Amorphous filler Ti-Zr-Cu-Ni with better performance and higher melting point than the α → β phase transition temperature 882.5°C of TA2, is appropriate for joining TC and TB titanium alloys but not for TA t...Amorphous filler Ti-Zr-Cu-Ni with better performance and higher melting point than the α → β phase transition temperature 882.5°C of TA2, is appropriate for joining TC and TB titanium alloys but not for TA titanium alloys, with which the ductility of the joined base metal TA2 gets down. In this paper, Sn is added into Ti-Zr-Cu-Ni filler to reduce its melting temperature then to satisfy the joining temperature requirement, and the effects of the content of Sn on the microstructure of the alloy and brazing performance are investigated. The results show that, the Ti-Zr-Cu-Ni-Sn brazing foils still possess amorphous structure;the melting point of fillers is reducing with the increase of the Sn content;the joint gap that formed during brazing TA2 and Q235 using Ti-Zr-Cu-Ni-Sn foils is fully filled with continuous compact surface and smooth uniform fillet;the shear strength of the joint is raising with the increase of Sn content in brazing fillers and the strength reaches to 112 MPa when Sn content is 3%;adding more Sn, more brittle intermetallic compounds TiFe and TiFe2 are gathering to form cluster and the shear strength of the joint is reducing;the shear fracture always occurs in the center of the seam.展开更多
Ti-Zr-Cu-Ni amorphous filler with good performance is suitable for joining TC and TB titanium alloy, but its melting temperature is higher than 882.5°C, the α→β phase transition temperature of TA2, which makes...Ti-Zr-Cu-Ni amorphous filler with good performance is suitable for joining TC and TB titanium alloy, but its melting temperature is higher than 882.5°C, the α→β phase transition temperature of TA2, which makes the ductility of TA2 fall and the microstructure of the joint coarse. In this paper, Ti-Zr-Cu-Ni amorphous filler was redesigned and optimized by using orthogonal experiment to obtain three easy-to-use Zr-Ti-Ni-Cu amorphous fillers with low melting points and good plasticity. The fast cooling equipment was used to fabricate the brazing filler foils to implement the braze welding of TA2 and Q235 with high frequency inductance. The results indicate that all the brazing foils are amorphous structure with lower melting temperature, for example, Zr52Ti22Ni18Cu8 filler’s is 538°C. The technical parameters in brazing welding are: welding temperature T = 800°C;heating electric current I =25 A;heating time t = 15 s and holding time t = 15 s, in the case of these conditions, the jointing head shear strength of TA2/Zr52Ti24Ni13Cu11/Q235 is 139 MPa. Fracture is mainly located in the brazing seam. The white brittle intermetallic TiFe, TiFe2 and enhancement TiC spread in the center zone of brazing seam.展开更多
文摘Amorphous filler Ti-Zr-Cu-Ni with better performance and higher melting point than the α → β phase transition temperature 882.5°C of TA2, is appropriate for joining TC and TB titanium alloys but not for TA titanium alloys, with which the ductility of the joined base metal TA2 gets down. In this paper, Sn is added into Ti-Zr-Cu-Ni filler to reduce its melting temperature then to satisfy the joining temperature requirement, and the effects of the content of Sn on the microstructure of the alloy and brazing performance are investigated. The results show that, the Ti-Zr-Cu-Ni-Sn brazing foils still possess amorphous structure;the melting point of fillers is reducing with the increase of the Sn content;the joint gap that formed during brazing TA2 and Q235 using Ti-Zr-Cu-Ni-Sn foils is fully filled with continuous compact surface and smooth uniform fillet;the shear strength of the joint is raising with the increase of Sn content in brazing fillers and the strength reaches to 112 MPa when Sn content is 3%;adding more Sn, more brittle intermetallic compounds TiFe and TiFe2 are gathering to form cluster and the shear strength of the joint is reducing;the shear fracture always occurs in the center of the seam.
文摘Ti-Zr-Cu-Ni amorphous filler with good performance is suitable for joining TC and TB titanium alloy, but its melting temperature is higher than 882.5°C, the α→β phase transition temperature of TA2, which makes the ductility of TA2 fall and the microstructure of the joint coarse. In this paper, Ti-Zr-Cu-Ni amorphous filler was redesigned and optimized by using orthogonal experiment to obtain three easy-to-use Zr-Ti-Ni-Cu amorphous fillers with low melting points and good plasticity. The fast cooling equipment was used to fabricate the brazing filler foils to implement the braze welding of TA2 and Q235 with high frequency inductance. The results indicate that all the brazing foils are amorphous structure with lower melting temperature, for example, Zr52Ti22Ni18Cu8 filler’s is 538°C. The technical parameters in brazing welding are: welding temperature T = 800°C;heating electric current I =25 A;heating time t = 15 s and holding time t = 15 s, in the case of these conditions, the jointing head shear strength of TA2/Zr52Ti24Ni13Cu11/Q235 is 139 MPa. Fracture is mainly located in the brazing seam. The white brittle intermetallic TiFe, TiFe2 and enhancement TiC spread in the center zone of brazing seam.