Improving catalytic performance is a yet still challenge in thermal catalytic oxidation.Herein,uniform mesoporous MnO_(2) nanospheresupported bimetallic Pt–Pd nanoparticles were successfully fabricated via a SiO_(2) ...Improving catalytic performance is a yet still challenge in thermal catalytic oxidation.Herein,uniform mesoporous MnO_(2) nanospheresupported bimetallic Pt–Pd nanoparticles were successfully fabricated via a SiO_(2) template strategy for the total catalytic degradation of volatile organic compounds at low temperature.The introduction of mesopores into the MnO_(2) support induces a large specific surface area and pore size,thus providing numerous accessible active sites and enhanced diffusion properties.Moreover,the addition of a secondary noble metal can adjust the O_(ads)/O_(latt) molar ratios,resulting in high catalytic activity.Among them,the catalyst having a Pt/Pd molar ratio of 7:3 exhibits optimized catalytic activity at a weight hourly space velocity of 36,000 mL g^(-1) h^(-1),reaching 100%toluene oxidation at 175℃ with a lower activation energy(57.0 kJ mol^(-1))than the corresponding monometallic Pt or non-Pt-based catalysts(93.8 kJ mol^(-1) and 214.2 kJ mol^(-1)).Our findings demonstrate that the uniform mesoporous MnO_(2) nanosphere-supported bimetallic Pt–Pd nanoparticles catalyst is an effective candidate for application in elimination of toluene.展开更多
Manganese oxide(MnO_(2))exhibits excellent activity for volatile organic compound oxidation.However,it is currently unknown whether lattice oxygen or adsorbed oxygen is more conducive to the progress of the catalytic ...Manganese oxide(MnO_(2))exhibits excellent activity for volatile organic compound oxidation.However,it is currently unknown whether lattice oxygen or adsorbed oxygen is more conducive to the progress of the catalytic reaction.In this study,novel hollow highly dispersed Pt/Copper modified-MnO_(2)catalysts were fabricated.Cu^(2+)was stabilized into theδ-MnO_(2)cladding substituting original K+,which produced lattice defects and enhance the content of adsorbed oxygen.The 2.03 wt%Pt Cu_(0.050)-MnO_(2)catalyst exhibited the highest catalytic activity and excellent stability for toluene and benzene oxidation,with T_(100)=160℃under high space velocity(36,000 mL g^(-1)h^(-1)).The excellent performance of catalytic oxidation of VOCs is attributed to the abundant adsorbed oxygen content,excellent low-temperature reducibility and the synergistic catalytic effect between the Pt nanoparticles and Cu_(0.050)-MnO_(2).This study provides a comprehensive understanding of the Langmuir-Hinshelwood(L-H)mechanism occurring on the catalysts.展开更多
As one of the most attractive and eco-friendly technologies,semiconductor photocatalysis is demonstrated as a potential strategy to solve global energy shortage environmental pollution problems.Regarding semiconductor...As one of the most attractive and eco-friendly technologies,semiconductor photocatalysis is demonstrated as a potential strategy to solve global energy shortage environmental pollution problems.Regarding semiconductor-based photocatalysts,Zinc indium sulfide(ZnIn_(2)S_(4)) with various morphological structures has become research hotspots owing to its superior visible light absorption,high chemical durability and low cost.Nevertheless,the photocatalytic activity of pristine ZnIn_(2)S_(4) is unsatisfactory due to limited range of visible light absorption and fast recombination rate of light-induced electrons and holes.Different modification strategies,such as metal deposition,element doping,vacancy engineering and semiconductor combination,have been systematically developed for enhancing the photocatalytic performance of ZnIn_(2)S_(4) materials.In order to promote further developments of ZnIn_(2)S_(4) in photocatalytic applications,this mini-review summarizes the progress of recent research works for the construction of highly activity ZnIn_(2)S_(4)-based photocatalysts for the first time.In addition,the typical applications of ZnIn_(2)S_(4)-based photocatalytic materials have been critically reviewed and described such as in hydrogen evolution from photocatalytic water splitting,carbon dioxide photoreduction,and treatment of water pollution.The current challenges and further prospects for the development of ZnIn_(2)S_(4) semiconductor photocatalysts are finally pointed out.展开更多
[Objectives]This study aimed to study and analyze the main components of the oil from seeds of 8 different pomegranate varieties.[Methods]The oil in sour and sweet pomegranate seeds was extracted by ultrasonic-assiste...[Objectives]This study aimed to study and analyze the main components of the oil from seeds of 8 different pomegranate varieties.[Methods]The oil in sour and sweet pomegranate seeds was extracted by ultrasonic-assisted method,and the composition of the soil after methyl esterification was identified by GC-MS.[Results]The oil yield of the four sweet pomegranate varieties and the four sour pomegranate varieties ranged from 9.43%-16.97%.A total of 6 compounds were identified in the methyl esterified pomegranate seed oil by GC-MS.[Conclusions]There were no significant differences in oil yield between sweet and sour pomegranate varieties(P>0.05).The content of methyl punicate in the four sweet pomegranate varieties was 52.18%-78.06%,and that in the four sour pomegranate varieties was 78.25%-84.55%.The content of methyl punicate in sour pomegranate was slightly higher than that in sweet pomegranate.展开更多
