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Development of a DFN-based probabilistic block theory approach for bench face angle design in open pit mining
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作者 jianhua yan Xiansen Xing +4 位作者 Zhihai Li Weida Ni Liuyuan Zhao Chun Zhu Yuanyuan He 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期3047-3062,共16页
In open pit mining,uncontrolled block instabilities have serious social,economic and regulatory consequences,such as casualties,disruption of operation and increased regulation difficulties.For this reason,bench face ... In open pit mining,uncontrolled block instabilities have serious social,economic and regulatory consequences,such as casualties,disruption of operation and increased regulation difficulties.For this reason,bench face angle,as one of the controlling parameters associated with block instabilities,should be carefully designed for sustainable mining.This study introduces a discrete fracture network(DFN)-based probabilistic block theory approach for the fast design of the bench face angle.A major advantage is the explicit incorporation of discontinuity size and spatial distribution in the procedure of key blocks testing.The proposed approach was applied to a granite mine in China.First,DFN models were generated from a multi-step modeling procedure to simulate the complex structural characteristics of pit slopes.Then,a modified key blocks searching method was applied to the slope faces modeled,and a cumulative probability of failure was obtained for each sector.Finally,a bench face angle was determined commensurate with an acceptable risk level of stability.The simulation results have shown that the number of hazardous traces exposed on the slope face can be significantly reduced when the suggested bench face angle is adopted,indicating an extremely low risk of uncontrolled block instabilities. 展开更多
关键词 Open pit mine Bench face angle Block theory Probabilistic approach Discrete fracture network modeling Fractured rock slope
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Delineating homogeneous domains of fractured rocks using topological manifolds and deep learning
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作者 Yongqiang Liu Jianping Chen +3 位作者 Fujun Zhou Jiewei Zhan Wanglai Xu jianhua yan 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期2996-3013,共18页
Determining homogeneous domains statistically is helpful for engineering geological modeling and rock mass stability evaluation.In this text,a technique that can integrate lithology,geotechnical and structural informa... Determining homogeneous domains statistically is helpful for engineering geological modeling and rock mass stability evaluation.In this text,a technique that can integrate lithology,geotechnical and structural information is proposed to delineate homogeneous domains.This technique is then applied to a high and steep slope along a road.First,geological and geotechnical domains were described based on lithology,faults,and shear zones.Next,topological manifolds were used to eliminate the incompatibility between orientations and other parameters(i.e.trace length and roughness)so that the data concerning various properties of each discontinuity can be matched and characterized in the same Euclidean space.Thus,the influence of implicit combined effect in between parameter sequences on the homogeneous domains could be considered.Deep learning technique was employed to quantify abstract features of the characterization images of discontinuity properties,and to assess the similarity of rock mass structures.The results show that the technique can effectively distinguish structural variations and outperform conventional methods.It can handle multisource engineering geological information and multiple discontinuity parameters.This technique can also minimize the interference of human factors and delineate homogeneous domains based on orientations or multi-parameter with arbitrary distributions to satisfy different engineering requirements. 展开更多
关键词 Homogeneous domain Geological domain Geotechnical domain Structural domain Topological manifold Deep learning
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Coupled DEM-FDM analyses of the effects of falling rock’s shape and impact angle on response of granular cushion and rock shed
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作者 Jingyu Xue Chen Cao +2 位作者 jianhua yan Yaopeng Ji Jianping Chen 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期3353-3364,共12页
