Nonreciprocity of energy transfer in a nonlinear asymmetric oscillator system with various vibration states

The nonreciprocity of energy transfer is constructed in a nonlinear asymmetric oscillator system that comprises two nonlinear oscillators with different parameters placed between two identical linear oscillators.The slow-flow equation of the system is derived by the complexification-averaging method.The semi-analytical solutions to this equation are obtained by the least squares method,which are compared with the numerical solutions obtained by the Runge-Kutta method.The distribution of the average energy in the system is studied under periodic and chaotic vibration states,and the energy transfer along two opposite directions is compared.The effect of the excitation amplitude on the nonreciprocity of the system producing the periodic responses is analyzed,where a three-stage energy transfer phenomenon is observed.In the first stage,the energy transfer along the two opposite directions is approximately equal,whereas in the second stage,the asymmetric energy transfer is observed.The energy transfer is also asymmetric in the third stage,but the direction is reversed compared with the second stage.Moreover,the excitation amplitude for exciting the bifurcation also shows an asymmetric characteristic.Chaotic vibrations are generated around the resonant frequency,irrespective of which linear oscillator is excited.The excitation threshold of these chaotic vibrations is dependent on the linear oscillator that is being excited.In addition,the difference between the energy transfer in the two opposite directions is used to further analyze the nonreciprocity in the system.The results show that the nonreciprocity significantly depends on the excitation frequency and the excitation amplitude.

One-step electrochemical in-situ Li doping and LiF coating enable ultra-stable cathode for sodium ion batteries

Despite of the higher energy density and inexpensive characteristics,commercialization of layered oxide cathodes for sodium ion batteries(SIBs)is limited due to the lack of structural stability at the high voltage.Herein,the one-step electrochemical in-situ Li doping and LiF coating are successfully achieved to obtain an advanced Na0.79Lix[Li_(0.13)Ni_(0.20)Mn_(0.67)]O_(2)@LiF(NaLi-LNM@LiF)cathode with superlattice structure.The results demonstrate that the Li^(+)doped into the alkali metal layer by electrochemical cycling act as"pillars"in the form of Li-Li dimers to stabilize the layered structure.The supplementation of Li to the superlattice structure inhibits the dissolution of transition metal ions and lattice mismatch.Furthermore,the in-situ LiF coating restrains side reactions,reduces surface cracks,and greatly improves the cycling stability.The electrochemical in-situ modification strategy significantly enhances the electrochemical performance of the half-cell.The NaLi-LNM@LiF exhibits high reversible specific capacity(170.6 m A h g^(-1)at 0.05 C),outstanding capacity retention(92.65%after 200 cycles at 0.5 C)and excellent rate performance(80 mA h g^(-1)at 7 C)in a wide voltage range of 1.5-4.5 V.This novel method of in-situ modification by electrochemical process will provide a guidance for the rational design of cathode materials for SIBs.

MOF-derived molybdenum selenide on Ti_(3)C_(2)T_(x) with superior capacitive performance for lithium-ion capacitors

Two-dimensional Ti_(3)C_(2)T_(x) exhibits outstanding rate property and cycle performance in lithium-ion capacitors(LICs)due to its unique layered structure,excellent electronic conductivity,and high specific surface area.However,like graphene,Ti_(3)C_(2)T_(x) restacks during electrochemical cycling due to hydrogen bonding or van der Waals forces,leading to a decrease in the specific surface area and an increase in the diffusion distance of electrolyte ions between the interlayer of the material.Here,a transition metal selenide MoSe_(2) with a special three-stacked atomic layered structure,derived from metal-organic framework(MOF),is introduced into the Ti_(3)C_(2)T_(x) structure through a solvo-thermal method.The synergic effects of rapid Li+diffusion and pillaring effect from the MoSe_(2) and excellent conductivity from the Ti_(3)C_(2)T_(x) sheets endow the material with excellent electrochemical reaction kinetics and capacity.The composite Ti_(3)C_(2)T_(x)@MoSe_(2) material exhibits a high capacity over 300 mAh·g^(-1) at 150 mA·g^(-1) and excellent rate property with a specific capacity of 150 mAh·g^(-1) at 1500 mA·g^(-1).Addition-ally,the material shows a superior capacitive contribution of 86.0%at 2.0 mV·s^(-1) due to the fast electrochemical reactions.A Ti_(3)C_(2)T_(x)@MoSe_(2)//AC LIC device is also fabricated and exhibits stable cycle performance.

