The asymmetric oxidation of sulfides catalyzed by WO3 and 30% H2O2 in the presence of salan as chiral ligands under heterogeneous conditions is described. The reaction system is very easily to be operated. Mild to hig...The asymmetric oxidation of sulfides catalyzed by WO3 and 30% H2O2 in the presence of salan as chiral ligands under heterogeneous conditions is described. The reaction system is very easily to be operated. Mild to high chemical yields and moderate enantioselectivities were obtained.展开更多
基金National Natural Science Foundation of China(No.20102002,20472028)Science Foundation of Jiangsu Province for their financial support(No.20332050).
文摘The asymmetric oxidation of sulfides catalyzed by WO3 and 30% H2O2 in the presence of salan as chiral ligands under heterogeneous conditions is described. The reaction system is very easily to be operated. Mild to high chemical yields and moderate enantioselectivities were obtained.