Rock shed is an effective protection measure against rockfall.To investigate the influences of falling rock’s shape and impact angle on the impact effect of the cushioned rock shed,a modeling approach for a rock shed... Rock shed is an effective protection measure against rockfall.To investigate the influences of falling rock’s shape and impact angle on the impact effect of the cushioned rock shed,a modeling approach for a rock shed with a cushion layer using PFC-FLAC.The granular cushion is modeled as an aggregate of discrete non-cohesion particles,while the concrete plate and the beam are modeled as zones.The falling rock with different sphericities and impact angles is modeled as a rigid assembly.The numerical model is validated by comparing the simulation results with experimental and numerical results from previous literature.This model is applied to analyze the effects of rock shape and impact angle on the dynamic interaction effects between falling rock and cushioned rock shed,including the impact force,transmitted bottom force,penetration depth,and plate deflection.The numerical results show that the variation in the falling rock’s shape has different effects on the falling rock with different impact angles.These findings could support rock shed design by revealing the limitations of the assumptions in the past research,which may result in unsafe rock sheds for some rockfall cases. 展开更多
关键词 Rockfall Coupled DEM-FDM analysis Rock’s shape Impact angle Granular cushion Rock shed
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Mechanism study of Cu(Ⅱ) adsorption from acidic wastewater by ultrasonic-modified municipal solid waste incineration fly ash
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作者 Shunda lin yang Lu +3 位作者 Lin Zheng Ling Long Xuguang Jiang jianhua yan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期157-165,共9页
High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(M... High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(MSWI) fly ash for Cu(Ⅱ) adsorption to achieve the purpose of “treating waste by waste.” The effects of p H, adsorption time, initial concentration, and temperature on the modified MSWI fly ash’s adsorption efficiency were systematically studied in this article. The adsorption performance of the modified MSWI fly ash can be enhanced by the ultrasonic modification. At pH = 2, 3 and 4, the adsorption capacity of the modified MSWI fly ash for Cu(Ⅱ) increased by 2.7, 1.9 and 1.2 times, respectively. Furthermore, it was suggested that the adsorption process of the modified MSWI fly ash can be better simulated by the pseudo-second-order kinetic model, with a maximum adsorption capacity calculated by the Langmuir model of 24.196 mg.g-1. Additionally, the adsorption process is spontaneous,endothermic, and chemisorption-dominated from the thermodynamic studies(ΔH and ΔS > 0, ΔG < 0).Finally, the enhanced adsorption performance of the modified MSWI fly ash for Cu(Ⅱ) may be attributed to electrostatic interaction and chelation effects. 展开更多
关键词 ULTRASOUND MSWI fly ash Cu(Ⅱ) WASTEWATER ADSORPTION
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Sodium Nitrate/Formamide Deep Eutectic Solvent as Flame-Retardant and Anticorrosive Electrolyte Enabling 2.6 V Safe Supercapacitors with Long Cyclic Stability
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作者 Huachao yang Yiheng Qi +6 位作者 Zifan Wang Qinghu Pan Chuanzhi Zhang jianhua yan Kefa Cen Zheng Bo Kostya(Ken)Ostrikov 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2024年第3期374-383,共10页
Safe operation of electrochemical capacitors(supercapacitors)is hindered by the flammability of commercial organic electrolytes.Non-flammable Water-in-Salt(WIS)electrolytes are promising alternatives;however,they are ... Safe operation of electrochemical capacitors(supercapacitors)is hindered by the flammability of commercial organic electrolytes.Non-flammable Water-in-Salt(WIS)electrolytes are promising alternatives;however,they are plagued by the limited operation voltage window(typically≤2.3 V)and inherent corrosion of current collectors.Herein,a novel deep eutectic solvent(DES)-based electrolyte which uses formamide(FMD)as hydrogen-bond donor and sodium nitrate(NaNO_(3))as hydrogen-bond acceptor is demonstrated.The electrolyte exhibits the wide electrochemical stability window(3.14 V),high electrical conductivity(14.01 mScm^(-1)),good flame-retardance,anticorrosive property,and ultralow cost(7%of the commercial electrolyte and 2%of WIS).Raman spectroscopy and Density Functional Theory calculations reveal that the hydrogen bonds between the FMD molecules and NO_(3)^(-)ions are primarily responsible for the superior stability and conductivity.The developed NaNO_(3)/FMD-based coin cell supercapacitor is among the best-performing state-of-art DES and WIS devices,evidenced by the high voltage window(2.6 V),outstanding energy and power densities(22.77 Wh kg^(-1)at 630 W kg^(-1)and 17.37 kW kg^(-1)at 12.55 Wh kg^(-1)),ultralong cyclic stability(86%after 30000 cycles),and negligible current collector corrosion.The NaNO_(3)/FMD industry adoption potential is demonstrated by fabricating 100 F pouch cell supercapacitors using commercial aluminum current collectors. 展开更多
关键词 cyclic stability deep eutectic solvents electrical conductivity electrochemical stability window SUPERCAPACITORS
