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Au(111)上过氧化氢在碱性介质中氧化反应的pH效应(英文) 被引量:1
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作者 李皎皎 魏杰 +1 位作者 蔡俊 陈艳霞 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2018年第6期779-783,733,共6页
本文经过系统地研究Au(111)上过氧化氢在pH值从10到13的不同碱性溶液体系中氧化反应(HPOOR),发现随着溶液pH的增大,HPOOR的活性增大,电流电势i-iE极化曲线的斜率减小.HO2-是碱性溶液中HPOOR的主要反应物种,在高pH溶液下有很快的动力学... 本文经过系统地研究Au(111)上过氧化氢在pH值从10到13的不同碱性溶液体系中氧化反应(HPOOR),发现随着溶液pH的增大,HPOOR的活性增大,电流电势i-iE极化曲线的斜率减小.HO2-是碱性溶液中HPOOR的主要反应物种,在高pH溶液下有很快的动力学反应主要是由于电极表面的正电荷与体系中的阴离子HO2-和OH-等有静电相互作用的原因.因此在溶液反应物随pH增大的时候,热力学的驱动力也加快了HO2-的氧化过程. 展开更多
关键词 H2O2的氧化反应 Au(111)电极 PH效应 静电相互作用
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Statistical analysis on strain-rate effects during serrations in a Zr-based bulk metallic glass
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作者 Bo Yuan jiao-jiao li Jun-wei Qiao 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2017年第4期455-461,共7页
By means of statistical analysis,the deformation mechanisms taking place in elastic loading and plastic shearing stages during serrated flows on the stress-strain curves for bulk metallic glasses were studied comprehe... By means of statistical analysis,the deformation mechanisms taking place in elastic loading and plastic shearing stages during serrated flows on the stress-strain curves for bulk metallic glasses were studied comprehensively.Normalized serration number presented a linear increasing tendency with the decrease of applied strain rates due to the reduction of free volumes.An excellent plastic deformation was illustrated from the influences of structure arrangement with activation energy.By using mean-field theory(MFT),maximum elastic-energy density at different strain rates could be predicted by MFT besides maximum stress drops during serrations.These results were helpful for understanding the serrated flow behavior or designing decent schemes to improve the plasticity of bulk metallic glasses at room temperature. 展开更多
关键词 Bulk metallic glass Shear band Mean-field theory Serration
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Universality of slip avalanches in a ductile Fe-based bulk metallic glass
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作者 jiao-jiao li Jun-wei Qiao +3 位作者 Karin A.Dahmen Wei-ming Yang Bao-long Shen Ming-wei Chen 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2017年第4期366-371,共6页
Intermittent serrated flows of a novel ductile Fe60Ni20P13C7 bulk metallic glass(BMG)at variant strain rates were investigated by statistics analysis.Peak and clutter distribution of slip-avalanche magnitudes are di... Intermittent serrated flows of a novel ductile Fe60Ni20P13C7 bulk metallic glass(BMG)at variant strain rates were investigated by statistics analysis.Peak and clutter distribution of slip-avalanche magnitudes are displayed during stable plastic flows at strain rates of 2×10-4 s-1 and 5×10-5 s-1,respectively,which means that serration behavior depends on the strain rate.However,the remarkable agreement between measured slip-avalanche magnitudes and the scaling behavior,i.e.a universal complementary cumulative distribution function(CCDF)predicted by mean-field theory(MFT)model,indicates that the plasticity of the present Fe-based BMGs can be tuned by imposed strain rates:Smax^6)ε-λ.This tuned plasticity is elucidated with expended free-volume model.Moreover,the scaling behavior of serrated flows for other strain rates can be predicted as well. 展开更多
关键词 Bulk metallic glass Slip avalanche Plasticity Mean-field theory model Strain rate
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模拟研究石墨烯/生物基尼龙复合材料的界面热阻 被引量:2
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作者 谢航 李娇娇 +4 位作者 王小勇 伍斌 夏茹 陈鹏 钱家盛 《高分子学报》 SCIE CAS CSCD 北大核心 2021年第4期399-405,I0004,共8页
生物基尼龙(PA56)源于天然产物,具有优良的环保性能和广阔应用前景,有望替代传统的石油基尼龙材料.为了开发基于PA56的导热材料,利用分子动力学模拟研究方法探索了石墨烯/PA56复合材料界面热阻的影响因素.首先,利用实验测试商用PA56样... 生物基尼龙(PA56)源于天然产物,具有优良的环保性能和广阔应用前景,有望替代传统的石油基尼龙材料.为了开发基于PA56的导热材料,利用分子动力学模拟研究方法探索了石墨烯/PA56复合材料界面热阻的影响因素.首先,利用实验测试商用PA56样品的玻璃化转变温度(Tg)和导热系数(Tc),验证了PA56模型的模拟参数.接着,通过设计和比较不同表面改性状态对石墨烯/PA56复合材料的界面热阻的影响规律,最后,为了降低界面改性的难度,设计了一种新型的二嵌段共聚物作为石墨烯/PA56复合体系的界面改性剂,研究了界面改性剂的结构对界面热阻的影响规律.研究结果对于实验研究制备生物基尼龙导热复合材料具有重要的参考价值. 展开更多
关键词 生物基尼龙 石墨烯 界面热阻 氢键
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Serration Behavior in Zr-Cu-Al Glass-forming Systems
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作者 Zhong WANG jiao-jiao li +3 位作者 li-wei REN Yong ZHANG Jun-wei QIAO Bao-cheng WANG 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2016年第1期42-47,共6页
The metallic glass matrix composites(MGMCs)and bulk metallic glasses(BMGs)were studied by statistical analysis during plastic deformation at the strain rates of 2×10^-2,2×10^-3,and 2×10^-4 s^-1,resp... The metallic glass matrix composites(MGMCs)and bulk metallic glasses(BMGs)were studied by statistical analysis during plastic deformation at the strain rates of 2×10^-2,2×10^-3,and 2×10^-4 s^-1,respectively.No serration events occur in both MGMCs and BMGs during compression tests at the strain rate of 2×10^-2 s^-1.When deformed at the strain rate of 2×10^-3 s^-1,the BMG displays a larger plasticity,which is due to the larger serration events followed by a series of small serrations caused by the continuous movement of free volume.The amplitudes and elastic-energy densities increase with increasing the strain rates owing to many serrations in MGMCs.It is deduced that the Young′s modulus decreases from the normalized stress drop and fluctuations are observed on stressstrain curves,which is attributed to a lower coefficient according to the stick-slip model. 展开更多
关键词 bulk metallic glass metallic glass matrix composite serration shear band
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