Inspired by the cartilage-bone structure in natural joints,soft-hard integrated materials have received extensive attention,which are the most promising candidates for artificial joints due to their combination of exc...Inspired by the cartilage-bone structure in natural joints,soft-hard integrated materials have received extensive attention,which are the most promising candidates for artificial joints due to their combination of excellent load-bearing properties and lubricating properties.The latest progress showed that the combination of hydrogel and titanium alloy can realize a bionic natural joint lubrication system on the surface of titanium alloy.However,obtaining a tough interface between the hydrogel(soft and wet)and the titanium substrate(hard and dry)is still a great challenge.Here,we designed a"soft(hydrogel)-hard(Ti6Al4V)"integrated material with outstanding combination,which simulates the structure and function of cartilage-bone in the natural joint.The load-bearing properties,binding performance,and tribological behaviors for different forms of the soft-hard integrated materials were investigated.The results showed that the hydrogel layer and Ti6Al4V substrate possess ultra-high interfacial toughness(3,900 J/m^(2)).In addition,the combination of the hydrogel layer and Ti6Al4V substrate provided a good lubrication system to endow the"soft(hydrogel)-hard(Ti6Al4V)"integrated material with high load-bearing and excellent tribological properties.Therefore,this study provided an effective strategy for prolonging the service life of Ti6Al4V in the biomedical field.展开更多
基金financially supported by Natural Science Foundation of Jiangsu Province(Grant No.BK20211243)National Natural Science Foundation of China(Grant Nos.51705517,51875563,51875564)+1 种基金the Tribology Science Fund of State Key Laboratory of Tribology(Grant No.SKLTKF21B15)the Open Fund of State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics(Grant No.LSL-2107).
文摘Inspired by the cartilage-bone structure in natural joints,soft-hard integrated materials have received extensive attention,which are the most promising candidates for artificial joints due to their combination of excellent load-bearing properties and lubricating properties.The latest progress showed that the combination of hydrogel and titanium alloy can realize a bionic natural joint lubrication system on the surface of titanium alloy.However,obtaining a tough interface between the hydrogel(soft and wet)and the titanium substrate(hard and dry)is still a great challenge.Here,we designed a"soft(hydrogel)-hard(Ti6Al4V)"integrated material with outstanding combination,which simulates the structure and function of cartilage-bone in the natural joint.The load-bearing properties,binding performance,and tribological behaviors for different forms of the soft-hard integrated materials were investigated.The results showed that the hydrogel layer and Ti6Al4V substrate possess ultra-high interfacial toughness(3,900 J/m^(2)).In addition,the combination of the hydrogel layer and Ti6Al4V substrate provided a good lubrication system to endow the"soft(hydrogel)-hard(Ti6Al4V)"integrated material with high load-bearing and excellent tribological properties.Therefore,this study provided an effective strategy for prolonging the service life of Ti6Al4V in the biomedical field.