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Zeolite-mediated hybrid Cu^(+)/Cu~0 interface for electrochemical nitrate reduction to ammonia
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作者 Jiabao Lv Angjian Wu +12 位作者 Liang Wang Yunhao Zhong Zhihao Zeng Qunxing Huang Xiaoqing Lin Hao Zhang Shaojun Liu Qian Liu Songqiang Zhu Xiaodong Li jianhua yan Zhifu Qi Hao Bin Wu 《Journal of Energy Chemistry》 SCIE EI CSCD 2023年第12期136-143,I0005,共9页
The electrocatalytic conversion of reactive nitrogen species to ammonia is a promising strategy for efficient NH_(3) synthesis.In this study,we reveal that the hybrid Cu^(+)/Cu~0 interface is catalytically active for ... The electrocatalytic conversion of reactive nitrogen species to ammonia is a promising strategy for efficient NH_(3) synthesis.In this study,we reveal that the hybrid Cu^(+)/Cu~0 interface is catalytically active for electrochemical ammonia synthesis from nitrate reduction.To maintain the hybrid Cu^(+)/Cu~0 state at negative reaction potentials,hydrophilic zeolite is used to modify Cu/Cu_(2)O electrocatalyst,which demonstrates an impressive NH_(3) production rate of 41.65 mg h^(-1) cm^(-2)with ~100% Faradaic efficiency of ammonia synthesis at-0.6 V vs.RHE.In-situ Raman spectroscopy unveil the high activity originates from the zeolite reconstruction at the electrode–electrolyte interface,which protects the valence state of Cu~0/Cu^(+) site under negative potential and promotes electrochemical activity towards NH_(3) synthesis. 展开更多
关键词 Electrochemical nitrate reduction reaction Ammonia synthesis In-situ Raman spectroscopy ZEOLITE Density functional theory
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基于混合溶剂有机电解液的超低温孔洞石墨烯超级电容 被引量:3
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作者 薄拯 孔竞 +4 位作者 杨化超 郑周威 陈鹏鹏 严建华 岑可法 《物理化学学报》 SCIE CAS CSCD 北大核心 2022年第4期28-37,共10页
适用于极低温环境的石墨烯超级电容具有广阔的应用前景。然而,由于片层间严重的堆叠团聚,目前石墨烯超级电容的低温储能性能并不理想。本文使用H_(2)O_(2)氧化刻蚀法制备了孔洞石墨烯(rHGO),将传统有机溶剂碳酸丙烯酯(PC)和低凝固点溶... 适用于极低温环境的石墨烯超级电容具有广阔的应用前景。然而,由于片层间严重的堆叠团聚,目前石墨烯超级电容的低温储能性能并不理想。本文使用H_(2)O_(2)氧化刻蚀法制备了孔洞石墨烯(rHGO),将传统有机溶剂碳酸丙烯酯(PC)和低凝固点溶剂甲酸甲酯(MF)混合制备了混合溶剂有机电解液,组装获得了能够在−60℃极低温环境下稳定工作的超级电容。结果表明,该超级电容在−60℃下的比电容为106.2 F·g^(-1),相对于常温电容(150.5 F·g^(-1))的性能保持率高达70.6%,显著优于未做处理的石墨烯(52.3%)以及文献中的其他石墨烯材料。得益于孔洞化形貌中丰富的介孔和大孔所形成的离子传输通道和缩短的离子传输路径,孔洞石墨烯内的离子扩散阻抗远小于普通石墨烯,且受温度降低的影响更小。在−60℃的极低温条件下,该超级电容表现出26.9 Wh·kg^(-1)的最大能量密度和18.7 kW·kg^(-1)的最大功率密度,优于传统碳材料的低温超级电容性能。−60℃时在5 A·g^(-1)电流密度下循环充放电10000次后电容保持率达89.1%,具有良好的低温循环稳定性。 展开更多
关键词 超级电容 超低温 孔洞石墨烯 混合溶剂有机电解液 电化学性能
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Degradation of PCDD/Fs in MSWI fly ash using a microwave-assisted hydrothermal process 被引量:5
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作者 Qili Qiu Xuguang Jiang +5 位作者 Guojun Lü Zhiliang Chen Shengyong Lu Mingjiang Ni jianhua yan Xiaobing Deng 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第7期1708-1715,共8页
In this work,microwave treatment was introduced to a hydrothermal treatment process to degrade PCDD/Fs(Polychlorinated dibenzo-p-dioxins and dibenzofurans)in municipal solid waste incineration(MSWI)fly ash.Three proce... In this work,microwave treatment was introduced to a hydrothermal treatment process to degrade PCDD/Fs(Polychlorinated dibenzo-p-dioxins and dibenzofurans)in municipal solid waste incineration(MSWI)fly ash.Three process additives(NaOH,Na2 HPO4,H2 O),temperatures(150℃,185℃,220℃)and reaction times(1 h,2 h,3 h)were investigated to identify their effect on the disposal of fly ash samples through orthogonal experiments.High-resolution gas chromatography–mass spectrometry(HRGC/MS)was applied to determine the PCDD/F concentrations in MSWI fly ash.The experimental results revealed that 83.7%of total PCDD/Fs was degraded.Reaction temperature was the most important factor for the degradation of the total PCDD/Fs.Both direct destruction and chlorination reactions(the chlorination degree of PCDFs increased)took part in the degradation of PCDD/Fs in fly ash,which was a new discovery.Several PCDD/F indexes determined by the concentration of indicative congeners were found to quantitatively characterize the dioxin toxicity of the fly ash.Furthermore,heavy metals in the fly ash sample were solidified using microwave-assisted hydrothermal treatment,which provided an experimental basis for the simultaneous disposal of dioxins and heavy metals.Thus,the microwave-assisted hydrothermal process should be considered for the future disposal of MSWI fly ash. 展开更多
关键词 DIOXINS DEGRADATION MSWI FLY ASH Hydrothermal treatment Microwave
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Effect of industrial microwave irradiation on the physicochemical properties and pyrolysis characteristics of lignite 被引量:5
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作者 Guoshun Zhou Qunxing Huang +3 位作者 Ben Yu Hui Tong Yong Chi jianhua yan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第5期1171-1178,共8页
