Ni3S2 buffered the volume changes and relieved mechanical strain during re- peated cycling. The intimate contact with the Ni substrate and the fixing effect of graphene maintained the structural stability of the Ni3S2 electrode during cycling. The G/Ni-supported Ni3S2 maintained a reversible capacity of 250 mAh·g^-1 after 100 cycles at 50 mA·g^-1, demon- strating the good cycling stability as a result of the unique microstructure of this electrode material.

Doping Effects on Electronic Conductivity and Electrochemical Performance of LiFePO_4

Olivine-structured pure LIFePO4 and doped LI（M, Fe）PO4 （M=La, Ce, Nd, Mn, Co, Ni） have been synthesized by a solvothermal method. X-ray diffraction and field emission scanning electron microscopy analyses indicate that the as-prepared LiFePO4 is well-crystallized nanopowders without any detectable impurity phases. The electronic conductivity of LiFePO4 is enhanced by around 1-3 orders by doping. It was found that doping alone is not sufficient for the high-rate performance of LiFePO4 and surface coating with such as carbon should be needed. The best dopant for LiFePO4 is Nd among those studied in the present work. Accordingly, doping with 1 mol fraction Nd leads to an increase in 70 mAh/g at 0.1 C for the hydrothermally synthesized sample and 50 mAh/g at 1.0 C after carbon-coating in comparison with the undoped samples.

Complex Least Squares Adjustment to Improve Tree Height Inversion Problem in PolInSAR

At present,the principal data processing methods involving complex observations are based on two strategies according to characteristics of the observation process,i.e.,step-by-step and direct resolution.However,these strategies have some limitations,e.g.they cannot consider statistical observation error information,redundant observations and so on.This paper applies least squares methods to complex data processing to extend surveying adjustment theory from real to complex number space.We compared the two adjustment criteria for a complex domain in a quantitative way.In order to understand the effectiveness of complex least squares,tree height inversion from PolInSAR data is taken as an example.We firstly established both a complex adjustment function model and a stochastic model for PolInSAR tree height inversion,and then applied the complex least squares method to estimate tree height.Results show that the complex least squares approach is reliable and outperforms other classic tree height retrieval methods;the method is simple and easy to implement.

Double-layer solid-state electrolyte enables compatible interfaces for high-performance lithium metal batteries

Solid-state lithium metal batteries are promising next-generation batteries for both micro-scale integrated electronic devices and macro-scale electric vehicles.However,electrochemical incompatibility between electrolyte and electrodes causes continuous performance degradation.Here,we report a unique design of a double-layer composite solid-state electrolyte(D-CSE),where each layer,composed of both polymer and ceramics,is electrochemically compatible with its contacting electrode(Li anode or LiCoO_(2)cathode).The D-CSE has a small thickness(50μm),high thermal stability(up to 160℃ without noticeable deformation),and good flexibility even at a high ceramics content(66.7 wt%).Large-area selfstanding film can be obtained by a facile coating route.The electrolyte/electrode interface can be further enhanced via forming a soft interface by in-situ polymerization.Quasi-solid-state Li|D-CSE|LiCoO_(2)coin cells with the cathode-supported D-CSE can deliver a high initial discharge capacity of 134 mAh g^(-1) and a high capacity retention of 83%after 200 cycles at 0.5 C and 60℃.Quasi-solid-state Li|D-CSE|LiCoO_(2)pouch cells(designed capacity 8.6 mAh)with the self-standing D-CSE have a high retention of80%after 180 cycles at 2 mA charge and 4 mA discharge.At a high cathode loading(19.1 mg cm^(-2)),the Li|D-CSE|LiCoO_(2)pouch cell still can be stably cycled,and can withstand abuse tests of folding,cutting and nail penetration,indicating practical applications of the D-CSE.