Optimize two-phase distribution of lithium-rich materials to stabilize structure and suppress voltage attenuation

Lithium-rich materials possess the ultra-high specific capacity,but the redox of oxygen is not completely reversible,resulting in voltage attenuation and structural instability.A stepwise co-precipitation method is used for the first time in this paper to achieve the control of the two-phase distribution through controlling the distribution of transition metal elements and realize the modification of particle surface structure without the aid of heterologous ions.The results of characterization tests show that the content of LiMO_(2) phase inside the particles and the content of Li_(2)MnO_(3) phase on the surface of the particles are successfully increased,and the surface induced formation of Li_(4)Mn_(5)O_(12) spinel phase or some disorderly ternary.The electrochemical performance of the modified sample is as follows:LR(pristine)shows specific discharge capacity of 72.7 mA·h·g^(−1)after 500 cycles at 1 C,while GR(modified sample)shows specific discharge capacity of 137.5 mA·h·g^(−1) at 1 C,and the discharge mid-voltage of GR still remains above 3 V when cycling to 220 cycles at 1 C(mid-voltage of LR remains above 3 V when cycling to 160 cycles at 1 C).Therefore,deliberately regulating the local state of the two phases is a successful way to reinforced the material structure and inhibition the voltage attenuation.

Performance measurement and evaluation of an ionic liquid electrospray thruster

As a novel micro-propulsion system for small satellites(from micro to nano),the ionic liquid electro spray propulsion system is a promising candidate.However,performance measurement and evaluation of the Ionic Liquid Electrospray Thruster(ILET)is one of the most challenging issues for practical application,due to the difficulties in the development of a prototype and direct measurements of micro-thrust and small flow rate.To address this issue,a Modular Ionic Liquid Electrospray Thruster(MILET)prototype is constructed,and a diagnostic system for thrust and mass flow rate is specially developed based on an analytical balance method.With the ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate as the propellant,a series of experiments is carried out on the MILET prototype under a wide operating condition through changing the applied voltage to control the thrust.Under different applied voltages,the thrust and the mass flow rate of the propellant are directly measured.The propulsive performance parameters of the thruster,such as thrust,specific impulse,thrust-to-power ratio,thruster efficiency,etc.,are comprehensively analyzed.Then,a performance comparison is made between the MILET and other representative ILETs.With a relatively low applied voltage ranging from 1550 V to 2000 V,the MILET achieves a quasi-constant specific impulse of 1263 s with the averaged thrust-to-power ratio of 65.2μN/W and thruster efficiency of 40.7%.The performance of ILET is also compared with other typical electric propulsions.The results demonstrate that the ILET exhibits an excellent ability of minimalization with high specific impulse and thruster efficiency,which guarantees a great superiority in micro propulsions.Finally,the ways to further improve the performance of ILET are discussed,which further confirms the potential prospect of ILET.The present result helps to advance the development and application of ILET.

Investigation of hot jet on active control of oblique detonation waves

The hot jet injection is utilized to actively control the oblique detonation wave,such as initiating and stabilizing an oblique detonation wave at a desired position that is shorter than the length of induction zone,and adjust the height of the oblique detonation wave at the exit of combustor when the oblique detonation wave engine is working on off-design flight conditions.The fifth order Weighted Essentially Non-Oscillatory(WENO)scheme and a two-step reversible reaction mechanism of the stoichiometric H_2/Air are adopted in the simulations.With the help of hot jet injection,the transition from inert oblique shock wave to the oblique detonation wave immediately occurs near the position of hot jet injection,and consequently the length of combustor can be reduced.The angle of oblique detonation wave also decreases as the hot jet injection approaches the nose of wedge.Additionally,the height of the oblique detonation wave at the exit of combustor can be flexibly adjusted,and also depends on the injection position and the strength of the hot jet.If the velocity of the hot jet is too weak to directly trigger the overall oblique detonation wave at the position of injection,increasing the injection pressure will improve the strength of the hot jet and results in a successful transition.

