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合理设计多电子转移机制实现更好的水系锌-有机电池
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作者 Kovan Khasraw Abdalla 王越洋 +5 位作者 Kozhi Khasraw Abdalla 熊嘉伟 李琦 王斌 孙晓明 赵逸 《Science China Materials》 SCIE EI CAS CSCD 2024年第5期1367-1378,共12页
由于环境相容性好、分子结构可定制和有机物资源丰富等优势,水系锌-有机物电池(AZOBs)成为构建新一代大规模储能系统的关键技术.然而,电导率差、有机物溶解和单一活性基团等问题严重限制了有机物正极材料的倍率性能、稳定性和比容量.因... 由于环境相容性好、分子结构可定制和有机物资源丰富等优势,水系锌-有机物电池(AZOBs)成为构建新一代大规模储能系统的关键技术.然而,电导率差、有机物溶解和单一活性基团等问题严重限制了有机物正极材料的倍率性能、稳定性和比容量.因此,具备多氧化还原中心和稳定骨架的有机物正极材料对于实现高性能有机物正极材料至关重要.这些多官能团有机物可协同作用并激发基于多电子转移的氧化还原反应,进而促进H^(+)/Zn^(2+)共嵌以显著提升电池性能.本文探索了多官能团有机物电极的分子结构与其氧化还原反应机理之间的构效关系.本文综述了多官能团有机正极材料在提高氧化还原电位、比容量、动力学以及稳定性等方面面临的挑战和解决策略,为进一步开发先进AZOBs的关键正极材料提供了重要基础. 展开更多
关键词 aqueous zinc organic battery multifunctional organic cathodes energy storage mechanism molecular structure optimization high performance
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A Stiffness-Tunable Composite with Wide Versatility and Applicability Based on Low-Melting-Point Alloys
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作者 jiawei xiong Bo Sun +6 位作者 Chunbao Liu Konghua Yang Yuchao Luo Yunhong Liang Zhiwu Han Lei Ren Zhaohua Lin 《Journal of Bionic Engineering》 SCIE EI CSCD 2023年第6期2786-2796,共11页
Flexible materials are essential in bionic fields such as soft robots.However,the lack of stiffness limits the mechanical performance of soft robots and makes them difficult to develop in many extreme working conditio... Flexible materials are essential in bionic fields such as soft robots.However,the lack of stiffness limits the mechanical performance of soft robots and makes them difficult to develop in many extreme working conditions,such as lifting and excavation operations.To address this issue,we prepared a stiffness-tunable composite by dispersing low-melting-point alloy into thermosetting epoxy resin.A dramatic and rapid change in stiffness was achieved by changing the state of matter at lower temperatures,and accurate control of the composite modulus was achieved by controlling the temperature.When the alloy content is at 30vol%,the tensile modulus changes 41.6 times,while the compressive modulus changes 58.9 times.By applying the composite to a flexible actuator,the initial stiffness of the actuator was improved by 124 times,reaching 332 mN/mm.In addition,the use of stiffness-tunable materials in the wheel allowed for timely changes in the grounding area to improve friction.These flexible materials with manageable mechanical properties have wide applicability in fields including bionics,robotics,and sensing.Our findings provide a new approach to designing and developing flexible materials with improved stiffness and controllability. 展开更多
关键词 Stiffness-tunable composite Manageable mechanical properties Flexible actuator
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