Effect of Transition Metal on the Electrochemical Performances of Some Intermetallic Anodes for Lithium Ion Batteries

Some transition metal antimonides were prepared by levitation melting and subsequent ball-milling. The electrochem-ical behaviors of these materials as new candidate negative electrode materials in lithium ion secondary batteries wereinvestigated. It was found that they exhibited significantly larger volumetric capacity than carbon-based materi-als. The formation and composition of solid electrolyte interface (SEI) film were characterized by electrochemicalimpedance spectroscopy (EIS) and Fourier transform infra-red (FTIR) spectroscopy.

Forging Inspired Processing of Sodium-Fluorinated Graphene Composite as Dendrite-Free Anode for Long-Life Na–CO_(2) Cells

Na–CO_(2) batteries recently are emerging as promising energy-storage devices due to the abundance of Na in the earth’s crust and the clean utilization of greenhouse gas CO_(2) .However,similar to metallic Li,metallic Na also suffers from a serious issue of dendrite growth upon repeated cycling,while a facile method to solve this issue is still lacking.In this work,we report an effective,environmentally friendly method to inhibit Na dendrite growth by in situ constructing a stable,NaF-rich solid electrolyte interface(SEI)layer on metallic Na via adding a small amount(~3 wt%)of fluorinated graphene(FG)in bulk Na.Inspired by the forging processing,a uniform Na/FG composite was obtained by melting and repetitive FG-adsorbing/hammering processes.The Na/FG–Na/FG half cell exhibits a low voltage hysteresis of 110–140 mV over 700 h at a current density up to 5 mA cm^(-2) with an areal capacity as high as 5 mAh cm^(-2).Na–CO_(2) full cell with the Na/FG anode is able to sustain a stable cycling of 391 cycles at a limited capacity of 1000 mAh g^(-1).Long cycle life of the cell can be attributed to the protecting effect of the in situ fabricated NaF-rich SEI layer on metallic Na.Both experiments and density functional theory(DFT)calculations confirm the formation of the NaF-rich SEI layer.The inhibition effect of the NaF-rich SEI layer for Na dendrites is verified by in situ optical microscopy observations.

Predication of 3-D Viscous Flowfield of a Centrifugal Impeller

A three-dimensional viscous code has been developed to solve Reynolds-averaged Navier-Stokes equations. The governing equations in finite volume form are solved by two-step Runge-Kutta scheme with implicit residual smoothing. The eddy viscous is obtained using the Baldwin-Lomax model. A prediction of the 3-D turbulent flow and the performance in the “all-over controlled vortex distribution” centrifugal impeller with a vaneless diffuser has been made for the compressor at design and off-design condition. The predicted effi-ciency is a little higher than the experiment data. These results suggest that the present calculation code is able to determine the flow development in the impeller and also the turbulence model in the centrifugal im-peller should be improved.

带有蓄能器的新型电静液作动器的启动特性研究

电静液作动器(EHA)广泛用于飞机和机器人系统,其应用正在逐步向大型机械设备发展。本文提出了一种在活塞侧连接一个蓄能器的新型EHA结构,该结构用于在空载情况下实现快速启动。此外,当外部负载突然施加或改变时,为了使蓄能器以最佳状态吸收系统压力和流量的脉动,提出了一种新的参数自适应控制方法(PACM)。建立了EHA和PACM的数学模型,并证明了所提出的结构和PACM的可行性和有效性。仿真结果表明,传统液压结构的EHA启动时间为62.8 s,而我们提出的配备蓄能器的EHA的启动时间为2.1 s,这使EHA的启动时间缩短了96.6%。当施加5000N的外部负载时,采用PACM可以使压力脉动降低31%,并且流量曲线过度平滑,可以根据特定的工作条件方便地调整PACM参数。

