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La掺杂TiO_2负载Pt催化剂制备及其室温氧化低浓度甲醛(英文) 被引量:11
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作者 彭洪根 应家伟 +6 位作者 张景岩 张先华 彭程 饶成 刘文明 张宁 王翔 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2017年第1期39-47,共9页
甲醛是室内装修污染的重要组分,已严重危害到人们身体健康,在室温条件下消除甲醛引起了人们的广泛兴趣.目前室温清除甲醛主要有物理吸附法、光催化法、等离子体技术及催化氧化技术.物理吸附法主要采用活性炭等作为吸附剂,其初期吸附效... 甲醛是室内装修污染的重要组分,已严重危害到人们身体健康,在室温条件下消除甲醛引起了人们的广泛兴趣.目前室温清除甲醛主要有物理吸附法、光催化法、等离子体技术及催化氧化技术.物理吸附法主要采用活性炭等作为吸附剂,其初期吸附效果较好,但当吸附饱和之后会重新释放甲醛造成二次污染;光催化法和等离子体技术需要特殊装置,不适合室内室温环境脱除甲醛;而催化氧化技术则可直接将甲醛转化为无毒无害的水和CO2,因而备受关注.Pt/TiO_2被认为是目前消除甲醛最有效的催化剂.为进一步降低贵金属Pt的用量及增强其稳定性(Pt被氧化后其活性会降低),本文首次采用稀土La掺杂锐钛矿型TiO_2,负载少量Pt后用于室内低浓度(0.5 ppm)甲醛的催化氧化.活性测试结果表明,纯TiO_2催化剂上甲醛转化率在5%以下,有可能是物理吸附或可见光催化所致.负载0.5%Pt后,Pt/TiO_2和Pt/La-TiO_2甲醛转化率均高于80%,尤其是La掺杂活性高达96%以上,且在连续反应8 h甚至延长至40 h后其活性均未见下降趋势.电镜结果表明,La掺杂Pt/La-TiO_2催化剂中Pt粒径从未掺杂的2.2 nm降至1.7 nm;CO程序升温脱附测试表明,Pt/La-TiO_2/Pt的分散度达66%,而未掺杂样品仅为51%;X射线光电子能谱测试表明,Pt/La-TiO_2的表面氧物种高于Pt/TiO_2催化剂,说明La掺杂增强了Pt和载体间的相互作用.为探讨Pt/La-TiO_2商业化应用前景,将粉体Pt/La-TiO_2涂覆在堇青石蜂窝陶瓷上制备成整体催化剂.该整体催化剂在容积为2 m3的密室测试中5 min内即可将浓度为0.5 ppm的甲醛将至0.02 ppm以下.该催化剂在存放3个月后活性略有下降,但在10 min内仍可将甲醛浓度降至0.08ppm,达到室内甲醛排放标准.综上,本文成功制备了La掺杂Pt/La-TiO_2用于室内低浓度甲醛催化氧化,该催化剂表现出优异的催化性能.通过多种表征手段表明,La修饰后贵金属Pt纳米粒子尺寸减小、分散度提高及Pt与载体间相互作用增强是其活性优异的主要原因.以Pt/La-TiO_2粉体制备的整体催化剂同样表现出了高的催化性能,具有工业应用前景. 展开更多
关键词 低浓度甲醛 室温氧化 稀土 镧掺杂 二氧化钛 整体催化剂
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Research progress and clinical translation of three-dimensional printed porous tantalum in orthopaedics
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作者 jiawei ying Haiyu Yu +7 位作者 Liangliang Cheng Junlei Li Bin Wu Liqun Song Pinqiao Yi Haiyao Wang Lingpeng Liu Dewei Zhao 《Biomaterials Translational》 2023年第3期166-179,共14页
With continuous developments in additive manufacturing technology, tantalum (Ta) metal has been manufactured into orthopaedic implants with a variety of forms, properties and uses by three-dimensional printing. Based ... With continuous developments in additive manufacturing technology, tantalum (Ta) metal has been manufactured into orthopaedic implants with a variety of forms, properties and uses by three-dimensional printing. Based on extensive research in recent years, the design, processing and performance aspects of this new orthopaedic implant material have been greatly improved. Besides the bionic porous structure and mechanical characteristics that are similar to human bone tissue, porous tantalum is considered to be a viable bone repair material due to its outstanding corrosion resistance, biocompatibility, bone integration and bone conductivity. Numerous in vitro, in vivo, and clinical studies have been carried out in order to analyse the safety and efficacy of these implants in orthopaedic applications. This study reviews the most recent advances in manufacturing, characteristics and clinical application of porous tantalum materials. 展开更多
关键词 3D printed additive manufacturing orthopaedic implant POROUS TANTALUM
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