Organic geochemical characteristics and significance of Permian Gufeng formation siliceous shale in well CSDP-2 of South Yellow Sea central uplift

In order to understand the hydrocarbon generation potential of the siliceous shale in the Permian Gufeng Formation of the South Yellow Sea,the organic geochemistry and organic petrology of the siliceous shale in the Gufeng Formation of the CSDP-2 well were studied and analyzed.It is found that the TOC of the samples is mainly between 9%and 12%,and Tmaxis mainly distributed between 510 and 540℃.The value of the organic microscopic type index(TI)is between 25.71 and 31.00,which is a set of II_(2)high-quality source rocks with high organic matter abundance in the over mature stage of largescale gas generation.According to the distribution characteristics of Molecular fossils in siliceous shale of Gufeng Formation of well CSDP-2,bacterial organic matter is the main hydrocarbon generating parent material,and aquatic animal organic matter is an important hydrocarbon generating parent material.The siliceous shale in Gufeng Formation of CSDP-2 well is in the stage of large-scale gas generation;Therefore,the Gufeng Formation in the central uplift of the South Yellow Sea has the material basis for the formation of large-scale shale gas reservoirs.At the same time,the siliceous metasomatism of the siliceous shale reservoir of Gufeng Formation is not conducive to the primary migration of oil,and there is much oil and gas remaining in the reservoir.

Exploration prospects of oil and gas in the Northwestern part of the Offshore Indus Basin, Pakistan

Oil and gas resources are short in Pakistan and no commercially viable oil and gas sources have been yet discovered in its offshore areas up to now.In this study,the onshore-offshore stratigraphic correlation and seismic data interpretation were conducted to determine the oil and gas resource potential in the Offshore Indus Basin,Pakistan.Based on the comprehensive analysis of the results and previous data,it is considered that the Cretaceous may widely exist and three sets of source rocks may be developed in the Offshore Indus Basin.The presence of Miocene mudstones has been proven by drilling to be high-quality source rocks,while the Cretaceous and Paleocene–Eocene mudstones are potential source rocks.Tectonic-lithologic traps are developed in the northwestern part of the basin affected by the strike-slip faults along Murray Ridge.Furthermore,the Cretaceous and Paleocene–Eocene source rocks are thick and are slightly affected by volcanic activities.Therefore,it can be inferred that the northwestern part of Offshore Indus Basin enjoys good prospects of oil and gas resources.

Discussion on "sandwich"structures and preservation conditions of shale gas in the South Yellow Sea Basin

In order to make a breakthrough in Mesozoic-Paleozoic shale gas exploration in the South Yellow Sea Basin,a comparison of the preservation conditions was made within the Barnett shale gas reservoirs in the Fortworth Basin,the Jiaoshiba shale gas reservoirs in Sichuan Basin and potential shale gas reservoirs in Guizhou Province.The results show that the "Sandwich"structure is of great importance for shale gas accumulation.Therein to,the "Sandwich"structure is a kind of special reservoir-cap rock assemblage which consist of limestone or dolomite on the top,mudstone or shale layer in the middle and limestone or dolomite at the bottom.In consideration of the Mesozoic-Paleozoie in the Lower Yangtze,and Laoshan Uplift with weak Paleozoic deformation and thrust fault sealing On both flanks of the Laoshan Uplift,a conclusion can be drawn that the preservation conditions of shale gas probably developed "Sandwich" structures in the Lower Cambrian and Permian,which are key layers for the breakthrough of shale gas in the South Yellow Sea.Moreover,the preferred targets for shale gas drilling probably locate at both flanks of the Laoshan Uplift.

Characteristics of major and trace elements in surface sediments of the Makran Accretionary Prism, Pakistan and their implications for natural gas hydrates

To accurately identify the natural gas hydrates(NGH)in the sea area of the Makran Accretionary Prism,Pakistan,this paper presents the testing and analysis of major and trace elements in sediment samples taken from two stations(S2 and S3)in the area by the China Geological Survey.As shown by testing results,all major elements are slightly different in content between the two stations except SiO2 and CaO.This also applies to the trace elements that include Sr and Ba primarily and Cr,Ni and Zn secondarily.It can be concluded in this study that the tectonic setting of the Makran Accretionary Prism is dominated by oceanic island arc and that provenance of the Makran Accretionary Prism is dominated by felsic igneous provenance,which is at the initial weathering stage and mainly consists of granodiorite.Besides terrigenous detritus,there are sediments possibly originating from Makran-Bela Ophiolite from the northwestern part and Murray Ridge igneous rocks from the southeastern part.The V/Cr,Ni/Co,and V/(V+Ni)ratios indicate that sediments of the two stations are in an oxidation-suboxidation environment.However,the authors infer that the sedimentary environment of the sediments 3.0 m below the seafloor tends to be gradually transformed into a reduction environment by comparison with the Qiongdongnan Basin in the South China Sea where NGH has been discovered.The sediments in the Makran Accretionary Prism are rich in organic matter,with total organic carbon(TOC)content greater than 1%.According to comprehensive research,the organic matter in the sediments mainly originates from marine algae and has high TOC content,which is favorable for the formation of NGH.

Formation of G-phase in 20Cr32Ni1Nb Stainless Steel and its Effect on Mechanical Properties

A series of tensile tests, Charpy impact tests, optical microscopy observations, and field emission-scanning electron microscopy examinations, were carded out to investigate the mechanical properties and microstructural evolution of 20Cr32NilNb steel. Experimental results indicate that the as-cast microstructure of the steel typically consists of a supersaturated solid solution of austenite matrix with a network of interdendritic primary carbides （NbC and M23C6）. In the ex-service samples, large amounts of secondary carbides precipitate within austenite matrix. Besides the growth and coarsening of NbC and M23C6 carbides during service condition, the Ni-Nb silicides known as G-phase （Nil6Nb6Si7） are formed at the interdendritic boundaries. The microstructural evolution results in the degradation of the mechanical properties of the ex-service steel. In addition, the precipitate rate of G-phase, depending in part on Si content, varies greatly for the 20Cr32NilNb steel, which plays a key role in the long-term microstructural stability of the steel. Based on the X-ray diffraction data, time-temperature-transformation curve for the steel is obtained from the aged specimens.

Gradient Elastic–Plastic Properties of Expanded Austenite Layer in 316L Stainless Steel

The gradient mechanical properties, variation of stress with strain and surface cracking behavior of expanded austenite developed on 316L austenitic stainless steel were investigated by nanoindentation tests, X-ray residual stress analysis and scanning electron microscope observation in four-point bending tests. The results show that the plastic properties of the carburizing layer including true initial yield strengths and strain hardening exponents increase significantly from substrate to surface, while the true elastic modulus just improves slightly. Due to the onset of plastic flow, the residual stresses are almost equivalent to the true initial yield strengths from surface to the depth of ～10 lm. The results of four-point bending tests show that surface stress increases linearly with the increase in strain until the strain reaches～1.0%, after that the plastic yield happens. The expanded austenite surface layer is brittle, and the cracks will be created at the strain of ～1.4%.The cracking stress is about～2.4 GPa.