The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS...The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS)as the electrolyte additive is proposed to facilitate the generation of stable CEI on NCM811 cathode surface and eliminate H_(2)O and HF in the electrolyte at the same time,which boosts the cycling performance of Li||NCM811 battery up to 1000 or 500 cycles with 4.5 V cut-off voltage at 25 or 60℃.展开更多
Alkali metals(Li,Na,and K)are promising candidates for high-performance rechargeable alkali metal battery anodes due to their high theoretical specific capacity and low electrochemical potential.However,the actual app...Alkali metals(Li,Na,and K)are promising candidates for high-performance rechargeable alkali metal battery anodes due to their high theoretical specific capacity and low electrochemical potential.However,the actual application of alkali metal anodes is impeded by the challenges of alkali metals,including their high chemical reactivity,uncontrolled dendrite growth,unstable solid electrolyte interphase,and infinite volume expansion during cycling processes.Introducing carbon nanotube-based nanomaterials in alkali metal anodesis an effective solution to these issues.These nanomaterials have attracted widespread attention owing to their unique properties,such as their high specific surface area,superior electronic conductivity,and excellent mechanical stability.Considering the rapidly growing research enthusiasm for this topic in the last several years,we review recent progress on the application of carbon nanotube-based nanomaterials in stable and dendrite-free alkali metal anodes.The merits and issues of alkali metal anodes,as well as their stabilizing strategies are summarized.Furthermore,the relationships among methods of synthesis,nano-or microstructures,and electrochemical properties of carbon nanotube-based alkali metal anodes are systematically discussed.In addition,advanced characterization technologies on the reaction mechanism of carbon nanotube-based nanomaterials in alkali metal anodes are also reviewed.Finally,the challenges and prospects for future study and applications of carbon nanotube-based AMAs in high-performance alkali metal batteries are discussed.展开更多
Orthorhombic Nb_(2)O_(5)(T-Nb_(2)O_(5))is attractive for fast-charging Li-ion batteries,but it is still hard to realize rapid charge transfer kinetics for Li-ion storage.Herein,F-doped T-Nb_(2)O_(5) microflowers(F-Nb_(...Orthorhombic Nb_(2)O_(5)(T-Nb_(2)O_(5))is attractive for fast-charging Li-ion batteries,but it is still hard to realize rapid charge transfer kinetics for Li-ion storage.Herein,F-doped T-Nb_(2)O_(5) microflowers(F-Nb_(2)O_(5))are rationally synthesized through topotactic conversion.Specifically,F-Nb_(2)O_(5) are assembled by single-crystal nanoflakes with nearly 97%exposed(100)facet,which maximizes the exposure of the feasible Li^(+)transport pathways along loosely packed 4g atomic layers to the electrolytes,thus effectively enhancing the Li^(+)-intercalation performance.Besides,the band gap of F-Nb_(2)O_(5) is reduced to 2.87 eV due to the doping of F atoms,leading to enhanced electrical conductivity.The synergetic effects between tailored exposed crystal facets,F-doping,and ultrathin building blocks,speed up the Li^(+)/electron transfer kinetics and improve the pseudocapacitive properties of F-Nb_(2)O_(5).Therefore,F-Nb_(2)O_(5) exhibit superior rate capability(210.8 and 164.9 mAh g^(-1) at 1 and 10 C,respectively)and good long-term 10 C cycling performance(132.7 mAh g^(-1) after 1500 cycles).展开更多
Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Neverthel...Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.展开更多
Carbon nitrides(including CN,C2N,C3N,C3N4,C4N,and C5N)are a unique family of nitrogen-rich carbon materials with multiple beneficial properties in crystalline structures,morphologies,and electronic configurations.In t...Carbon nitrides(including CN,C2N,C3N,C3N4,C4N,and C5N)are a unique family of nitrogen-rich carbon materials with multiple beneficial properties in crystalline structures,morphologies,and electronic configurations.In this review,we provide a comprehensive review on these materials properties,theoretical advantages,the synthesis and modification strategies of different carbon nitride-based materials(CNBMs)and their application in existing and emerging rechargeable battery systems,such as lithium-ion batteries,sodium and potassium-ion batteries,lithium sulfur batteries,lithium oxygen batteries,lithium metal batteries,zinc-ion batteries,and solid-state batteries.The central theme of this review is to apply the theoretical and computational design to guide the experimental synthesis of CNBMs for energy storage,i.e.,facilitate the application of first-principle studies and density functional theory for electrode material design,synthesis,and characterization of different CNBMs for the aforementioned rechargeable batteries.At last,we conclude with the challenges,and prospects of CNBMs,and propose future perspectives and strategies for further advancement of CNBMs for rechargeable batteries.展开更多
Klebsiella pneumoniae is a facultative anaerobic gram-negative, non-motile, capsulated, gas-producing rod found widely in nature and often associated with urinary and respiratory infections in humans. Orbital cellulit...Klebsiella pneumoniae is a facultative anaerobic gram-negative, non-motile, capsulated, gas-producing rod found widely in nature and often associated with urinary and respiratory infections in humans. Orbital cellulitis with abscess formation caused by K. pneumoniae is rare. Here, we present a case of K. pneumonia-inducing orbital cellulitis with abscess formation in a patient who had undergone an orbital wall fracture prosthesis with hydroxyapatite implantation due to orbital trauma 9 years ago. The patient was treated successfully with antibiotics and surgery.展开更多