The surface functional groups and pyrolysis characteristics of lignite irradiated by microwave were comparatively studied to evaluate the feasibility of using industrial 915 MHz for lignite drying. The drying kinetics... The surface functional groups and pyrolysis characteristics of lignite irradiated by microwave were comparatively studied to evaluate the feasibility of using industrial 915 MHz for lignite drying. The drying kinetics, micro structure, chemical functional groups, re-adsorption properties, and pyrolysis characteristics of the dried coal were respectively analyzed. Results indicated that for typical Chinese lignite studied in this paper, 915 MHz microwave drying was 7.8 times faster than that of the hot air drying. After industrial microwave drying, the sample possessed much higher total specific surface area and specific pore volume than that of air dried sample. The oxygen functional groups and re-adsorption ratio of microwave irradiated coal decreased, showing weakened hydrophilicity. Moreover, during the pyrolysis of the coal dried by hot air and microwave, the yield of tar largely increased from 1.3% to 8.5% and the gas production increased correspondingly. The composition of the tar was also furtherly analyzed, results indicated that Miscellaneous hydrocarbons(HCs) were the main component of the tar, and microwave irradiation can reduce the fraction of polycyclic aromatic hydrocarbons(PAHs) from 26.4% to 22.7%. 展开更多
关键词 LIGNITE Industrial microwave Physicochemical properties Pyrolysis characteristics
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Tumor microenvironment responsive drug delivery systems 被引量:5
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作者 Qunye He Jun Chen +6 位作者 jianhua yan Shundong Cai Hongjie Xiong yanfei Liu Dongming Peng Miao Mo Zhenbao Liu 《Asian Journal of Pharmaceutical Sciences》 SCIE CAS 2020年第4期416-448,共33页
Conventional tumor-targeted drug delivery systems(DDSs)face challenges,such as unsatisfied systemic circulation,low targeting efficiency,poor tumoral penetration,and uncontrolled drug release.Recently,tumor cellular m... Conventional tumor-targeted drug delivery systems(DDSs)face challenges,such as unsatisfied systemic circulation,low targeting efficiency,poor tumoral penetration,and uncontrolled drug release.Recently,tumor cellular molecules-triggered DDSs have aroused great interests in addressing such dilemmas.With the introduction of several additional functionalities,the properties of these smart DDSs including size,surface charge and ligand exposure can response to different tumor microenvironments for a more efficient tumor targeting,and eventually achieve desired drug release for an optimized therapeutic efficiency.This review highlights the recent research progresses on smart tumor environment responsive drug delivery systems for targeted drug delivery.Dynamic targeting strategies and functional moieties sensitive to a variety of tumor cellular stimuli,including pH,glutathione,adenosine-triphosphate,reactive oxygen species,enzyme and inflammatory factors are summarized.Special emphasis of this review is placed on their responsive mechanisms,drug loading models,drawbacks and merits.Several typical multi-stimuli responsive DDSs are listed.And the main challenges and potential future development are discussed. 展开更多
关键词 Cancer therapy Stimuli responsive Dynamic targeting Drug delivery system Controlled release
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Graphene Array-Based Anti-fouling Solar Vapour Gap Membrane Distillation with High Energy Efficiency 被引量:3
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作者 Biyao Gong Huachao yang +5 位作者 Shenghao Wu Guoping Xiong jianhua yan Kefa Cen Zheng Bo Kostya Ostrikov 《Nano-Micro Letters》 SCIE EI CAS CSCD 2019年第3期249-262,共14页
Photothermal membrane distillation(MD)is a promising technology for desalination and water purification.However,solar-thermal conversion suffers from low energy efficiency(a typical solar-water efficiency of ~50%),whi... Photothermal membrane distillation(MD)is a promising technology for desalination and water purification.However,solar-thermal conversion suffers from low energy efficiency(a typical solar-water efficiency of ~50%),while complex modifications are needed to reduce membrane fouling.Here,we demonstrate a new concept of solar vapour gap membrane distillation(SVGMD)synergistically combining self-guided water transport,localized heating,and separation of membrane from feed solution.A free-standing,multifunctional light absorber based on graphene array is custom-designed to locally heat the thin water layer transporting through graphene nanochannels.The as-generated vapour passes through a gap and condenses,while salt/contaminants are rejected before reaching the membrane.The high solar-water efficiency(73.4% at 1 sun),clean water collection ratio(82.3%),excellent anti-fouling performance,and stable permeate flux in continuous operation over 72 h are simultaneously achieved.Meanwhile,SVGMD inherits the advantage of MD in microorganism removal and water collection,enabling the solar-water efficiency 3.5 times higher compared to state-of-the-art solar vapour systems.A scaled system to treat oil/seawater mixtures under natural sunlight is developed with a purified water yield of 92.8 kg m-2 day-1.Our results can be applied for diverse mixed-phase feeds,leading to the next-generation solar-driven MD technology. 展开更多