Because of its importance in enhancing charge separation and transfer,built-in electric field engineering has been acknowledged as an effective technique for improving photocatalytic performance.Herein,a stable p–n h...Because of its importance in enhancing charge separation and transfer,built-in electric field engineering has been acknowledged as an effective technique for improving photocatalytic performance.Herein,a stable p–n heterojunction of 2D/2D(2D:twodimensional)Co_(3)O_(4)/ZnIn_(2)S_(4)with a strong built-in electric field is precisely constructed.The Co_(3)O_(4)/ZnIn_(2)S_(4)heterojunction exhibits a higher visible-light photocatalytic hydrogen(H2)evolution rate than the individual components,which is primarily attributed to the synergy effect of improved light absorption,abundant active sites,short charge transport distance,high separation efficiency of photogenerated carriers.Furthermore,the photoelectrochemical studies and density functional theory(DFT)calculation results demonstrate that the enhanced interfacial charge separation and migration induced by the generated built-in electric field are the critical reasons for the boosted photocatalytic performance.This research might pave the way for the rational design and manufacturing of 2D/2D heterojunction photocatalysts with extremely efficient photocatalytic performance for solar energy conversion.展开更多
4-(3-(4-(Dimethylamino)phenyl)acryloyl)phenyl-2-bromo-2-methylpropanoate(APPBr)was used for the heterogeneous atom transfer radical polymerization(ATRP)of styrene(St)with copper(I)bromide/N,N,N',N",N"-pe...4-(3-(4-(Dimethylamino)phenyl)acryloyl)phenyl-2-bromo-2-methylpropanoate(APPBr)was used for the heterogeneous atom transfer radical polymerization(ATRP)of styrene(St)with copper(I)bromide/N,N,N',N",N"-pentamethyldiethylenetriamine(PMDETA)catalytic system.The functional end group was characterized via UV-Vis and ^(1)H NMR spectra.The polymerization showed a first-order kinetic characteristic and each of the obtained polymers had well-controlled molecular weight and relatively low polydispersity index(PDI).Furthermore,the obtained end-functionalized polystyrene(PS)in solution showed strong green-light emission which is further affected by mixing different metal cations.In particular,the fluorescent intensity of the polymer was decreased in the presence of Ag^(+),Cu^(2+)and Fe^(3+).展开更多
High-entropy materials are mainly composed of high-entropy alloys(HEAs)and their derivates.Among them,HEAs account for a big part.As a new kind of alloy,they are now arousing great interests because of their high mech...High-entropy materials are mainly composed of high-entropy alloys(HEAs)and their derivates.Among them,HEAs account for a big part.As a new kind of alloy,they are now arousing great interests because of their high mechanical strength,extraordinary fracture toughness,corrosion resistance compared with traditional alloys.These characteristics allow the use of HEAs in various fields,including mechanical manufacturing,heat-resistant,radiation-resistant,corrosion-resistant,wear-resistant coatings,energy storage,heterocatalysis,etc.In order to promote the extensive application of HEAs,it is of significance to realize their rational design and preparation.In this paper,a systematic review focusing on the rational design and fabrication of nanosized HEAs is given.The design principles of how to match different elements in HEAs and the premise for the formation of single-phase solid solution HEAs are first illustrated.Computation methods for the prediction of formation conditions and properties of HEAs are also in discussion.Then,a detailed description and comparison of the synthesis methods of HEAs and their derivate,as well as their growing mechanism under various synthetic environments is provided.The commonly used characterization methods for the detection of HEAs,along with the typical cases of the application of HEAs in industrial materials,energy storage materials and catalytic materials are also included.Finally,the challenges and perspectives in the design and synthesis of HEAs would be proposed.We hope this review will give guidance for the future development of HEAs materials.展开更多
Summary of main observation and conclusion Tetracycline (TC) and other antibiotics accumulated in groundwater and soil pollute ecological environment and threaten human health. Gold nan oparticles doped on photocataly...Summary of main observation and conclusion Tetracycline (TC) and other antibiotics accumulated in groundwater and soil pollute ecological environment and threaten human health. Gold nan oparticles doped on photocatalysts are able to enhance the photodegradation efficiency during removing these antibiotics, but preparation of Au nanoparticles of well-dispersion on photocatalysts remains challenging. In this work, zeolite imidazolate (ZIF-8) was employed as the precursor to prepare Au@ZnO photocatalyst via impregnation and in-situ reduction method to efficiently degrade the tetracycline in the aqueous solution. Au nanoparticles are of 10 nm in size and uniformly dispersed on the surfaces of ZnO microstructures. The as-prepared Au@ZnO is able to remove 85.5% of TC of 0.010 mg/mL within 2h, presenting higher photocatalytic activity than pure ZnO catalyst. Most importantly, the catalyst shows its superior stability after five cycles without structure and activity changing. The mechanism of the photocatalytic degradation was discussed in detail.展开更多