The olivine-type lithium iron phosphate(LiFePO_(4))cathode material is promising and widely used as a high-performance lithium-ion battery cathode material in commercial batteries due to its low cost,environmental fri...The olivine-type lithium iron phosphate(LiFePO_(4))cathode material is promising and widely used as a high-performance lithium-ion battery cathode material in commercial batteries due to its low cost,environmental friendliness,and high safety.At present,LiFePO_(4)/C sec-ondary batteries are widely used for electronic products,automotive power batteries,and other occasion-related applications with good thermal stability,stable cycle performance,and low room-temperature self-discharge rate.However,LiFePO_(4)-based battery applications are seriously limited when they are operated in a cold climate.This outcome is due to a considerable decrease in Li+transport capabilities within the elec-trode,particularly leading to a dramatic decrease in the electrochemical capacity and power performance of the electrolyte.Therefore,the design of low-temperature electrolytes is important for the further commercial application of LiFePO_(4) batteries.This paper reviews the key factors for the poor low-temperature performance of LiFePO_(4)-based batteries and the research progress of low-temperature electrolytes.Spe-cial attention is paid to electrolyte components,including lithium salts,cosolvents,additives,and the development of new electrolytes.The factors affecting the anode are also analyzed.Finally,according to the current research progress,some viewpoints are summarized to provide suitable modification methods and research suggestions for improving the practicability of LiFePO_(4)/C commercial batteries at low temperat-ures in the future.展开更多
High-efficiency sodium-ion batteries(SIBs) are in great demand for energy storage applications,which are dominated by the Na+storage performance of electrode materials.Here,a one-pot solvothermal method is developed t...High-efficiency sodium-ion batteries(SIBs) are in great demand for energy storage applications,which are dominated by the Na+storage performance of electrode materials.Here,a one-pot solvothermal method is developed to construct amorphous/crystalline MoO_(2)(a/c-MoO_(2)) homojunction for boosting Na+storage.Theoretical simulations signify that electrons redistribute at the homogenous interface of a/c-MoO_(2),resulting in an inbuilt driving force to easily adsorb charge carriers and promote the electron/ion transfer ability.Relying on its crystallographic superiorities,the a/c-MoO_(2)homojunction with high Na adsorbability(-1.61 eV) and low Na diffusion energy barrier(0.519 eV) achieves higher capacity(307 mA h g^(-1)at 0.1 A/g),better rate capability and cycling stability than either a-MoO_(2)or c-MoO_(2)counterpart.Combining in-situ X-ray diffraction(XRD) and ex-situ X-ray photoelectron spectroscopy(XPS)techniques,the ’adsorption-insertion-conversion’ mechanism is well established for Na+storage of MoO_(2).Our work opens new opportunities to optimize electrode materials via crystallographic engineering for efficient Na+storage,and helps to better understand the effects of homojunction structure in enhanced electrochemical performance.展开更多
Owing to the advantages of high operating voltage,environmental benignity,and low cost,potassium-based dual-ion batteries(KDIBs)have been considered as a potential candidate for large-scale energy storage.However,KDIB...Owing to the advantages of high operating voltage,environmental benignity,and low cost,potassium-based dual-ion batteries(KDIBs)have been considered as a potential candidate for large-scale energy storage.However,KDIBs generally suffer from poor cycling performance and unsatisfied capacity,and inactive components of conductive agents,binders,and current collector further lower their overall capacity.Herein,we prepare coral-like carbon nanowres(CCNWs)doped with nitrogen as a binder-free anode material for K^(+)-ion storage,in which the unique coral-like porous nanostructure and amorphous/short-range-ordered composite feature are conducive to enhancing the structural stability,to facilitating the ion transfer and to boosting the full utilization of active sites during potassiation/de-potassiation process.As a result,the CCNW anode possesses a hybrid K^(+)-storage mechanism of diffusive behavior and capacitive adsorption,and stably delivers a high capacity of 276 mAh g^(-1)at 50 mA g^(-1),good rate capability up to 2 A g^(-1),and long-term cycling stability with 93%capacity retention after 2000 cycles at 1 A g^(-1).Further,assembling this CCNW anode with an environmentally benign expanded graphite(EG)cathode yields a proof-of-concept KDIB,which shows a high specific capacity of 134.4 mAh g^(-1)at 100 mA g^(-1),excellent rate capability of 106.5 mAh g^(-1)at 1 A g^(-1),and long-term cycling stability over 1000 cycles with negligible capacity loss.This study provides a feasible approach to developing high-performance anodes for potassium-based energy storage devices.展开更多
Research on two-dimensional(2D) materials has been explosively increasing in last seventeen years in varying subjects including condensed matter physics, electronic engineering, materials science, and chemistry since ...Research on two-dimensional(2D) materials has been explosively increasing in last seventeen years in varying subjects including condensed matter physics, electronic engineering, materials science, and chemistry since the mechanical exfoliation of graphene in 2004. Starting from graphene, 2D materials now have become a big family with numerous members and diverse categories. The unique structural features and physicochemical properties of 2D materials make them one class of the most appealing candidates for a wide range of potential applications. In particular, we have seen some major breakthroughs made in the field of 2D materials in last five years not only in developing novel synthetic methods and exploring new structures/properties but also in identifying innovative applications and pushing forward commercialisation. In this review, we provide a critical summary on the recent progress made in the field of 2D materials with a particular focus on last five years. After a brief backgroundintroduction, we first discuss the major synthetic methods for 2D materials, including the mechanical exfoliation, liquid exfoliation, vapor phase deposition, and wet-chemical synthesis as well as phase engineering of 2D materials belonging to the field of phase engineering of nanomaterials(PEN). We then introduce the superconducting/optical/magnetic properties and chirality of 2D materials along with newly emerging magic angle 2D superlattices. Following that, the promising applications of 2D materials in electronics, optoelectronics, catalysis, energy storage, solar cells, biomedicine, sensors, environments, etc. are described sequentially. Thereafter, we present the theoretic calculations and simulations of 2D materials. Finally, after concluding the current progress, we provide some personal discussions on the existing challenges and future outlooks in this rapidly developing field.展开更多