关键词 SOLAR energy Plasma-made nanostructures PHOTOTHERMAL conversion Water PURIFICATION
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Highly Thermo-Conductive Three-Dimensional Graphene Aqueous Medium 被引量:2
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作者 Zheng Bo Chongyan Ying +7 位作者 Huachao yang Shenghao Wu Jinyuan yang Jing Kong Shiling yang yanguang Zhou jianhua yan Kefa Cen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2020年第10期224-235,共12页
Highly thermo-conductive aqueous medium is a crucial premise to demonstrate high-performance thermal-related applications.Graphene has the diamond comparable thermal conductivity,while the intrinsic two-dimensional re... Highly thermo-conductive aqueous medium is a crucial premise to demonstrate high-performance thermal-related applications.Graphene has the diamond comparable thermal conductivity,while the intrinsic two-dimensional reality will result in strong anisotropic thermal conductivity and wrinkles or even crumples that significantly sacrifices its inherent properties in practical applications.One strategy to overcome this is to use three-dimensional(3D)architecture of graphene.Herein,3D graphene structure with covalent-bonding nanofins(3D-GS-CBF)is proposed,which is then used as the filler to demonstrate effective aqueous medium.The thermal conductivity and thermal conductivity enhancement efficiency of 3D-GS-CBF(0.26 vol%)aqueous medium can be as high as 2.61 W m-1 K-1 and 1300%,respectively,around six times larger than highest value of the existed aqueous mediums.Meanwhile,3D-GS-CBF can be stable in the solution even after 6 months,addressing the instability issues of conventional graphene networks.A multiscale modeling including non-equilibrium molecular dynamics simulations and heat conduction model is applied to interpret experimental results.3D-GS-CBF aqueous medium can largely improve the solar vapor evaporation rate(by 1.5 times)that are even comparable to the interfacial heating system;meanwhile,its cooling performance is also superior to commercial coolant in thermal management applications. 展开更多
关键词 Three-dimensional graphene Thermo-conductive aqueous medium Multiscale modeling Solar thermal conversion Practical thermal management
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Flexible heteroatom-doped porous carbon nanofiber cages for electrode scaffolds 被引量:6
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作者 Weiping Cai Yuanyuan Zhang +1 位作者 Yongtang Jia jianhua yan 《Carbon Energy》 CAS 2020年第3期472-481,共10页
Porous carbon nanofibers(PCNFs)with rich functionalities and high surface areas are important electrode scaffolds to load active materials,but increasing their pore volumes and strength simultaneously is a challenge.H... Porous carbon nanofibers(PCNFs)with rich functionalities and high surface areas are important electrode scaffolds to load active materials,but increasing their pore volumes and strength simultaneously is a challenge.Here,we report a scalable method to fabricate B-F-N triply doped PCNF cages with high porosity of greater than 92.8%and small bending stiffness of 10 mN by electrospinning the mixed sol of poly(tetrafluoroethylene),poly(vinyl alcohol),boric acid,and carbon nanotubes(CNTs)followed by pyrolysis.The macromicro dual-phase separation creates well-controlled macropores(>60 nm)and meso-micropores with large pore volumes(0.55 cm3/g)on carbon nanofibers,while the interior CNTs can cushion the applied stress and render the PCNF films with superior flexibility.Fabricated symmetrical supercapacitors with the PCNF cages exhibit high gravimetric capacitance of 164 F/g at 20 mV/s and 92.5%capacity retention after 20000 cycles at 2 A/g.The reported approach allows the green synthesis of a new PCNF scaffold material with properties appealing for applications. 展开更多
关键词 electrode scaffold ELECTROSPINNING energy storage devices high porosity and strength porous carbon nanofiber
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Design of Supercapacitor Electrodes Using Molecular Dynamics Simulations 被引量:2
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作者 Zheng Bo Changwen Li +3 位作者 Huachao yang Kostya Ostrikov jianhua yan Kefa Cen 《Nano-Micro Letters》 SCIE EI CAS 2018年第2期162-184,共23页