With the rapid development of data-driven human interaction,advanced datastorage technologies with lower power consumption,larger storage capacity,faster switching speed,and higher integration density have become the ...With the rapid development of data-driven human interaction,advanced datastorage technologies with lower power consumption,larger storage capacity,faster switching speed,and higher integration density have become the goals of future memory electronics.Nevertheless,the physical limitations of conventional Si-based binary storage systems lag far behind the ultrahigh-density requirements of post-Moore information storage.In this regard,the pursuit of alternatives and/or supplements to the existing storage technology has come to the forefront.Recently,organic-based resistive memory materials have emerged as promising candidates for next-generation information storage applications,which provide new possibilities of realizing high-performance organic electronics.Herein,the memory device structure,switching types,mechanisms,and recent advances in organic resistive memory materials are reviewed.In particular,their potential of fulfilling multilevel storage is summarized.Besides,the present challenges and future prospects confronted by organic resistive memory materials and devices are discussed.展开更多
In this paper,poly(pyridine-imide)s,PI-Ph and PI-Naphth,were successfully synthesised and fabricated for use as memory devices.The Al/PI-Ph/indium tin oxide(ITO)device showed dynamic random access memory characteristi...In this paper,poly(pyridine-imide)s,PI-Ph and PI-Naphth,were successfully synthesised and fabricated for use as memory devices.The Al/PI-Ph/indium tin oxide(ITO)device showed dynamic random access memory characteristics,whereas Al/PI-Naphth/ITO showed rewritable(FLASH)memory characteristics.Characterisation of their UV,cyclic voltammograms,and density functional theory,were used to illustrate the different memory behaviours.The results show that the stability of electric-field-induced-charge-transfer complexes can affect memory performance.展开更多
This paper is focused on investigation of coordination polymers constructed by Cu(II)and rigid pyridyl ligands,such as 4,4'-bipyridyl-1,2,4-triazole(Hpytz)and 1,10-phenanthroline(phen)from a mononuclear precursor[...This paper is focused on investigation of coordination polymers constructed by Cu(II)and rigid pyridyl ligands,such as 4,4'-bipyridyl-1,2,4-triazole(Hpytz)and 1,10-phenanthroline(phen)from a mononuclear precursor[Cu(DMF)_(4)(NCS)_(2)](1).As expected,the complex was self-assembled with phen to form a 1D double-stranded chain of[Cu(phen)(μ-SCN)_(2)]∞(2),with Hpytz to form 1D zigzag chain of[Cu_(2)(μ-Hpytz)_(2)(NCS)_(2)(DMF)_(2)(μ-SCN)_(2)]∞(3)in which thiocyanate anion linked the Cu-μ-Hpytz-Cu chain into an infinite 2D network via weak Cu…S interaction.To treat 3 with the bridged anion dca,a novel 3D framework[Cu(μ-Hpytz)(μ-dca)(μ-SCN)]∞(4)was obtained in which Cu-μ-Hpytz-Cu chain is preserved and both thiocyanate anion and dicyanamide(dca)act as bridging ligands.In addition,complex 3 was applied as a metal catalyst in polymerization of MMA in aqueous solution at room temperature.展开更多
Adjusting the spacers between the electron-acceptor and the elector-donor is important to design organic ternary memory material but rarely reported. In this paper, two small molecules, ZIPGA and ZIPCAD with benzene r...Adjusting the spacers between the electron-acceptor and the elector-donor is important to design organic ternary memory material but rarely reported. In this paper, two small molecules, ZIPGA and ZIPCAD with benzene ring or triphenylamine as the spacers,were designed and synthesized to fabricate memory devices. The Al/ZIPGA/indium-tin oxide (ITO) device showed ternary characteristics, whereas Al/ZIPCAD/ITO had no obvious memory characteristics. Density functional theory calculation, X-ray diffraction (XRD) and atomic force microscopy (AFM) were employed to interpret the different memory properties. ZIPGA thin film has the closer intermolecular packing and flatter surface morphology than ZIPCAD film, which was favorable to the electron migration. This work demonstrates the importance of spacers and reveals that triphenylamine may be not a good spacer in design of new memory material.展开更多