Molybdenum and tungsten chalcogenides have attracted tremendous attention in energy storage and conversion due to their outstanding physicochemical and electrochemical properties.There are intensive studies on molybde...Molybdenum and tungsten chalcogenides have attracted tremendous attention in energy storage and conversion due to their outstanding physicochemical and electrochemical properties.There are intensive studies on molybdenum and tungsten chalcogenides for energy storage and conversion,however,there is no systematic review on the applications of WS2,Mo Se2and WSe2as anode materials for lithium-ion batteries(LIBs)and sodium-ion batteries(SIBs),except Mo S2.Considering the importance of these contents,it is extremely necessary to overview the recent development of novel layered WS2,Mo Se2and WSe2beyond Mo S2in energy storage.Here,we will systematically overview the recent progress of WS2,Mo Se2and WSe2as anode materials in LIBs and SIBs.This review will also discuss the opportunities,and perspectives of these materials in the energy storage fields.展开更多
Two-dimensional (2D) layered vanadium disulfide (VS2) is a promising anode material for lithium ion batteries (LIBs) due to the high theoretical capacity.However,it remains a challenge to synthesize monodispersed ultr...Two-dimensional (2D) layered vanadium disulfide (VS2) is a promising anode material for lithium ion batteries (LIBs) due to the high theoretical capacity.However,it remains a challenge to synthesize monodispersed ultrathin VS2 nanosheets to realize the full potential.Herein,a novel solvothermal method has been developed to prepare the monodispersed bowl-shaped NH3-inserted VS2 nanosheets (VS2).The formation of such a unique structure is caused by the blocked growth of (001) or (002) crystal planes in combination with a ripening process driven by the thermodynamics.The annealing treatment in Ar/H2creates porous monodispersed VS2(H-VS2),which is subsequently integrated with graphene oxide to form porous monodispersed H-VS2/rGO composite coupled with a reduction process.As an anode material for LIBs,H-VS2/rGO delivers superior rate performance and longer cycle stability:a high average capacity of 868/525 mAh g^-1 at a current density of 1/10 A g^-1;a reversible capacity of 1177/889 mAh g^-1 after 150/500 cycles at 0.2/1 A g^-1.Such excellent electrochemical performance may be attributed to the increased active sites available for lithium storage,the alleviated volume variations and the shortened Li-ion diffusion induced from the porous structure with large specific surface area,as well as the protective effect from graphene nanosheets.展开更多
It is urgent to solve the problems of the dramatic volume expansion and pulverization of SnO_2 anodes during cycling process in battery systems. To address this issue, we design a hybrid structure of N-doped carbon fi...It is urgent to solve the problems of the dramatic volume expansion and pulverization of SnO_2 anodes during cycling process in battery systems. To address this issue, we design a hybrid structure of N-doped carbon fibers@SnO_2 nanoflowers(NC@SnO_2) to overcome it in this work. The hybrid NC@SnO_2 is synthesized through the hydrothermal growth of SnO_2 nanoflowers on the surface of N-doped carbon fibers obtained by electrospinning. The NC is introduced not only to provide a support framework in guiding the growth of the SnO_2 nanoflowers and prevent the flower-like structures from agglomeration, but also serve as a conductive network to accelerate electronic transmission along one-dimensional structure effectively. When the hybrid NC@SnO_2 was served as anode, it exhibits a high discharge capacity of 750 Ah g^(-1) at 1 A g^(-1) after 100 cycles in Li-ion battery and 270 mAh g^(-1) at 100 mA g^(-1) for 100 cycles in Na-ion battery, respectively.展开更多
One-dimensional nano-structured materials have attracted attention due to its unique properties afforded such as the across-linked structures and large aspect ratios.In this work,one-dimensional CoSe@N-doped carbon na...One-dimensional nano-structured materials have attracted attention due to its unique properties afforded such as the across-linked structures and large aspect ratios.In this work,one-dimensional CoSe@N-doped carbon nanofibers(CoSe@NCNFs)are successfully by combining the techniques of electrospinning and annealing.Selenium powder are directly dispersed in the polyacrylonitrile/N,N-Dimethylformamide(DMF)solution containing cobalt salt to form the product.The performance of these materials was investigated in Li-ion batteries after the annealing at different temperatures.The Co Se@NC nanofibers annealed at 550℃(CoSe@NC-550)and displayed excellent storage properties,affording a high capacity of 796 m Ah·g-1at a current density of 1 A·g^-1 for 100 cycles.Moreover,it is confirmed that the pseudocapacitive contribution of CoSe@NC-550 is up to 72.8%at the scan rate of 1 mV/s through the cyclic voltammetry analysis.展开更多
Several emerging energy storage technologies and systems have been demonstrated that feature low cost,high rate capability,and durability for potential use in large-scale grid and high-power applications.Owing to its ...Several emerging energy storage technologies and systems have been demonstrated that feature low cost,high rate capability,and durability for potential use in large-scale grid and high-power applications.Owing to its outstanding ion conductivity,ultrafast Na-ion insertion kinetics,excellent structural stability,and large theoretical capacity,the sodium superionic conductor(NASICON)-structured insertion material NaTi2(PO4)3(NTP)has attracted considerable attention as the optimal electrode material for sodium-ion batteries(SIBs)and Na-ion hybrid capacitors(NHCs).On the basis of recent studies,NaTi2(PO4)3 has raised the rate capabilities,cycling stability,and mass loading of rechargeable SIBs and NHCs to commercially acceptable levels.In this comprehensive review,starting with the structures and electrochemical properties of NTP,we present recent progress in the application of NTP to SIBs,including non-aqueous batteries,aqueous batteries,aqueous batteries with desalination,and sodium-ion hybrid capacitors.After a thorough discussion of the unique NASICON structure of NTP,various strategies for improving the performance of NTP electrode have been presented and summarized in detail.Further,the major challenges and perspectives regarding the prospects for the use of NTP-based electrodes in energy storage systems have also been summarized to offer a guideline for further improving the performance of NTP-based electrodes.展开更多