Electric double-layer capacitors(EDLCs) are advanced electrochemical devices for energy storage and have attracted strong interest due to their outstanding properties. Rational optimization of electrode–electrolyte i... Electric double-layer capacitors(EDLCs) are advanced electrochemical devices for energy storage and have attracted strong interest due to their outstanding properties. Rational optimization of electrode–electrolyte interactions is of vital importance to enhance device performance for practical applications. Molecular dynamics(MD) simulations could provide theoretical guidelines for the optimal design of electrodes and the improvement of capacitive performances, e.g., energy density and power density. Here we discuss recent MD simulation studies on energy storage performance of electrode materials containing porous to nanostructures. The energy storage properties are related to the electrode structures, including electrode geometry and electrode modifications. Altering electrode geometry, i.e., pore size and surface topography,can influence EDL capacitance. We critically examine different types of electrode modifications, such as altering the arrangement of carbon atoms, doping heteroatoms and defects, which can change the quantum capacitance. The enhancement of power density can be achieved by the intensified ion dynamics and shortened ion pathway.Rational control of the electrode morphology helps improve the ion dynamics by decreasing the ion diffusion pathway. Tuning the surface properties(e.g., the affinity between the electrode and the ions) can affect the ionpacking phenomena. Our critical analysis helps enhance the energy and power densities of EDLCs by modulating the corresponding electrode structures and surface properties. 展开更多
关键词 Electric double-layer capacitors Molecular dynamics Porous structure NANOSTRUCTURE
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Mucoepidermoid Carcinoma of the Eyelid: A Case Report and Review of the Literature 被引量:2
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作者 Hao Zhang jianhua yan +1 位作者 Yongping Li Ping Zhang 《Eye Science》 CAS 2005年第3期152-157,共6页
Purpose: To report the clinical features, therapeutic method, and histopathological findings of a case of mucoepidermoid carcinoma in the lower eyelid and review the literature about the mucoepidermoid carcinoma arisi... Purpose: To report the clinical features, therapeutic method, and histopathological findings of a case of mucoepidermoid carcinoma in the lower eyelid and review the literature about the mucoepidermoid carcinoma arising from the eye.Methods: Case report and review of the literature.Results: An 88-year-old man developed a painless, indurated nodule in the left lower eyelid for two years and ulceration of the skin existed for a year. He underwent tumor resection and reconstruction of the eyelid. By histopathology, tumor cells showed an admixture of epidermoid and mucus-secreting cells, which was consistent with mucoepidermoid carcinoma. Mucoepidermoid carcinoma is a common malignant tumor of the salivary glands, but rare in the eye tissues among which conjunctiva and lacrimal gland are most commonly involved. It has a higher degree of malignancy than basal cell carcinoma and squamous cell carcinoma. It displays an unusual capacity of aggressive local invasion and recurs easily after simple excision and tumors may require enucleation or exenteration because of the involvement of the intraocular structures and/or orbit.Frequent follow-up is necessary for the patient after operation.Conclusions: Mucoepidermoid carcinoma arising from the eye is rare and has a high degree of malignancy. It should be differentiated from other neoplasms such as basal cell carcinoma and squamous cell carcinoma. 展开更多
关键词 眼睑肿瘤 病例报告 临床表现 组织病理学 溃疡疾病
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Experimental and simulation investigation of electrical and plasma parameters in a low pressure inductively coupled argon plasma 被引量:1
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作者 Jian yanG Angjian WU +6 位作者 Xiaodong LI yang LIU Fengsen ZHU Zhiliang CHEN jianhua yan Ruijuan CHEN Wangjun SHEN 《Plasma Science and Technology》 SCIE EI CAS CSCD 2017年第11期12-22,共11页
The electrical and plasma parameters of a low pressure inductively coupled argon plasma are investigated over a wide range of parameters(RF power, flow rate and pressure) by diverse characterizations. The external a... The electrical and plasma parameters of a low pressure inductively coupled argon plasma are investigated over a wide range of parameters(RF power, flow rate and pressure) by diverse characterizations. The external antenna voltage and current increase with the augment of RF power, whereas decline with the enhancement of gas pressure and flow rate conversely.Compared with gas flow rate and pressure, the power transfer efficiency is significantly improved by RF power, and achieved its maximum value of 0.85 after RF power injected excess125 W. Optical emission spectroscopy(OES) provides the local mean values of electron excited temperature and electron density in inductively coupled plasma(ICP) post regime, which vary in a range of 0.81 eV to 1.15 eV and 3.7×10^(16)m^(-3)to 8.7×10^(17)m^(-3)respectively. Numerical results of the average magnitudes of electron temperature and electron density in twodimensional distribution exhibit similar variation trend with the experimental results under different operating condition by using COMSOL Multiphysics. By comprehensively understanding the characteristics in a low pressure ICP, optimized operating conditions could be anticipated aiming at different academic and industrial applications. 展开更多
