Adhesion and corrosion resistance of polycaprolactone coating on NiTi alloy surface after alkali heat pretreatment

Selective laser melting of nickel-titanium alloy(SLM-NiTi)can precisely control the size of the sample molding structure and has attracted extensive attention due to its special superelasticity and shape memory effect.However,the biological inertness and poor corrosion resistance of SLM-NiTi alloy limit their wide application as biomedical implant materials.In this study,polycaprolactone(PCL)coating was prepared on SLM-NiTi alloy by dipping and pulling method,and the effects of alkali heat pretreatment on the morphology,adhesion,corrosion resistance,long-term stability and biomineralisation of the PCL coatings were investigated.The results showed that PCL coating can substan-tially improve the performance of SLM-NiTi alloy,and the PCL coating after alkali heat pretreatment has higher adhesion(increased from 1,747 to 2,498 mN)and lower corrosion current density(reduced by about an order of magnitude compared to PCL coating alone).In addition,the necessary stability,biomineralisation and biocompatibility ability of coatings were also further improved.Therefore,the alkali heat pretreated PCL-coated SLM-NiTi alloy has good application prospects in implants due to its superior properties.

Review of control and guidance technology on hypersonic vehicle

Air-breathing hypersonic vehicle has great military and potential economic value due to its characteristics:high velocity,long range,quick response.Therefore,the development of hypersonic vehicle and its guidance and control technology are reviewed in this paper.Firstly,the development and classification of hypersonic vehicles around the world are summarized,and the geometric configuration and mission profile of typical air-breathing hypersonic vehicle are given.Secondly,the control difficulties of air-breathing hypersonic vehicle are introduced,including integrated design of engine and fuselage,static instability,strong nonlinearity,uncertain aerodynamic parameters,etc.According to its control requirements,the control methods considering external disturbance,fault-tolerant control methods,anti-saturation methods,and prescribed performance control methods considering transient performance constraints are summarized respectively.The classification and comparison of various control methods are given,and the frontiers of theoretical development are analyzed.Finally,considering the effects of composite disturbances,the design of terminal guidance law under multiple constraints is overviewed,including guidance law with angle constraint,velocity constraint,acceleration constraint and time constraint.Similarly,the classification of guidance law design methods under different constraints,their advantages as well as the future development trend and requirements are introduced.