Chemical vapor deposition(CVD)-grown diamond films have been developed as irradiation-resistant materials to replace or upgrade current detectors for use in extreme radiation environments. However, their sensitivity i...Chemical vapor deposition(CVD)-grown diamond films have been developed as irradiation-resistant materials to replace or upgrade current detectors for use in extreme radiation environments. However, their sensitivity in practical applications has been inhibited by space charge stability issues caused by defects and impurities in pure diamond crystal materials. In this study, two high-quality CVD-grown single-crystal diamond(SCD) detectors with low content of nitrogen impurities were fabricated and characterized. The intrinsic properties of the SCD samples were characterized using Raman spectroscopy, stereomicroscopy, and X-ray diffraction with the rocking curve mode, cathode luminescence(CL), and infrared and ultraviolet-visible-near infrared spectroscopies. After packaging the detectors, the dark current and energy resolution under α particle irradiation were investigated. Dark currents of less than 5 pA at 100 V were obtained after annealing the electrodes, which is comparable with the optimal value previously reported. The detector that uses a diamond film with higher nitrogen content showed poor energy resolution, whereas the detector with more dislocations showed poor charge collection efficiency(CCE). This demonstrates that the nitrogen content in diamond has a significant effect on the energy resolution of detectors, while the dislocations in diamond largely contribute to the poor CCE of detectors.展开更多
The classification of low permeability-tight reservoirs is the premise of development. The deep reservoir of Shahejie 3 member contains rich low permeability-tight reserves, but the strong heterogeneity and complex mi...The classification of low permeability-tight reservoirs is the premise of development. The deep reservoir of Shahejie 3 member contains rich low permeability-tight reserves, but the strong heterogeneity and complex micro pore structure make the main controlling factors subjective and the classification boundaries unclear. Therefore, a new indicator considering the interaction between fluid and rock named Threshold Flow Zone Indicator(TFZI) is proposed, it can be used as the main sequence of correlation analysis to screen the main controlling factors, and the clustering algorithm is optimized combined with probability distribution to determine the classification boundaries. The sorting coefficient, main throat radius, movable fluid saturation and displacement pressure are screened as the representative parameters for the following four key aspects: rock composition, microstructure, flow capacity and the interaction between rock and fluid. Compared with the traditional probability distribution and clustering algorithm, the boundary of the optimized clustering algorithm proposed in this paper is more accurate.The classification results are consistent with sedimentary facies, oil levels and oil production intensity.This method provides an important basis for the development of low permeability-tight reservoirs.展开更多
基金This work was financially supported by the Natural Science Foundation of Beijing,China(No.4192038)National Key Research and Development Program of China(Nos.2016YFE0133200 and 2018YFB0406501)European Union’s Horizon 2020 Research and Innovation Staff Exchange Scheme(No.734578).
文摘Chemical vapor deposition(CVD)-grown diamond films have been developed as irradiation-resistant materials to replace or upgrade current detectors for use in extreme radiation environments. However, their sensitivity in practical applications has been inhibited by space charge stability issues caused by defects and impurities in pure diamond crystal materials. In this study, two high-quality CVD-grown single-crystal diamond(SCD) detectors with low content of nitrogen impurities were fabricated and characterized. The intrinsic properties of the SCD samples were characterized using Raman spectroscopy, stereomicroscopy, and X-ray diffraction with the rocking curve mode, cathode luminescence(CL), and infrared and ultraviolet-visible-near infrared spectroscopies. After packaging the detectors, the dark current and energy resolution under α particle irradiation were investigated. Dark currents of less than 5 pA at 100 V were obtained after annealing the electrodes, which is comparable with the optimal value previously reported. The detector that uses a diamond film with higher nitrogen content showed poor energy resolution, whereas the detector with more dislocations showed poor charge collection efficiency(CCE). This demonstrates that the nitrogen content in diamond has a significant effect on the energy resolution of detectors, while the dislocations in diamond largely contribute to the poor CCE of detectors.
基金supported by China Natural Science Foundation(Grant No.51704303)Beijing Natural Science Foundation(Grant No.3173044)。
文摘The classification of low permeability-tight reservoirs is the premise of development. The deep reservoir of Shahejie 3 member contains rich low permeability-tight reserves, but the strong heterogeneity and complex micro pore structure make the main controlling factors subjective and the classification boundaries unclear. Therefore, a new indicator considering the interaction between fluid and rock named Threshold Flow Zone Indicator(TFZI) is proposed, it can be used as the main sequence of correlation analysis to screen the main controlling factors, and the clustering algorithm is optimized combined with probability distribution to determine the classification boundaries. The sorting coefficient, main throat radius, movable fluid saturation and displacement pressure are screened as the representative parameters for the following four key aspects: rock composition, microstructure, flow capacity and the interaction between rock and fluid. Compared with the traditional probability distribution and clustering algorithm, the boundary of the optimized clustering algorithm proposed in this paper is more accurate.The classification results are consistent with sedimentary facies, oil levels and oil production intensity.This method provides an important basis for the development of low permeability-tight reservoirs.