Comparison of α particle detectors based on single-crystal diamond films grown in two types of gas atmospheres by microwave plasma-assisted chemical vapor deposition

Chemical vapor deposition(CVD)-grown diamond films have been developed as irradiation-resistant materials to replace or upgrade current detectors for use in extreme radiation environments. However, their sensitivity in practical applications has been inhibited by space charge stability issues caused by defects and impurities in pure diamond crystal materials. In this study, two high-quality CVD-grown single-crystal diamond(SCD) detectors with low content of nitrogen impurities were fabricated and characterized. The intrinsic properties of the SCD samples were characterized using Raman spectroscopy, stereomicroscopy, and X-ray diffraction with the rocking curve mode, cathode luminescence(CL), and infrared and ultraviolet-visible-near infrared spectroscopies. After packaging the detectors, the dark current and energy resolution under α particle irradiation were investigated. Dark currents of less than 5 pA at 100 V were obtained after annealing the electrodes, which is comparable with the optimal value previously reported. The detector that uses a diamond film with higher nitrogen content showed poor energy resolution, whereas the detector with more dislocations showed poor charge collection efficiency(CCE). This demonstrates that the nitrogen content in diamond has a significant effect on the energy resolution of detectors, while the dislocations in diamond largely contribute to the poor CCE of detectors.

A novel method of quantitative evaluation and comprehensive classification of low permeability-tight oil reservoirs: A case study of Jidong Oilfield, China

The classification of low permeability-tight reservoirs is the premise of development. The deep reservoir of Shahejie 3 member contains rich low permeability-tight reserves, but the strong heterogeneity and complex micro pore structure make the main controlling factors subjective and the classification boundaries unclear. Therefore, a new indicator considering the interaction between fluid and rock named Threshold Flow Zone Indicator(TFZI) is proposed, it can be used as the main sequence of correlation analysis to screen the main controlling factors, and the clustering algorithm is optimized combined with probability distribution to determine the classification boundaries. The sorting coefficient, main throat radius, movable fluid saturation and displacement pressure are screened as the representative parameters for the following four key aspects: rock composition, microstructure, flow capacity and the interaction between rock and fluid. Compared with the traditional probability distribution and clustering algorithm, the boundary of the optimized clustering algorithm proposed in this paper is more accurate.The classification results are consistent with sedimentary facies, oil levels and oil production intensity.This method provides an important basis for the development of low permeability-tight reservoirs.

Numerical evaluations on the fluid production in the in-situ conversion of continental shale oil reservoirs

In-situ conversion presents a promising technique for exploiting continental oil shale formations,characterized by highly fractured organic-rich rock.A 3D in-situ conversion model,which incorporates a discrete fracture network,is developed using a self-developed thermal-flow-chemical(TFC)simulator.Analysis of the model elucidates the in-situ conversion process in three stages and defines the transformation of fluids into three distinct outcomes according to their end stages.The findings indicate that kerogen decomposition increases fluid pressure,activating fractures and subsequently enhancing permeability.A comprehensive analysis of activated fracture permeability and heating power reveals four distinct production modes,highlighting that increasing heating power correlates with higher cumulative fluid production.Activated fractures,with heightened permeability,facilitate the mobility of heavy oil toward production wells but hinder its cracking,thereby limiting light hydrocarbon production.Additionally,energy efficiency research demonstrates the feasibility of the in-situ conversion in terms of energy utilization,especially when considering the surplus energy from high-fluctuation energy sources such as wind and solar power to provide heating.