Valuing Water Resources in Turkey: A Case Study of Beyşehir Lake

Water resource management is critical to Turkey’s economy and environment. The country has about 112 billion m3 per year of economically exploitable water. However, population growth, climate change and pollution of water bodies are putting increasing pressure on these resources. In this context, understanding the contribution of water to the economy and environment is crucial for its conservation. To meet this need, the World Bank launched a program aiming at improving valuation and accounting systems of natural resources in Turkey. As part of this program, this article estimates in monetary terms the economic value of water in Bey?ehir Lake, the largest freshwater lake in Turkey. Valuation is based on the Total Economic Value concept, which includes use and non-use values. The results show that the economic value of water is about seven times higher than its financial value. In addition, the economic value of water allocated for municipal use (TL5/m3) is substantially greater than that supplied for irrigation (TL0.5/m3). The analysis suggests that allocation of water from Bey?ehir Lake among different uses is inefficient. To validate this conclusion and improve allocation, a more comprehensive assessment of the economic benefits of water resources is needed, particularly of water supply for irrigation, municipal use, recreation and biodiversity. The analysis also indicates that economic valuation can be a powerful tool to improve water management at the river basin level.

Efficient and selective H_(2)O_(2)production through uranyl-assisted photocatalytic oxygen reduction reaction process in a uranium-organic framework

Harnessing solar energy by photocatalytically converting oxygen and water into high-value-added H_(2)O_(2)is a promising way of alleviating both environmental and energy issues.It is worth noting that suppressing detrimental side reactions,such as the generation of·O_(2)^(-),is a critical approach to enhancing H_(2)O_(2)production.Herein,a 2-fold interpenetrating 3D uranium-organic framework(YTU-W-1)was developed and introduced for photocatalytic H_(2)O_(2)production.The material demonstrates a different photocatalytic mechanism when employing uranyl as an initiator,as compared with the conventional semiconductor photocatalytic pathway involving photo-generated charge carriers.Benefiting from the strong hydrogen abstraction effect of the U≡O·and the direct one-step oxygen reduction pathway,YTU-W-1 exhibits enhanced photocatalytic performance for H_(2)O_(2)production with yield efficiency of 221μmol h^(-1)g^(-1).Furthermore,YTU-W-1 displays a high H_(2)O_(2)selectivity of 68%,confirmed by rotating ring-disk electrode(RRDE)measurement.DFTcalculations were used to elucidate the critical role of uranyl in the photocatalytic oxygen reduction reaction for H_(2)O_(2)production.This research introduces an innovative approach to photo-driven H_(2)O_(2)production,underscoring the potential for heterogeneous catalysts to engage in photocatalytic reactions independently of photogenerated charge carriers.

Superior Iodine Uptake Capacity Enabled by an Open Metal-Sulfide Framework Composed of Three Types of Active Sites

Efficient adsorption of gaseous radioiodine is pivotal for the sustainable development of nuclear energy and the long-termradiation safety of the ecological system.However,state-of-the-art adsorbents(e.g.metal-organic frameworks and covalent-organic frameworks)currently under exploration suffer severely from limited adsorption capacity,especially under a real-world scenariowith extremely lowradioiodine concentration and elevated temperature.This mostly originates from the relatively weak sorption driving forces mainly determinedby the iodine-adsorbent interaction consistingof noncovalent interactionswith a small fraction of strong chemical bonding.Here,we document the discovery of an open metal-sulfide framework((NH_(4))_(2)(Sn_(3)S_(7)),donated as SCU-SnS)constructed by three different types of active sites as a superior iodine adsorbent.Benefiting from the ability of iodine for pre-enrichment into the framework by charge-balancing NH_(4)^(+)through N-H···I interaction,the efficient reduction of I^(2)affording I^(-)by S^(2-),and extremely high binding affinity between Sn_(4)^(+)and I^(-),SCU-SnS exhibit a record-breaking iodine adsorption capacity(2.12 g/g)under dynamic breakthrough conditions and the highest static capacity(6.12 g/g)among all reported inorganic adsorbents,both at 348 K.Its facile synthesis and low cost endow SCU-SnS with powerful application potential for the nuclear industry.

