The hierarchical mesoporous Zn/ZSM-5 zeolite catalyst was prepared by NaOH treatment and Zn impregnation, and its application in the conversion of methanol to gasoline （MTG） was studied. N2 adsorption-desorption res...The hierarchical mesoporous Zn/ZSM-5 zeolite catalyst was prepared by NaOH treatment and Zn impregnation, and its application in the conversion of methanol to gasoline （MTG） was studied. N2 adsorption-desorption results showed that the mesopores with sizes of 2-20 nm in HZ5/0.3AT was formed by 0.3 M NaOH alkali treatment. The zeolite samples after modification were also characterized by XRF, AAS, XRD, SEM and NH3-TPD methods. Zn impregnated catalyst Zn/HZ5/0.3AT exhibited dramatic improvements in catalytic lifetime and liquid hydrocarbons yield. The selectivity of aromatic hydrocarbons was also improved after Zn impregnation. It is suggested that the mesopores of Zn/HZ5/0.3AT enhanced the synergetic effect of Zn species and acid sites and the capability to coke tolerance, which were confirmed by the results of catalytic test and TGA analysis, respectively.展开更多
The operational numerical weather prediction system established by the China Meteorological Administration(CMA),based on the Global/Regional Assimilation and Prediction System(GRAPES)model,adopts the classical semi-im...The operational numerical weather prediction system established by the China Meteorological Administration(CMA),based on the Global/Regional Assimilation and Prediction System(GRAPES)model,adopts the classical semi-implicit semi-Lagrangian(SISL)time integration algorithm.This paper describes a major upgrade to the dynamical core of the CMA global forecast system(CMA-GFS),which was successfully incorporated into operation in 2020.In the upgrade,the classical SISL is further developed into a predictor–corrector scheme,a three-dimensional(3D)reference profile instead of the original isothermal reference profile is applied when implementing the semi-implicit algorithm,and a hybrid terrain-following vertical coordinate system is also applied.The new version of the dynamical core greatly improves the model performance,the time integration reaches second-order accuracy,the time step can be extended by 50%,and the efficiency is greatly improved(by approximately 30%).Atmospheric circulation simulation is systematically improved,and deviations in temperature,wind,and humidity are reduced.The new version of the dynamical core provides a solid foundation for further development of the entire operational system of the CMA.展开更多
基金supported by the Fundamental Research Funds for the Central Universities, HUST (No. Z2009008)the National Natural Science Foundation of China (No. 20973068)
文摘The hierarchical mesoporous Zn/ZSM-5 zeolite catalyst was prepared by NaOH treatment and Zn impregnation, and its application in the conversion of methanol to gasoline （MTG） was studied. N2 adsorption-desorption results showed that the mesopores with sizes of 2-20 nm in HZ5/0.3AT was formed by 0.3 M NaOH alkali treatment. The zeolite samples after modification were also characterized by XRF, AAS, XRD, SEM and NH3-TPD methods. Zn impregnated catalyst Zn/HZ5/0.3AT exhibited dramatic improvements in catalytic lifetime and liquid hydrocarbons yield. The selectivity of aromatic hydrocarbons was also improved after Zn impregnation. It is suggested that the mesopores of Zn/HZ5/0.3AT enhanced the synergetic effect of Zn species and acid sites and the capability to coke tolerance, which were confirmed by the results of catalytic test and TGA analysis, respectively.
基金Supported by the National Natural Science Foundation of China(42090032 and 42275168).
文摘The operational numerical weather prediction system established by the China Meteorological Administration(CMA),based on the Global/Regional Assimilation and Prediction System(GRAPES)model,adopts the classical semi-implicit semi-Lagrangian(SISL)time integration algorithm.This paper describes a major upgrade to the dynamical core of the CMA global forecast system(CMA-GFS),which was successfully incorporated into operation in 2020.In the upgrade,the classical SISL is further developed into a predictor–corrector scheme,a three-dimensional(3D)reference profile instead of the original isothermal reference profile is applied when implementing the semi-implicit algorithm,and a hybrid terrain-following vertical coordinate system is also applied.The new version of the dynamical core greatly improves the model performance,the time integration reaches second-order accuracy,the time step can be extended by 50%,and the efficiency is greatly improved(by approximately 30%).Atmospheric circulation simulation is systematically improved,and deviations in temperature,wind,and humidity are reduced.The new version of the dynamical core provides a solid foundation for further development of the entire operational system of the CMA.