Defect engineering has been used to develop low-cost and effective catalysts to boost oxygen reduction reactions.However,the development of catalysts that use metal cation vacancies as the active sites for oxygen redu...Defect engineering has been used to develop low-cost and effective catalysts to boost oxygen reduction reactions.However,the development of catalysts that use metal cation vacancies as the active sites for oxygen reduction reaction is lacking.In this study,ZnS nanoparticles on N-doped carbon serve as an oxygen reduction reaction catalyst.These catalysts were prepared via a one-step method at 900℃.Amazingly,the high-resolution transmission electron microscope image revealed obvious defects in the ZnS nanoparticles.These facilitated the catalyst synthesis,and the product displayed good electrocatalytic performance for the oxygen reduction reaction in an alkaline medium,including a lower onset potential,lower mid-wave potential,four electron transfer process,and better durability compared with 20 wt%Pt/C.More importantly,the density functional theory results indicated that using the Zn vacancies in the prepared catalyst as active sites required a lower reaction energy to produce OOH*from*OO toward oxygen reduction reaction.Therefore,the proposed catalyst with Zn vacancies can be used as a potential electrocatalyst and may be substitutes for Pt-based catalysts in fuel cells,given the novel catalyst’s resulting performance.展开更多
Designing providential catalyst is the key to drive the electrochemical nitrogen reduction reactions(NRR),which is referring to multiple intermediates and products. By means of density functional theory(DFT)calculatio...Designing providential catalyst is the key to drive the electrochemical nitrogen reduction reactions(NRR),which is referring to multiple intermediates and products. By means of density functional theory(DFT)calculations, we studied heteronuclear bi-atom electrocatalyst(HBEC) for NRR. Our results revealed that compared to homonuclear bi-atom electrocatalyst(Fe_2@C_2N, V_2@C_2N), Fe, V-co-doped C_2N(Fe V@C_2N)had a smaller limiting potential of-0.17 V and could accelerate N_2-to-NH_3 conversion through the enzymatic pathway of NRR. Importantly, N–N bond length monotonically increases with increasing the Bader charges of adsorbed N_2 molecule but decreases with increasing the Bader charge difference of two adsorbed N atoms. Additionally, the Fe V@C_2N could suppress the production of H_2 by the preferential adsorption and reduction of N_2 molecule. Thus, the as-designed HBEC may have the outstanding electrochemical NRR performance. This work opens a new perspective for NRR by HBECs under mild conditions.展开更多
Nitrogen fixation is one of the most important and challenging process in production of ammonia at ambient temperature. We have first performed density function theory to propose the edge of Janus MoSSe(EJM) monolayer...Nitrogen fixation is one of the most important and challenging process in production of ammonia at ambient temperature. We have first performed density function theory to propose the edge of Janus MoSSe(EJM) monolayer as a potential catalyst for nitrogen reduction reaction. Our results show that the superficial D-band centers play an important role in nitrogen fixation. The strain effects greatly alter the D-band center, and further change the interaction between the adsorbates and the surface of catalysts.Our findings provide a new thought into designing transition-metal chalcogenide catalysts for nitrogen fixation.展开更多
Crystal planes of a catalyst play crucial role in determining the electrocatalytic performance for CO2 reduction.The catalyst SnO2 can convert CO2 molecules into valuable formic acid(HCOOH).Incorporating heteroatom N ...Crystal planes of a catalyst play crucial role in determining the electrocatalytic performance for CO2 reduction.The catalyst SnO2 can convert CO2 molecules into valuable formic acid(HCOOH).Incorporating heteroatom N into SnO2 further improves its catalytic activity.To understand the mechanism and realize a highly efficient CO2-to-HCOOH conversion,we used density functional theory(DFT)to calculate the free energy of CO2 reduction reactions(CO2RR)on different crystal planes of N-doped SnO2(N-SnO2).The results indicate that N-SnO2 lowered the activation energy of intermediates leading to a better catalytic performance than pure SnO2.We also discovered that the N-Sn O2 (211)plane possesses the most suitable free energy during the reduction process,exhibiting the best catalytic ability for the CO2-to-HCOOH conversion.The intermediate of CO2RR on N-SnO2 is HCOO*or COOH* instead of OCHO*.These results may provide useful insights into the mechanism of CO2RR,and promote the development of heteroatomdoped catalyst for efficient CO2RR.展开更多
Increasing the energy density, power density as well as widening the operation voltage are essential to electrochemical capacitors to meet the practical energy demands. Herein, a novel flexible quasi-solid-state dual-...Increasing the energy density, power density as well as widening the operation voltage are essential to electrochemical capacitors to meet the practical energy demands. Herein, a novel flexible quasi-solid-state dual-ion asymmetric supercapacitor(ASC) with Ni(OH)2 and Nb2O5 nanosheets directly grown on stainless steel mesh is developed. In the dual-ion ASC, Nb2O5 negative and Ni(OH)2 positive electrodes react with Li+ and OH- respectively in alkaline gel electrolyte to store energy, which is quite different from conventional alkali metal ion SCs and alkaline SCs. The as-assembled flexible device has an extended working voltage of 1.7 V and delivers a capacity of 5.37 mAh cm-2, a maximum energy density and power density of 0.52 mWh cm-3 and 170 mW cm-3 , respectively. The device maintains around 60% capacity retention after long cycling up to 1000 cycles. Moreover, our device can light up a LED light efficiently upon fast charging. The proposed quasi-solid-state dual-ion ASC has potential applications in future portable electronics and flexible energy storage devices.展开更多
基金the support from the National Natural Science Foundation of China(Grant No.51971090 and U21A20311)。
文摘The construction of stable cathode electrolyte interphase(CEI)is the key to improve the NCM811 particle structure and interfacial stability via electrolyte engineering.In He’s work,lithium hexamethyldisilazide(LiHMDS)as the electrolyte additive is proposed to facilitate the generation of stable CEI on NCM811 cathode surface and eliminate H_(2)O and HF in the electrolyte at the same time,which boosts the cycling performance of Li||NCM811 battery up to 1000 or 500 cycles with 4.5 V cut-off voltage at 25 or 60℃.