中空海胆状结构的碳包覆Fe2O3用作锂离子电池的高性能负极材料

Fe2O3由于成本低廉,储量丰富和理论比容量高(1007 mA hg^-1)等特点,在锂离子电池负极材料的应用中极具发展前景.然而一些问题仍然存在,如:充放电过程中比容量的迅速衰减,不可逆的体积膨胀以及较短的循环寿命等.这些问题严重制约了Fe2O3在锂离子电池中的实际应用.为了突破这些局限,本文以金属-有机骨架(MOFs)包覆的FeOOH(FeOOH@MIL-100(Fe))作为前驱体和自牺牲模板,通过高温热处理制备得到一种能良好继承前驱体形貌的中空海胆状碳包覆的Fe2O3(Fe2O3@MOFC)复合材料.在热处理过程中,外部的MOF层很好地保护了内部Fe2O3结构的完整性,并以原位转化的方式衍生为均匀分布在纳米粒子外部的碳涂层.在0.1 Ag^-1的电流密度下,Fe2O3@MOFC可提供高达1366.9 mA hg^-1的初始放电容量,且充放电循环200次后,仍能保持大约1551.3 mA hg^-1的高放电容量.在1 Ag^-1的高电流密度下循环300次后,其比容量仍可保持在1208.6 mA hg^-1.

Solvothermal-assisted morphology evolution of nanostructured LiMnPO_4 as high-performance lithium-ion batteries cathode

As a potential substitute for LiFePO4, LiMnPO4 has attracted more and more attention due to its higher energy, showing potential application in electric vehicle（EV） or hybrid electric vehicle（HEV）. In this work,solvothermal method was used to prepare nano-sized LiMnPO4, where ethylene glycol was used as solvent, and lithium acetate（LiAc）, phosphoric acid（H3 PO4） and manganese chloride（MnCl2） were used as precursors. The crystal structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The electrochemical performance was evaluated by charge-discharge cycling, cyclic voltammetry and electrochemical impedance spectroscopy. The results show that the molar ratio of LiAc：H3 PO4：MnCl2 plays a critical role in directing the morphology of LiMnPO4. Large plates transform into irregular nanoparticles when the molar ratio changes from 2：1：1 to 6：1：1. After carbon coating, the product prepared from the 6：1：1 precursor could deliver discharge capacities of 156.9,122.8, and 89.7 mAhg-1 at 0.05 C, 1 C and 10 C, respectively.The capacity retention can be maintained at 85.1% after 200 cycles at 1 C rate for this product.

高性能锂离子电池正极Calix[6]quinone（英文）

有机醌类化合物因其具有高的理论容量值而引起了人们的广泛关注.本文合成了一种新型的环状大分子Calix[6]quinone(C6Q),它由6个对苯醌单元组成,可提供12个电化学位点,是一种极具发展前景的锂离子正极材料.C6Q在0.1 C的电流密度下展示了高达423 mA h g^-1的初始放电比容量(理论放电比容量为447 mA h g^-1).经过100圈充放电循环之后,它的容量保持在216 mA h g^-1;经过300次循环之后,仍然拥有195 mA h g^-1的高容量.C6Q具有高容量和宽的电化学窗口,因此可以提供高达1201 W h kg^-1的能量密度.此外,使用有序介孔碳CMK-3固载C6Q的方法可以进一步提高C6Q的电化学性能.

Remarkable improvement of cyclic stability in Li-O2 batteries using ruthenocene as a redox mediator

Nonaqueous Li-O2 batteries attract attention for their theoretical specific energy density.However,due to the difficulty of decomposition of Li2 O2,Li-O2 batteries have high charge overpotential and poor cycling life.So all kinds of catalysts have been studied on the cathode.Compared to heterogeneous solid catalysts,soluble catalysts achieve faster and more effective transport of electrons by reversible redox pairs.Here,we first report ruthenocene(Ruc) as a mobile redox mediator in a Li-O2 battery.0.01 mol/L Ruc in the electrolyte effectively reduces the charging voltage by 610 mV.Additionally,Ruc greatly increases the cycling life by four-fold(up to 83 cycles) with a simple ketjen black(KB) cathode.The results of SEM,XPS and XRD confirm that less discharge product residue accumulated after recharge.To verify the reaction mechanisms of the mediato r,free energy profiles of the possible reaction pathways based on DFT are provided.