Nanoscale noble metals with a hollow interior formed through inside-out diffusion of silver in solid-state core- shell nanoparticles

有空内部和可定制的壳作文的高贵金属 nanoparticles 为许多应用有巨大的潜力。此处，我们在场为有空结构的高贵金属 nanoparticles 的合成的灵巧、一般、划算的策略，它基于在内外面 Ag 在的散开固态核心壳 nanoparticles。这条途径与居住在核心区域的 Ag 以核心壳 nanoparticles 的准备开始，它然后在稳固的底层上被装载并且在空中变老允许在内外面从核心区域的 Ag 的散开，导致形成一金属或合金有一个空内部的高贵金属 nanoparticles 。合成在房间温度被执行并且能在不同稳固的底层上被完成。特别地，自从它，在内外面，为关于基于 Ag 的核心壳 nanoparticles 的催化表演的评估的特定的担心的 Ag 电话的散开可以潜在地防碍核心壳粒子的物理、化学的性质。

A theoretical and 1-D numerical investigation on a valve/valveless air-breathing pulse detonation engine

The important operating characteristics of pulsed Pressure Gain Combustion(PGC)propulsion are the pressure gain of the combustor component and the propulsive performance gain of the engine.A ramjet-type valve/valveless air-breathing pulsed detonation engine with a supersonic internal compression inlet is investigated.Based on an ideal thermal cycle,the ideal equivalent pressure ratios(pcb)of the Pulsed Detonation Combustor(PDC)are obtained theoretically which are directly related with the propulsive performance of the engine.By introducing an orifice loss model into the cycles,the critical pressure drop ratios through the orifice for the PDC achieving pressure gain and the engine achieving thrust gain are studied.More influencing factors are investigated by the use of a one-dimensional(1-D)numerical simulation model.The operating characteristics of the pulse detonation engine are investigated with changes of the valve type,the inlet/outlet area ratio of the PDC,the nozzle area ratio,and flight conditions.All these factors can affect pcbof the PDC,and pcbcan be optimized by changing the geometry of the engine.The most important influence parameter is the valve type.When using an orifice-type aerodynamic valve,simulation results show that the PDC cannot achieve the pressure gain characteristics.When a supersonic internal compression inlet is introduced to the engine,whether the Pulse Detonation Engine(PDE)can achieve thrust gain comparable with that of an ideal Brayton cycle engine not only is related to the pressure gain of the combustor,but also needs to optimize the engine structure to reduce the total pressure loss.

Microwave-hydrothermal preparation of a graphene/hierarchy structure MnO_2 composite for a supercapacitor

Graphene/hierarchy structure manganese dioxide （GN/MnO2） composites were synthesized using a simple microwave-hydrothermal method. The properties of the prepared composites were analyzed using field emission scanning electron microscopy （FE-SEM）, X-ray diffraction （XRD）, transmission electron microscopy （TEM）, and X-ray photoelectron spectroscopy （XPS） measurements. The electrochemical performances of the composites were analyzed using cyclic voltammetry, electrochemical impedance spectrometry （EIS）, and chronopotentiometry. The results showed that GN/MnO2 （10 wt% graphene） displayed a specific capacitance of 244 F/g at a current density of 100 mA/g. An excellent cyclic stability was obtained with a capacity retention of approximately 94.3% after 500 cycles in a 1 mol/L Li2SO4 solution. The improved electrochemical performance is attributed to the hierarchy structure of the manganese dioxide, which can enlarge the interface between the active materials and the electrolyte. The prepa- ration route provides a new approach for hierarchy structure graphene composites; this work could be readily extended to the preparation of other graphene-based composites with different structures for use in energy storage devices.

MXenes@Te作为高性能铝电池复合正极材料

新兴的二维材料MXenes在储能领域中发挥着重要作用,并展现了优异的电化学性能.本文中我们制备了二维层状MXenes(F-Ti_(3)C_(2)T_(x)),通过高温蒸镀法将Te单质负载在F-Ti_(3)C_(2)T_(x)的表面,以MXenes@Te作为铝电池正极,其首次充/放电比容量为987/1096 mAh g^(-1).在不同电流密度条件下,铝电池的放电电压平台稳定在1.3 V左右,当以MXenes@Te为活性材料计算时,铝电池的比容量为258 mAh g^(-1),这得益于MXenes材料优异的电导率及其二维层状结构.通过密度泛函理论探索了其机理,计算结果表明,Ti_(3)C_(2)O_(2)@Te比Ti_(3)C_(2)O_(2)更倾向于吸附[AlCl_(4)]^(-).此外,通过热力学计算(Factsage7.1)和X射线光电子能谱研究了元素Te的价态变化.研究结果表明,当铝电池充满至2.4 V时,单质Te和Ti离子(Ti^(3+),Ti^(2+))被氧化为Te^(4+)和Ti^(4+).在放电过程中,高价态的Te^(4+)和Ti^(4+)被重新还原为单质Te和Ti离子(Ti^(3+),Ti^(2+)).当放电电压低于0.6 V时,单质Te被还原为更低价态的Te^(2-),而要将单质Te氧化为Te^(6+),则需要更高的充电电压(2.56 V).