The synthesis of Pt-based nanoparticles(NPs)with ultrasmall feature and tailored structure is of great importance for catalysis yet challenging.In this work,we demonstrate a facile top–down strategy for the fabricati...The synthesis of Pt-based nanoparticles(NPs)with ultrasmall feature and tailored structure is of great importance for catalysis yet challenging.In this work,we demonstrate a facile top–down strategy for the fabrication of small-sized Pt-based intermetallic compounds(IMCs)with L10 structure through the evaporation of Cd under high temperature.Impressively,such thermal treatment can be used as a versatile strategy for creating binary,ternary,quaternary,quinary,and senary L10-Pt-based IMCs.Moreover,the small-sized Pt-based IMCs display high stability against high temperature of 700℃,which can serve as active and selective catalyst for the selective hydrogenation of 4-nitrophenylacetylene.This work may not only provide a versatile top–down strategy for fabricating highly stable small-sized Pt-based NPs with L10 structure,but also promote their extensive applications in catalysis and beyond.展开更多
Ion-in-conjugation(IIC) materials are eme rging as an important class of organic electronic materials with wide applications in energy storage,resistive memories and gas sensors.Many IIC materials were designed and in...Ion-in-conjugation(IIC) materials are eme rging as an important class of organic electronic materials with wide applications in energy storage,resistive memories and gas sensors.Many IIC materials were designed and investigated,however the role of conjugation in IIC materials’ performance is yet investigated.Here we designed two molecules obtained by condensation of 4-butylaniline and oxocarbon acid.Squaric acid derivatives squaraine named SA-Bu and a croconamide named CA-Bu which only differ in their oxocarbon cores.While employing SA-Bu and CA-Bu as resistive memory and gas sensory materials,SA-Bu has attained promising performance in ternary memo ry and detection of NO_(2) as low as 10 parts-per-billion whereas CA-Bu show mainly binary memory behavior and negligible NO_(2) response.Theoretical calculations reveal that conjugation of CA-Bu was distorted by the increased steric hindrance,frustrating the charge transport and suppressing the conductivity.Our work demonstrates that the conjugation plays a crucial role in ion-in-materials promoting ternary RRAM devices and highperformance gas sensors manufacture.展开更多
Four 1,8-naphthalimide hydrazone molecules with different electron-donating groups have been applied in the study of linear and nonlinear optical(NLO)properties.These compounds showed strong green emission in solution...Four 1,8-naphthalimide hydrazone molecules with different electron-donating groups have been applied in the study of linear and nonlinear optical(NLO)properties.These compounds showed strong green emission in solution.Their NLO properties such as two-photon absorption(TPA)behavior with femtosecond laser pulses ca.800 nm and excited-state absorption(ESA)behavior with nanosecond laser pulses at 532 nm were investigated.Compound 4 presented the largest two-photon cross section(550 GM)among them due to two factors:the conjugated length of compound 4 is the longest and the electron-donating ability of compound 4 is the strongest.Different from TPA behavior,compound 2 showed the best nonlinear absorption properties at 532 nm and its nonlinear absorption coef-ficient and third-order nonlinear optical susceptibilitiesχ^(3)were up to 1.41×10^(−10) MKS and 4.65×10^(−12) esu,re-spectively.Through the modification of the structure,the nonlinear optical properties of these compounds at differ-ent wavelengths(532 and 800 nm)were well tuned.The great broad-band nonlinear optical properties indicate hy-drazones are good candidates for organic nonlinear optical absorption materials.展开更多
基金financial support provided by the National Key R&D Program of China(2017YFC0210901,2017YFC0210906)National Natural Science Foundation of China(51573122,21722607,21776190)+2 种基金Natural Science Foundation of the Jiangsu Higher Education Institutions of China(17KJA430014,17KJA150009)the Science and Technology Program for Social Development of Jiangsu(BE2015637)the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘Improving catalytic performance is a yet still challenge in thermal catalytic oxidation.Herein,uniform mesoporous MnO_(2) nanospheresupported bimetallic Pt–Pd nanoparticles were successfully fabricated via a SiO_(2) template strategy for the total catalytic degradation of volatile organic compounds at low temperature.The introduction of mesopores into the MnO_(2) support induces a large specific surface area and pore size,thus providing numerous accessible active sites and enhanced diffusion properties.Moreover,the addition of a secondary noble metal can adjust the O_(ads)/O_(latt) molar ratios,resulting in high catalytic activity.Among them,the catalyst having a Pt/Pd molar ratio of 7:3 exhibits optimized catalytic activity at a weight hourly space velocity of 36,000 mL g^(-1) h^(-1),reaching 100%toluene oxidation at 175℃ with a lower activation energy(57.0 kJ mol^(-1))than the corresponding monometallic Pt or non-Pt-based catalysts(93.8 kJ mol^(-1) and 214.2 kJ mol^(-1)).Our findings demonstrate that the uniform mesoporous MnO_(2) nanosphere-supported bimetallic Pt–Pd nanoparticles catalyst is an effective candidate for application in elimination of toluene.