基金supported by the National Key Research and Development Program of China(2020YFB1713500)the Chinese 02 Special Fund(2017ZX02408003)+1 种基金Open Fund of State Key Laboratory of Advanced Refractories(SKLAR202210)the Foundation of Department of Science and Technology of Henan Province(212102210219).
文摘Alkali metals(Li,Na,and K)are promising candidates for high-performance rechargeable alkali metal battery anodes due to their high theoretical specific capacity and low electrochemical potential.However,the actual application of alkali metal anodes is impeded by the challenges of alkali metals,including their high chemical reactivity,uncontrolled dendrite growth,unstable solid electrolyte interphase,and infinite volume expansion during cycling processes.Introducing carbon nanotube-based nanomaterials in alkali metal anodesis an effective solution to these issues.These nanomaterials have attracted widespread attention owing to their unique properties,such as their high specific surface area,superior electronic conductivity,and excellent mechanical stability.Considering the rapidly growing research enthusiasm for this topic in the last several years,we review recent progress on the application of carbon nanotube-based nanomaterials in stable and dendrite-free alkali metal anodes.The merits and issues of alkali metal anodes,as well as their stabilizing strategies are summarized.Furthermore,the relationships among methods of synthesis,nano-or microstructures,and electrochemical properties of carbon nanotube-based alkali metal anodes are systematically discussed.In addition,advanced characterization technologies on the reaction mechanism of carbon nanotube-based nanomaterials in alkali metal anodes are also reviewed.Finally,the challenges and prospects for future study and applications of carbon nanotube-based AMAs in high-performance alkali metal batteries are discussed.
基金supported by the National Natural Science Foundation of China(No.51802163)the Natural Science Foundation of Henan Province of China(No.222300420252)the Natural Science Foundation of Henan Department of Education(No.20A480004).
文摘Orthorhombic Nb_(2)O_(5)(T-Nb_(2)O_(5))is attractive for fast-charging Li-ion batteries,but it is still hard to realize rapid charge transfer kinetics for Li-ion storage.Herein,F-doped T-Nb_(2)O_(5) microflowers(F-Nb_(2)O_(5))are rationally synthesized through topotactic conversion.Specifically,F-Nb_(2)O_(5) are assembled by single-crystal nanoflakes with nearly 97%exposed(100)facet,which maximizes the exposure of the feasible Li^(+)transport pathways along loosely packed 4g atomic layers to the electrolytes,thus effectively enhancing the Li^(+)-intercalation performance.Besides,the band gap of F-Nb_(2)O_(5) is reduced to 2.87 eV due to the doping of F atoms,leading to enhanced electrical conductivity.The synergetic effects between tailored exposed crystal facets,F-doping,and ultrathin building blocks,speed up the Li^(+)/electron transfer kinetics and improve the pseudocapacitive properties of F-Nb_(2)O_(5).Therefore,F-Nb_(2)O_(5) exhibit superior rate capability(210.8 and 164.9 mAh g^(-1) at 1 and 10 C,respectively)and good long-term 10 C cycling performance(132.7 mAh g^(-1) after 1500 cycles).
基金supported by the National Key Research and Development Program of China(2020YFB1713500)the Chinese 02 Special Fund(2017ZX02408003)+2 种基金the Open Fund of National Joint Engineering Research Center for abrasion control and molding of metal materials(HKDNM201807)the Student Research Training Plan of Henan University of Science and Technology(2020026)the National Undergraduate Innovation and Entrepreneurship Training Program(202010464031,202110464005)。
文摘Rechargeable aqueous Zn-ion batteries(AZIBs)are one of the most promising energy storage devices for large-scale energy storage owing to their high specific capacity,eco-friendliness,low cost and high safety.Nevertheless,zinc metal anodes suffer from severe dendrite growth and side reactions,resulting in the inferior electrochemical performance of AZIBs.To address these problems,surface modification of zinc metal anodes is a facile and effective method to regulate the interaction between the zinc anode and an electrolyte.In this review,the current challenges and strategies for zinc metal anodes are presented.Furthermore,recent advances in surface modification strategies to improve their electrochemical performance are concluded and discussed.Finally,challenges and prospects for future development of zinc metal anodes are proposed.We hope this review will be useful for designing and fabricating highperformance AZIBs and boosting their practical applications.
基金the Australia Research Council Discovery Projects(DP160102627 and DP1701048343)of AustraliaShenzhen Peacock Plan of China(KQTD2016112915051055)the 111 Project(D20015)of China Three Gorges University.
文摘Carbon nitrides(including CN,C2N,C3N,C3N4,C4N,and C5N)are a unique family of nitrogen-rich carbon materials with multiple beneficial properties in crystalline structures,morphologies,and electronic configurations.In this review,we provide a comprehensive review on these materials properties,theoretical advantages,the synthesis and modification strategies of different carbon nitride-based materials(CNBMs)and their application in existing and emerging rechargeable battery systems,such as lithium-ion batteries,sodium and potassium-ion batteries,lithium sulfur batteries,lithium oxygen batteries,lithium metal batteries,zinc-ion batteries,and solid-state batteries.The central theme of this review is to apply the theoretical and computational design to guide the experimental synthesis of CNBMs for energy storage,i.e.,facilitate the application of first-principle studies and density functional theory for electrode material design,synthesis,and characterization of different CNBMs for the aforementioned rechargeable batteries.At last,we conclude with the challenges,and prospects of CNBMs,and propose future perspectives and strategies for further advancement of CNBMs for rechargeable batteries.
文摘Klebsiella pneumoniae is a facultative anaerobic gram-negative, non-motile, capsulated, gas-producing rod found widely in nature and often associated with urinary and respiratory infections in humans. Orbital cellulitis with abscess formation caused by K. pneumoniae is rare. Here, we present a case of K. pneumonia-inducing orbital cellulitis with abscess formation in a patient who had undergone an orbital wall fracture prosthesis with hydroxyapatite implantation due to orbital trauma 9 years ago. The patient was treated successfully with antibiotics and surgery.