关键词 ICP OES simulation electrical properties
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Conversion of coalbed methane surrogate into hydrogen and graphene sheets using rotating gliding arc plasma
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作者 Angjian WU Hang CHEN +8 位作者 Jiageng ZHENG Jian yanG Xiaodong LI Changming DU Zhiliang CHEN Aoni XU Jie QIU Yi XU jianhua yan 《Plasma Science and Technology》 SCIE EI CAS CSCD 2019年第11期55-67,共13页
The use of atmospheric rotating gliding arc(RGA)plasma is proposed as a facile,scalable and catalyst-free approach to synthesizing hydrogen(H2)and graphene sheets from coalbed methane(CBM).CH4 is used as a CBM surroga... The use of atmospheric rotating gliding arc(RGA)plasma is proposed as a facile,scalable and catalyst-free approach to synthesizing hydrogen(H2)and graphene sheets from coalbed methane(CBM).CH4 is used as a CBM surrogate.Based on a previous investigation of discharge properties,product distribution and energy efficiency,the operating parameters such as CH4 concentration,applied voltage and gas flow rate can effectively affect the CH4 conversion rate,the selectivity of H2 and the properties of solid generated carbon.Nevertheless,the basic properties of RGA plasma and its role in CH4 conversion are scarcely mentioned.In the present work,a 3D RGA model,with a detailed nonequilibrium CH4/Ar plasma chemistry,is developed to validate the previous experiments on CBM conversion,aiming in particular at the distribution of H2 and other gas products.Our results demonstrate that the dynamics of RGA is derived from the joint effects of electron convection,electron migration and electron diffusion,and is prominently determined by the variation of the gas flow rate and applied voltage.Subsequently,a combined experimental and chemical kinetical simulation is performed to analyze the selectivity of gas products in an RGA reaction,taking into consideration the formation and loss pathways of crucial targeted substances(such as CH4,C2H2,H2 and H radicals)and corresponding contribution rates.Additionally,the effects of operating conditions on the properties of solid products are investigated by scanning electron microscopy(SEM)and Raman spectroscopy.The results show that increasing the applied voltage and decreasing CH4 concentration will change the solid carbon from its initial spherical structure into folded multilayer graphene sheets,while the size of the graphene sheets is slightly affected by the change in gas flow rate. 展开更多
关键词 coalbed METHANE HYDROGEN graphene SHEETS ROTATING GLIDING arc(RGA) multi-physical field coupling plasma chemistry
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Co-synthesis of vertical graphene nanosheets and high-value gases using inductively coupled plasma enhanced chemical vapor deposition
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作者 Jian yanG Ruiyang XU +4 位作者 Angjian WU Xiaodong LI Li LI Wangjun SHEN jianhua yan 《Plasma Science and Technology》 SCIE EI CAS CSCD 2018年第12期86-95,共10页
One-step controllable synthesis of vertical graphene nanosheets (VGs) and high-value gases was achieved using inductively coupled plasma enhanced chemical vapor deposition (ICPECVD). The basic physical properties ... One-step controllable synthesis of vertical graphene nanosheets (VGs) and high-value gases was achieved using inductively coupled plasma enhanced chemical vapor deposition (ICPECVD). The basic physical properties of the ICPECVD process were revealed via electrical diagnosis and optical emission spectroscopy. The coil current and voltage increased linearly with the augmenting of injected power, and CH, C2, H2 and H were detected at a wavelength from 300 to 700 nm, implying the generation of abundant graphene-building species. The morphology and structure of solid carbon products, graphene nanosheets, were systemically characterized in terms of the variations of operating conditions, such as pressure, temperature, gas proportion, etc. The results indicated that an appropriate operating condition was indispensable for the growth process of graphene nanosheets. In the present work, the optimized result was achieved at the pressure, heating temperature, applied power and gas proportion of 600 mTorr, 800 ~C, 500 W and 20:20:15, respectively, and the augmenting of both CH4 and H2 concentrations had a positive effect on the etching of amorphous carbon. Additionally, H2 and C2 hydrocarbons were detected as the main exhaust gases. The selectivity of H2 and C2H2, measured in exhaust gases, reached up to 52% and 8%, respectively, which implied a process of free radical reactions and electron collision dissociation. Based on a comprehensive investigation of spectral and electrical parameters and synthesized products, the reaction mechanism of collision, dissociation, diffusion, etc, in ICPECVD could be speculated, providing a probable guide for experimental and industrial applications. 展开更多