基金financial support provided by the National Key R&D Program of China(2020YFC1808401)National Natural Science Foundation of China(22078213,21938006,51973148,21776190)+1 种基金cuttingedge technology basic research project of Jiangsu(BK20202012)the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘Manganese oxide(MnO_(2))exhibits excellent activity for volatile organic compound oxidation.However,it is currently unknown whether lattice oxygen or adsorbed oxygen is more conducive to the progress of the catalytic reaction.In this study,novel hollow highly dispersed Pt/Copper modified-MnO_(2)catalysts were fabricated.Cu^(2+)was stabilized into theδ-MnO_(2)cladding substituting original K+,which produced lattice defects and enhance the content of adsorbed oxygen.The 2.03 wt%Pt Cu_(0.050)-MnO_(2)catalyst exhibited the highest catalytic activity and excellent stability for toluene and benzene oxidation,with T_(100)=160℃under high space velocity(36,000 mL g^(-1)h^(-1)).The excellent performance of catalytic oxidation of VOCs is attributed to the abundant adsorbed oxygen content,excellent low-temperature reducibility and the synergistic catalytic effect between the Pt nanoparticles and Cu_(0.050)-MnO_(2).This study provides a comprehensive understanding of the Langmuir-Hinshelwood(L-H)mechanism occurring on the catalysts.
基金financial support provided by the National Key R&D Program of China(2020YFC1808401)National Natural Science Foundation of China(22078213,21938006,51973148,21776190)+1 种基金cuttingedge technology basic research project of Jiangsu(BK20202012)the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘As one of the most attractive and eco-friendly technologies,semiconductor photocatalysis is demonstrated as a potential strategy to solve global energy shortage environmental pollution problems.Regarding semiconductor-based photocatalysts,Zinc indium sulfide(ZnIn_(2)S_(4)) with various morphological structures has become research hotspots owing to its superior visible light absorption,high chemical durability and low cost.Nevertheless,the photocatalytic activity of pristine ZnIn_(2)S_(4) is unsatisfactory due to limited range of visible light absorption and fast recombination rate of light-induced electrons and holes.Different modification strategies,such as metal deposition,element doping,vacancy engineering and semiconductor combination,have been systematically developed for enhancing the photocatalytic performance of ZnIn_(2)S_(4) materials.In order to promote further developments of ZnIn_(2)S_(4) in photocatalytic applications,this mini-review summarizes the progress of recent research works for the construction of highly activity ZnIn_(2)S_(4)-based photocatalysts for the first time.In addition,the typical applications of ZnIn_(2)S_(4)-based photocatalytic materials have been critically reviewed and described such as in hydrogen evolution from photocatalytic water splitting,carbon dioxide photoreduction,and treatment of water pollution.The current challenges and further prospects for the development of ZnIn_(2)S_(4) semiconductor photocatalysts are finally pointed out.
基金the Program of Study Abroad for Young Scholar Sponsored by China Scholarship Council(CSC201800850005)Central University Basic Research Funds Project(No.2019NYB31).