基金supported by the National Natural Science Foundation of China (No. 52102470)Guangxi Innovation Driven Development Project (No. AA17204100)
文摘The olivine-type lithium iron phosphate(LiFePO_(4))cathode material is promising and widely used as a high-performance lithium-ion battery cathode material in commercial batteries due to its low cost,environmental friendliness,and high safety.At present,LiFePO_(4)/C sec-ondary batteries are widely used for electronic products,automotive power batteries,and other occasion-related applications with good thermal stability,stable cycle performance,and low room-temperature self-discharge rate.However,LiFePO_(4)-based battery applications are seriously limited when they are operated in a cold climate.This outcome is due to a considerable decrease in Li+transport capabilities within the elec-trode,particularly leading to a dramatic decrease in the electrochemical capacity and power performance of the electrolyte.Therefore,the design of low-temperature electrolytes is important for the further commercial application of LiFePO_(4) batteries.This paper reviews the key factors for the poor low-temperature performance of LiFePO_(4)-based batteries and the research progress of low-temperature electrolytes.Spe-cial attention is paid to electrolyte components,including lithium salts,cosolvents,additives,and the development of new electrolytes.The factors affecting the anode are also analyzed.Finally,according to the current research progress,some viewpoints are summarized to provide suitable modification methods and research suggestions for improving the practicability of LiFePO_(4)/C commercial batteries at low temperat-ures in the future.
基金Financial support by National Natural Science Foundation of China(21706103 and U21A20311)Natural Science Foundation of Jiangsu Province(BK20170549)China Postdoctoral Science Foundation(2022M711381)。
文摘High-efficiency sodium-ion batteries(SIBs) are in great demand for energy storage applications,which are dominated by the Na+storage performance of electrode materials.Here,a one-pot solvothermal method is developed to construct amorphous/crystalline MoO_(2)(a/c-MoO_(2)) homojunction for boosting Na+storage.Theoretical simulations signify that electrons redistribute at the homogenous interface of a/c-MoO_(2),resulting in an inbuilt driving force to easily adsorb charge carriers and promote the electron/ion transfer ability.Relying on its crystallographic superiorities,the a/c-MoO_(2)homojunction with high Na adsorbability(-1.61 eV) and low Na diffusion energy barrier(0.519 eV) achieves higher capacity(307 mA h g^(-1)at 0.1 A/g),better rate capability and cycling stability than either a-MoO_(2)or c-MoO_(2)counterpart.Combining in-situ X-ray diffraction(XRD) and ex-situ X-ray photoelectron spectroscopy(XPS)techniques,the ’adsorption-insertion-conversion’ mechanism is well established for Na+storage of MoO_(2).Our work opens new opportunities to optimize electrode materials via crystallographic engineering for efficient Na+storage,and helps to better understand the effects of homojunction structure in enhanced electrochemical performance.
基金supported by the Key-Area Research and Development Program of Guangdong Province(2019B090914003)National Natural Science Foundation of China(11904379,51972329,51822210,52061160484)+2 种基金Shenzhen Science and Technology Planning Project(JCYJ20190807171803813,JCYJ2020010911562492,KQTD20161129150510559)China Postdoctoral Science Foundation(2018M643235)Guangdong Basic and Applied Basic Research Foundation(2019A1515011902,2019TX05L389)。
文摘Owing to the advantages of high operating voltage,environmental benignity,and low cost,potassium-based dual-ion batteries(KDIBs)have been considered as a potential candidate for large-scale energy storage.However,KDIBs generally suffer from poor cycling performance and unsatisfied capacity,and inactive components of conductive agents,binders,and current collector further lower their overall capacity.Herein,we prepare coral-like carbon nanowres(CCNWs)doped with nitrogen as a binder-free anode material for K^(+)-ion storage,in which the unique coral-like porous nanostructure and amorphous/short-range-ordered composite feature are conducive to enhancing the structural stability,to facilitating the ion transfer and to boosting the full utilization of active sites during potassiation/de-potassiation process.As a result,the CCNW anode possesses a hybrid K^(+)-storage mechanism of diffusive behavior and capacitive adsorption,and stably delivers a high capacity of 276 mAh g^(-1)at 50 mA g^(-1),good rate capability up to 2 A g^(-1),and long-term cycling stability with 93%capacity retention after 2000 cycles at 1 A g^(-1).Further,assembling this CCNW anode with an environmentally benign expanded graphite(EG)cathode yields a proof-of-concept KDIB,which shows a high specific capacity of 134.4 mAh g^(-1)at 100 mA g^(-1),excellent rate capability of 106.5 mAh g^(-1)at 1 A g^(-1),and long-term cycling stability over 1000 cycles with negligible capacity loss.This study provides a feasible approach to developing high-performance anodes for potassium-based energy storage devices.
文摘Research on two-dimensional(2D) materials has been explosively increasing in last seventeen years in varying subjects including condensed matter physics, electronic engineering, materials science, and chemistry since the mechanical exfoliation of graphene in 2004. Starting from graphene, 2D materials now have become a big family with numerous members and diverse categories. The unique structural features and physicochemical properties of 2D materials make them one class of the most appealing candidates for a wide range of potential applications. In particular, we have seen some major breakthroughs made in the field of 2D materials in last five years not only in developing novel synthetic methods and exploring new structures/properties but also in identifying innovative applications and pushing forward commercialisation. In this review, we provide a critical summary on the recent progress made in the field of 2D materials with a particular focus on last five years. After a brief backgroundintroduction, we first discuss the major synthetic methods for 2D materials, including the mechanical exfoliation, liquid exfoliation, vapor phase deposition, and wet-chemical synthesis as well as phase engineering of 2D materials belonging to the field of phase engineering of nanomaterials(PEN). We then introduce the superconducting/optical/magnetic properties and chirality of 2D materials along with newly emerging magic angle 2D superlattices. Following that, the promising applications of 2D materials in electronics, optoelectronics, catalysis, energy storage, solar cells, biomedicine, sensors, environments, etc. are described sequentially. Thereafter, we present the theoretic calculations and simulations of 2D materials. Finally, after concluding the current progress, we provide some personal discussions on the existing challenges and future outlooks in this rapidly developing field.