关键词 vertical graphene nanosheets gaseous products OES electrical diagnosis ICPECVD
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Synthesis of vertical graphene nanowalls by cracking n-dodecane using RF inductively-coupled plasma-enhanced chemical vapor deposition
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作者 Jiageng ZHENG Qinhuai TAN +5 位作者 Hang CHEN Angjian WU Xiaodong LI jianhua yan Jiaxu DAI Jiao ZHOU 《Plasma Science and Technology》 SCIE EI CAS CSCD 2020年第2期95-103,共9页
A facile and controllable one-step method to treat liquid hydrocarbons and synthesize vertical graphene nanowalls has been developed by using the technique of inductively-coupled plasma-enhanced chemical vapor deposit... A facile and controllable one-step method to treat liquid hydrocarbons and synthesize vertical graphene nanowalls has been developed by using the technique of inductively-coupled plasma-enhanced chemical vapor deposition for plasma cracking of n-dodecane.Herein,the morphology and microstructure of solid carbon material and graphene nanowalls are characterized in terms of different operating conditions,i.e.input power,H2/Ar ratio,injection rate and reaction temperature.The results reveal that the optimal operating conditions were 500 W,5:10,30μl min^-1 and 800℃ for the input power,H2/Ar ratio,injection rate and reaction temperature,respectively.In addition,the degree of graphitization and the gaseous product are analyzed by Raman spectroscopy and gas chromatography detection.It can be calculated from the Raman spectrum that the relative intensity of ID/IG is approximately 1.55,and I2D/IG is approximately 0.48,indicating that the graphene prepared from n-dodecane has a rich defect structure and a high degree of graphitization.By calculating the mass loading and detecting the outlet gas,we find that the cracking rate of n-dodecane is only 6%-7%and that the gaseous products below C2 mainly include CH4,C2H2,C2H4,C2H6 and H2.Among them,the proportion of hydrogen in the outlet gas of n-dodecane cracking ranges from 1.3%-15.1%under different hydrogen flows.Based on our research,we propose a brand new perspective for both liquid hydrocarbon treatment and other value-added product syntheses. 展开更多
关键词 ICPECVD n-dodecane cracking vertical graphene nanowalls
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Efficient Strip-Mode SAR Raw-Data Simulator of Extended Scenes Included Moving Targets Based on Reversion of Series
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作者 Liang yang Daojian Zeng +1 位作者 jianhua yan Yaozhang Sai 《Computers, Materials & Continua》 SCIE EI 2020年第7期313-323,共11页
The Synthetic Aperture Radar(SAR)raw data generator is required to the evaluation of focusing algorithms,moving target analysis,and hardware design.The time-domain SAR simulator can generate the accurate raw data but ... The Synthetic Aperture Radar(SAR)raw data generator is required to the evaluation of focusing algorithms,moving target analysis,and hardware design.The time-domain SAR simulator can generate the accurate raw data but it needs much time.The frequency-domain simulator not only increases the efficiency but also considers the trajectory deviations of the radar.In addition,the raw signal of the extended scene included static and moving targets can be generated by some frequency-domain simulators.However,the existing simulators concentrate on the raw signal simulation of the static extended scene and moving targets at uniform speed mostly.As for the issue,the two-dimensional signal spectrum of moving targets with constant acceleration can be derived accurately based on the geometric model of a side-looking SAR and reversion of series.And a frequency-domain algorithm for SAR echo signal simulation is presented based on the two-dimensional signal spectrum.The raw data generated with proposed method is verified by several simulation experiments.In addition to reveal the efficiency of the presented frequency-domain SAR scene simulator,the computational complexity of the proposed method is compared with the time-domain approach using the complex multiplication.Numerical results demonstrate that the present method can reduce the computational time significantly without accuracy loss while simulating SAR raw data. 展开更多
关键词 Raw data simulation moving target reversion of series
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