文摘[Objectives]This study aimed to study and analyze the main components of the oil from seeds of 8 different pomegranate varieties.[Methods]The oil in sour and sweet pomegranate seeds was extracted by ultrasonic-assisted method,and the composition of the soil after methyl esterification was identified by GC-MS.[Results]The oil yield of the four sweet pomegranate varieties and the four sour pomegranate varieties ranged from 9.43%-16.97%.A total of 6 compounds were identified in the methyl esterified pomegranate seed oil by GC-MS.[Conclusions]There were no significant differences in oil yield between sweet and sour pomegranate varieties(P>0.05).The content of methyl punicate in the four sweet pomegranate varieties was 52.18%-78.06%,and that in the four sour pomegranate varieties was 78.25%-84.55%.The content of methyl punicate in sour pomegranate was slightly higher than that in sweet pomegranate.
基金the National Key R&D Program of China(No.2020YFC1808401)the National Natural Science Foundation of China(Nos.22078213,21938006,51973148,and 21776190)+2 种基金cutting-edge technology basic research project of Jiangsu(No.BK20202012)the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).G.P.Z.is also grateful for support from the Project funded by China Postdoctoral Science Foundation(No.2021M702389)Jiangsu Funding Program for Excellent Postdoctoral Talent(No.2022ZB536).
文摘Because of its importance in enhancing charge separation and transfer,built-in electric field engineering has been acknowledged as an effective technique for improving photocatalytic performance.Herein,a stable p–n heterojunction of 2D/2D(2D:twodimensional)Co_(3)O_(4)/ZnIn_(2)S_(4)with a strong built-in electric field is precisely constructed.The Co_(3)O_(4)/ZnIn_(2)S_(4)heterojunction exhibits a higher visible-light photocatalytic hydrogen(H2)evolution rate than the individual components,which is primarily attributed to the synergy effect of improved light absorption,abundant active sites,short charge transport distance,high separation efficiency of photogenerated carriers.Furthermore,the photoelectrochemical studies and density functional theory(DFT)calculation results demonstrate that the enhanced interfacial charge separation and migration induced by the generated built-in electric field are the critical reasons for the boosted photocatalytic performance.This research might pave the way for the rational design and manufacturing of 2D/2D heterojunction photocatalysts with extremely efficient photocatalytic performance for solar energy conversion.
基金This work is supported by the National Natural Science Foundation of China(Nos.21336005,21371128 and 21176164).
文摘4-(3-(4-(Dimethylamino)phenyl)acryloyl)phenyl-2-bromo-2-methylpropanoate(APPBr)was used for the heterogeneous atom transfer radical polymerization(ATRP)of styrene(St)with copper(I)bromide/N,N,N',N",N"-pentamethyldiethylenetriamine(PMDETA)catalytic system.The functional end group was characterized via UV-Vis and ^(1)H NMR spectra.The polymerization showed a first-order kinetic characteristic and each of the obtained polymers had well-controlled molecular weight and relatively low polydispersity index(PDI).Furthermore,the obtained end-functionalized polystyrene(PS)in solution showed strong green-light emission which is further affected by mixing different metal cations.In particular,the fluorescent intensity of the polymer was decreased in the presence of Ag^(+),Cu^(2+)and Fe^(3+).
基金the National Natural Science Foundation of China(Nos.21703149,51872193,21938006,and 5192500409)the National Key Research&Development Program of China(No.2020YFC1808401)+1 种基金Cutting-Edge Technology Basic Research Project of Jiangsu(No.BK20202012)the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).
文摘High-entropy materials are mainly composed of high-entropy alloys(HEAs)and their derivates.Among them,HEAs account for a big part.As a new kind of alloy,they are now arousing great interests because of their high mechanical strength,extraordinary fracture toughness,corrosion resistance compared with traditional alloys.These characteristics allow the use of HEAs in various fields,including mechanical manufacturing,heat-resistant,radiation-resistant,corrosion-resistant,wear-resistant coatings,energy storage,heterocatalysis,etc.In order to promote the extensive application of HEAs,it is of significance to realize their rational design and preparation.In this paper,a systematic review focusing on the rational design and fabrication of nanosized HEAs is given.The design principles of how to match different elements in HEAs and the premise for the formation of single-phase solid solution HEAs are first illustrated.Computation methods for the prediction of formation conditions and properties of HEAs are also in discussion.Then,a detailed description and comparison of the synthesis methods of HEAs and their derivate,as well as their growing mechanism under various synthetic environments is provided.The commonly used characterization methods for the detection of HEAs,along with the typical cases of the application of HEAs in industrial materials,energy storage materials and catalytic materials are also included.Finally,the challenges and perspectives in the design and synthesis of HEAs would be proposed.We hope this review will give guidance for the future development of HEAs materials.