基金supported by the National Natural Science Foundation of China (Grant No. 51302079)the Natural Science Foundation of Hunan Province (Grant No. 2017JJ1008)
文摘Molybdenum and tungsten chalcogenides have attracted tremendous attention in energy storage and conversion due to their outstanding physicochemical and electrochemical properties.There are intensive studies on molybdenum and tungsten chalcogenides for energy storage and conversion,however,there is no systematic review on the applications of WS2,Mo Se2and WSe2as anode materials for lithium-ion batteries(LIBs)and sodium-ion batteries(SIBs),except Mo S2.Considering the importance of these contents,it is extremely necessary to overview the recent development of novel layered WS2,Mo Se2and WSe2beyond Mo S2in energy storage.Here,we will systematically overview the recent progress of WS2,Mo Se2and WSe2as anode materials in LIBs and SIBs.This review will also discuss the opportunities,and perspectives of these materials in the energy storage fields.
基金the Natural Science Foundation of Hunan Province(Grant no.2017JJ1008)the Key Research and Development Program of Hunan Province of China under Grant 2018GK2031。
文摘Two-dimensional (2D) layered vanadium disulfide (VS2) is a promising anode material for lithium ion batteries (LIBs) due to the high theoretical capacity.However,it remains a challenge to synthesize monodispersed ultrathin VS2 nanosheets to realize the full potential.Herein,a novel solvothermal method has been developed to prepare the monodispersed bowl-shaped NH3-inserted VS2 nanosheets (VS2).The formation of such a unique structure is caused by the blocked growth of (001) or (002) crystal planes in combination with a ripening process driven by the thermodynamics.The annealing treatment in Ar/H2creates porous monodispersed VS2(H-VS2),which is subsequently integrated with graphene oxide to form porous monodispersed H-VS2/rGO composite coupled with a reduction process.As an anode material for LIBs,H-VS2/rGO delivers superior rate performance and longer cycle stability:a high average capacity of 868/525 mAh g^-1 at a current density of 1/10 A g^-1;a reversible capacity of 1177/889 mAh g^-1 after 150/500 cycles at 0.2/1 A g^-1.Such excellent electrochemical performance may be attributed to the increased active sites available for lithium storage,the alleviated volume variations and the shortened Li-ion diffusion induced from the porous structure with large specific surface area,as well as the protective effect from graphene nanosheets.
基金supported by the National Natural Science Foundation of China (Grant No. 51302079)the National Natural Science Foundation of Hunan Province (Grant No. 2017JJ1008)
文摘It is urgent to solve the problems of the dramatic volume expansion and pulverization of SnO_2 anodes during cycling process in battery systems. To address this issue, we design a hybrid structure of N-doped carbon fibers@SnO_2 nanoflowers(NC@SnO_2) to overcome it in this work. The hybrid NC@SnO_2 is synthesized through the hydrothermal growth of SnO_2 nanoflowers on the surface of N-doped carbon fibers obtained by electrospinning. The NC is introduced not only to provide a support framework in guiding the growth of the SnO_2 nanoflowers and prevent the flower-like structures from agglomeration, but also serve as a conductive network to accelerate electronic transmission along one-dimensional structure effectively. When the hybrid NC@SnO_2 was served as anode, it exhibits a high discharge capacity of 750 Ah g^(-1) at 1 A g^(-1) after 100 cycles in Li-ion battery and 270 mAh g^(-1) at 100 mA g^(-1) for 100 cycles in Na-ion battery, respectively.
基金supported by the National Natural Science Foundation of China (Grant No. 51302079)the Natural Science Foundation of Hunan Province (Grant No. 2017JJ1008)
文摘One-dimensional nano-structured materials have attracted attention due to its unique properties afforded such as the across-linked structures and large aspect ratios.In this work,one-dimensional CoSe@N-doped carbon nanofibers(CoSe@NCNFs)are successfully by combining the techniques of electrospinning and annealing.Selenium powder are directly dispersed in the polyacrylonitrile/N,N-Dimethylformamide(DMF)solution containing cobalt salt to form the product.The performance of these materials was investigated in Li-ion batteries after the annealing at different temperatures.The Co Se@NC nanofibers annealed at 550℃(CoSe@NC-550)and displayed excellent storage properties,affording a high capacity of 796 m Ah·g-1at a current density of 1 A·g^-1 for 100 cycles.Moreover,it is confirmed that the pseudocapacitive contribution of CoSe@NC-550 is up to 72.8%at the scan rate of 1 mV/s through the cyclic voltammetry analysis.
基金supported by the National Natural Science Foundation of China (No. 51302079)the Natural Science Foundation of Hunan Province (No. 2017JJ1008)the Key Research and Development Program of Hunan Province of China under Grant 2018GK2031
文摘Several emerging energy storage technologies and systems have been demonstrated that feature low cost,high rate capability,and durability for potential use in large-scale grid and high-power applications.Owing to its outstanding ion conductivity,ultrafast Na-ion insertion kinetics,excellent structural stability,and large theoretical capacity,the sodium superionic conductor(NASICON)-structured insertion material NaTi2(PO4)3(NTP)has attracted considerable attention as the optimal electrode material for sodium-ion batteries(SIBs)and Na-ion hybrid capacitors(NHCs).On the basis of recent studies,NaTi2(PO4)3 has raised the rate capabilities,cycling stability,and mass loading of rechargeable SIBs and NHCs to commercially acceptable levels.In this comprehensive review,starting with the structures and electrochemical properties of NTP,we present recent progress in the application of NTP to SIBs,including non-aqueous batteries,aqueous batteries,aqueous batteries with desalination,and sodium-ion hybrid capacitors.After a thorough discussion of the unique NASICON structure of NTP,various strategies for improving the performance of NTP electrode have been presented and summarized in detail.Further,the major challenges and perspectives regarding the prospects for the use of NTP-based electrodes in energy storage systems have also been summarized to offer a guideline for further improving the performance of NTP-based electrodes.