文摘Summary of main observation and conclusion Tetracycline (TC) and other antibiotics accumulated in groundwater and soil pollute ecological environment and threaten human health. Gold nan oparticles doped on photocatalysts are able to enhance the photodegradation efficiency during removing these antibiotics, but preparation of Au nanoparticles of well-dispersion on photocatalysts remains challenging. In this work, zeolite imidazolate (ZIF-8) was employed as the precursor to prepare Au@ZnO photocatalyst via impregnation and in-situ reduction method to efficiently degrade the tetracycline in the aqueous solution. Au nanoparticles are of 10 nm in size and uniformly dispersed on the surfaces of ZnO microstructures. The as-prepared Au@ZnO is able to remove 85.5% of TC of 0.010 mg/mL within 2h, presenting higher photocatalytic activity than pure ZnO catalyst. Most importantly, the catalyst shows its superior stability after five cycles without structure and activity changing. The mechanism of the photocatalytic degradation was discussed in detail.
基金Jiangsu Key Disciplines of the Thirteenth Five-Year Plan,Grant/Award Number:20168765Six Talent Peaks Project of Jiangsu Province,Grant/Award Number:XCL-078+4 种基金NSF of Jiangsu Higher Education Institutions,Grant/Award Number:17KJA140001National Excellent Doctoral Dissertation funds of China,Grant/Award Number:201455National Natural Science Foundation of China,Grant/Award Numbers:21878199,21938006Undergraduate Innovation and Entrepreneurship Training Program of Jiangsu Province,Grant/Award Number:201910332067YNatural Science Foundation of the Jiangsu Higher。
文摘With the rapid development of data-driven human interaction,advanced datastorage technologies with lower power consumption,larger storage capacity,faster switching speed,and higher integration density have become the goals of future memory electronics.Nevertheless,the physical limitations of conventional Si-based binary storage systems lag far behind the ultrahigh-density requirements of post-Moore information storage.In this regard,the pursuit of alternatives and/or supplements to the existing storage technology has come to the forefront.Recently,organic-based resistive memory materials have emerged as promising candidates for next-generation information storage applications,which provide new possibilities of realizing high-performance organic electronics.Herein,the memory device structure,switching types,mechanisms,and recent advances in organic resistive memory materials are reviewed.In particular,their potential of fulfilling multilevel storage is summarized.Besides,the present challenges and future prospects confronted by organic resistive memory materials and devices are discussed.
基金supported by the National Natural Science Foundation of China(21336005,21371128)the major research project of Jiangsu Province Office of Education(15KJA150008)
文摘In this paper,poly(pyridine-imide)s,PI-Ph and PI-Naphth,were successfully synthesised and fabricated for use as memory devices.The Al/PI-Ph/indium tin oxide(ITO)device showed dynamic random access memory characteristics,whereas Al/PI-Naphth/ITO showed rewritable(FLASH)memory characteristics.Characterisation of their UV,cyclic voltammograms,and density functional theory,were used to illustrate the different memory behaviours.The results show that the stability of electric-field-induced-charge-transfer complexes can affect memory performance.
基金The authors appreciate financial support from Chinese Natural Science Foundation(21371128 and 21336005)the Major Project of Environmental Protection in Jiangsu Province(2013020).
文摘This paper is focused on investigation of coordination polymers constructed by Cu(II)and rigid pyridyl ligands,such as 4,4'-bipyridyl-1,2,4-triazole(Hpytz)and 1,10-phenanthroline(phen)from a mononuclear precursor[Cu(DMF)_(4)(NCS)_(2)](1).As expected,the complex was self-assembled with phen to form a 1D double-stranded chain of[Cu(phen)(μ-SCN)_(2)]∞(2),with Hpytz to form 1D zigzag chain of[Cu_(2)(μ-Hpytz)_(2)(NCS)_(2)(DMF)_(2)(μ-SCN)_(2)]∞(3)in which thiocyanate anion linked the Cu-μ-Hpytz-Cu chain into an infinite 2D network via weak Cu…S interaction.To treat 3 with the bridged anion dca,a novel 3D framework[Cu(μ-Hpytz)(μ-dca)(μ-SCN)]∞(4)was obtained in which Cu-μ-Hpytz-Cu chain is preserved and both thiocyanate anion and dicyanamide(dca)act as bridging ligands.In addition,complex 3 was applied as a metal catalyst in polymerization of MMA in aqueous solution at room temperature.
基金supported by the National Natural Science Foundation of China (21176164, 21336005)the Chinese-Singapore Joint Project (2012DFG41900)the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
文摘Adjusting the spacers between the electron-acceptor and the elector-donor is important to design organic ternary memory material but rarely reported. In this paper, two small molecules, ZIPGA and ZIPCAD with benzene ring or triphenylamine as the spacers,were designed and synthesized to fabricate memory devices. The Al/ZIPGA/indium-tin oxide (ITO) device showed ternary characteristics, whereas Al/ZIPCAD/ITO had no obvious memory characteristics. Density functional theory calculation, X-ray diffraction (XRD) and atomic force microscopy (AFM) were employed to interpret the different memory properties. ZIPGA thin film has the closer intermolecular packing and flatter surface morphology than ZIPCAD film, which was favorable to the electron migration. This work demonstrates the importance of spacers and reveals that triphenylamine may be not a good spacer in design of new memory material.
基金supports by the National Key Research and Development(R&D)Program of China(No.2020YFB1505802)the Ministry of Science and Technology of China(No.2017YFA0208200)+2 种基金the National Natural Science Foundation of China(Nos.22025108,U21A20327,22121001,and 51802206)Guangdong Provincial Natural Science Fund for Distinguished Young Scholars(No.2021B1515020081)startup supports from Xiamen University and Guangzhou Key Laboratory of Low Dimensional Materials and Energy Storage Devices(No.20195010002).
文摘The synthesis of Pt-based nanoparticles(NPs)with ultrasmall feature and tailored structure is of great importance for catalysis yet challenging.In this work,we demonstrate a facile top–down strategy for the fabrication of small-sized Pt-based intermetallic compounds(IMCs)with L10 structure through the evaporation of Cd under high temperature.Impressively,such thermal treatment can be used as a versatile strategy for creating binary,ternary,quaternary,quinary,and senary L10-Pt-based IMCs.Moreover,the small-sized Pt-based IMCs display high stability against high temperature of 700℃,which can serve as active and selective catalyst for the selective hydrogenation of 4-nitrophenylacetylene.This work may not only provide a versatile top–down strategy for fabricating highly stable small-sized Pt-based NPs with L10 structure,but also promote their extensive applications in catalysis and beyond.
基金financial support provided by the National Key R&D Program of China (Nos.2020YFC1818401,2017YFC0210906)National Natural Science Foundation of China (Nos.21978185,21938006,21776190)+2 种基金Basic Research Project of Leading Technology in Jiangsu Province (No.BK20202012)Suzhou Science and Technology Bureau Project (No.SYG201935)the project supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)。
文摘Ion-in-conjugation(IIC) materials are eme rging as an important class of organic electronic materials with wide applications in energy storage,resistive memories and gas sensors.Many IIC materials were designed and investigated,however the role of conjugation in IIC materials’ performance is yet investigated.Here we designed two molecules obtained by condensation of 4-butylaniline and oxocarbon acid.Squaric acid derivatives squaraine named SA-Bu and a croconamide named CA-Bu which only differ in their oxocarbon cores.While employing SA-Bu and CA-Bu as resistive memory and gas sensory materials,SA-Bu has attained promising performance in ternary memo ry and detection of NO_(2) as low as 10 parts-per-billion whereas CA-Bu show mainly binary memory behavior and negligible NO_(2) response.Theoretical calculations reveal that conjugation of CA-Bu was distorted by the increased steric hindrance,frustrating the charge transport and suppressing the conductivity.Our work demonstrates that the conjugation plays a crucial role in ion-in-materials promoting ternary RRAM devices and highperformance gas sensors manufacture.
基金The authors thank the National Natural Science Foundation of China(Nos.21071105,20902065 and 21176164).
文摘Four 1,8-naphthalimide hydrazone molecules with different electron-donating groups have been applied in the study of linear and nonlinear optical(NLO)properties.These compounds showed strong green emission in solution.Their NLO properties such as two-photon absorption(TPA)behavior with femtosecond laser pulses ca.800 nm and excited-state absorption(ESA)behavior with nanosecond laser pulses at 532 nm were investigated.Compound 4 presented the largest two-photon cross section(550 GM)among them due to two factors:the conjugated length of compound 4 is the longest and the electron-donating ability of compound 4 is the strongest.Different from TPA behavior,compound 2 showed the best nonlinear absorption properties at 532 nm and its nonlinear absorption coef-ficient and third-order nonlinear optical susceptibilitiesχ^(3)were up to 1.41×10^(−10) MKS and 4.65×10^(−12) esu,re-spectively.Through the modification of the structure,the nonlinear optical properties of these compounds at differ-ent wavelengths(532 and 800 nm)were well tuned.The great broad-band nonlinear optical properties indicate hy-drazones are good candidates for organic nonlinear optical absorption materials.