基金supported by the National Natural Science Foundation of China(21865025)the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT_15R46)
文摘Defect engineering has been used to develop low-cost and effective catalysts to boost oxygen reduction reactions.However,the development of catalysts that use metal cation vacancies as the active sites for oxygen reduction reaction is lacking.In this study,ZnS nanoparticles on N-doped carbon serve as an oxygen reduction reaction catalyst.These catalysts were prepared via a one-step method at 900℃.Amazingly,the high-resolution transmission electron microscope image revealed obvious defects in the ZnS nanoparticles.These facilitated the catalyst synthesis,and the product displayed good electrocatalytic performance for the oxygen reduction reaction in an alkaline medium,including a lower onset potential,lower mid-wave potential,four electron transfer process,and better durability compared with 20 wt%Pt/C.More importantly,the density functional theory results indicated that using the Zn vacancies in the prepared catalyst as active sites required a lower reaction energy to produce OOH*from*OO toward oxygen reduction reaction.Therefore,the proposed catalyst with Zn vacancies can be used as a potential electrocatalyst and may be substitutes for Pt-based catalysts in fuel cells,given the novel catalyst’s resulting performance.
基金supported by the National Natural Science Foundation of China (Grant no. 51302079)the National Natural Science Foundation of Hunan Province (Grant no. 2017JJ1008)。
文摘Designing providential catalyst is the key to drive the electrochemical nitrogen reduction reactions(NRR),which is referring to multiple intermediates and products. By means of density functional theory(DFT)calculations, we studied heteronuclear bi-atom electrocatalyst(HBEC) for NRR. Our results revealed that compared to homonuclear bi-atom electrocatalyst(Fe_2@C_2N, V_2@C_2N), Fe, V-co-doped C_2N(Fe V@C_2N)had a smaller limiting potential of-0.17 V and could accelerate N_2-to-NH_3 conversion through the enzymatic pathway of NRR. Importantly, N–N bond length monotonically increases with increasing the Bader charges of adsorbed N_2 molecule but decreases with increasing the Bader charge difference of two adsorbed N atoms. Additionally, the Fe V@C_2N could suppress the production of H_2 by the preferential adsorption and reduction of N_2 molecule. Thus, the as-designed HBEC may have the outstanding electrochemical NRR performance. This work opens a new perspective for NRR by HBECs under mild conditions.
基金supported by the National Natural Science Foundation of China (Grant no. 51302079 and 11675051)the Natural Science Foundation of Hunan Province (Grant no. 2017JJ1008)
文摘Nitrogen fixation is one of the most important and challenging process in production of ammonia at ambient temperature. We have first performed density function theory to propose the edge of Janus MoSSe(EJM) monolayer as a potential catalyst for nitrogen reduction reaction. Our results show that the superficial D-band centers play an important role in nitrogen fixation. The strain effects greatly alter the D-band center, and further change the interaction between the adsorbates and the surface of catalysts.Our findings provide a new thought into designing transition-metal chalcogenide catalysts for nitrogen fixation.
基金supported by the National Natural Science Foundation of China (51302079)the Natural Science Foundation of Hunan Province (Grant No. 2017JJ1008)
文摘Crystal planes of a catalyst play crucial role in determining the electrocatalytic performance for CO2 reduction.The catalyst SnO2 can convert CO2 molecules into valuable formic acid(HCOOH).Incorporating heteroatom N into SnO2 further improves its catalytic activity.To understand the mechanism and realize a highly efficient CO2-to-HCOOH conversion,we used density functional theory(DFT)to calculate the free energy of CO2 reduction reactions(CO2RR)on different crystal planes of N-doped SnO2(N-SnO2).The results indicate that N-SnO2 lowered the activation energy of intermediates leading to a better catalytic performance than pure SnO2.We also discovered that the N-Sn O2 (211)plane possesses the most suitable free energy during the reduction process,exhibiting the best catalytic ability for the CO2-to-HCOOH conversion.The intermediate of CO2RR on N-SnO2 is HCOO*or COOH* instead of OCHO*.These results may provide useful insights into the mechanism of CO2RR,and promote the development of heteroatomdoped catalyst for efficient CO2RR.
基金supported by the National Natural Science Foundation of China (Grant No. 51302079, 51705527 and 51672205)the National Key R&D Program of China (Grant No. 2016YFA0202602)+1 种基金the Natural Science Foundation of Hunan Province (Grant No. 2017JJ1008)the financial support by Queensland University of Technology Stratergic research grant
文摘Increasing the energy density, power density as well as widening the operation voltage are essential to electrochemical capacitors to meet the practical energy demands. Herein, a novel flexible quasi-solid-state dual-ion asymmetric supercapacitor(ASC) with Ni(OH)2 and Nb2O5 nanosheets directly grown on stainless steel mesh is developed. In the dual-ion ASC, Nb2O5 negative and Ni(OH)2 positive electrodes react with Li+ and OH- respectively in alkaline gel electrolyte to store energy, which is quite different from conventional alkali metal ion SCs and alkaline SCs. The as-assembled flexible device has an extended working voltage of 1.7 V and delivers a capacity of 5.37 mAh cm-2, a maximum energy density and power density of 0.52 mWh cm-3 and 170 mW cm-3 , respectively. The device maintains around 60% capacity retention after long cycling up to 1000 cycles. Moreover, our device can light up a LED light efficiently upon fast charging. The proposed quasi-solid-state dual-ion ASC has potential applications in future portable electronics and flexible energy storage devices.