ZnO thin film was fabricated on tin-doped indium oxide electrode as an electron selective layer of inverted polymer solar cells using magnetron sputtering deposition. Ionic liquid-functionalized carbon nanoparticles(I...ZnO thin film was fabricated on tin-doped indium oxide electrode as an electron selective layer of inverted polymer solar cells using magnetron sputtering deposition. Ionic liquid-functionalized carbon nanoparticles(ILCNs) film was further deposited onto ZnO surfaces by drop-casting ILCNs solution to improve interface properties. The power conversion efficiency(PCE) of inverted polymer solar cells(PSCs)with only ZnO layer was quickly decreased from 2.7% to 2.2% when the thickness of ZnO layer was increased from 15 nm to 60 nm. However, the average PCE of inverted PSCs with ZnO layer modified with ILCNs only decreased from 3.5% to 3.4%, which is comparable to that of traditional PSCs with poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) anode buffer layer. The results suggested that the contact barrier between ZnO layer and poly(3-hexylthiophene) and phenyl-C61-butyric acid methylester(P3HT:PCBM)blended film compared to ZnO bulk resistance can more significantly influence the performance of inverted PSCs with sputtered ZnO layer. The vanishment of negative capacitive behavior of inverted PSCs with ILCNs modified ZnO layer indicated ILCNs can greatly decrease the contact barrier of ZnO/P3HT:PCBM interface.展开更多
Artistic specialty students are relatively special in high school education of our country,fine art students is one of them.This article explains the reasons for the current problems to art students in the process of ...Artistic specialty students are relatively special in high school education of our country,fine art students is one of them.This article explains the reasons for the current problems to art students in the process of constructing the conception of history,combining with the actual conditions,it tentatively proposes corresponding solutions to promote the deepening development of the history teaching of art students and the construction of the conception of history,carry out the educational requirements of“strengthening moral education and cultivating people”in the teaching process.展开更多
基金supported by National Natural Science Foundation of China (grant Nos.61275038,11274119)Natural Science Foundation of Shanghai Science and Technology Commission (grant No.11ZR1411300)+2 种基金Pujiang Talent Program of Shanghai Science and Technology Commission (grant No.11PJ1402700)Doctoral Fund of Ministry of Education of China (grant No.20110076120017)SRF for ROCS,SEM
文摘ZnO thin film was fabricated on tin-doped indium oxide electrode as an electron selective layer of inverted polymer solar cells using magnetron sputtering deposition. Ionic liquid-functionalized carbon nanoparticles(ILCNs) film was further deposited onto ZnO surfaces by drop-casting ILCNs solution to improve interface properties. The power conversion efficiency(PCE) of inverted polymer solar cells(PSCs)with only ZnO layer was quickly decreased from 2.7% to 2.2% when the thickness of ZnO layer was increased from 15 nm to 60 nm. However, the average PCE of inverted PSCs with ZnO layer modified with ILCNs only decreased from 3.5% to 3.4%, which is comparable to that of traditional PSCs with poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) anode buffer layer. The results suggested that the contact barrier between ZnO layer and poly(3-hexylthiophene) and phenyl-C61-butyric acid methylester(P3HT:PCBM)blended film compared to ZnO bulk resistance can more significantly influence the performance of inverted PSCs with sputtered ZnO layer. The vanishment of negative capacitive behavior of inverted PSCs with ILCNs modified ZnO layer indicated ILCNs can greatly decrease the contact barrier of ZnO/P3HT:PCBM interface.
文摘Artistic specialty students are relatively special in high school education of our country,fine art students is one of them.This article explains the reasons for the current problems to art students in the process of constructing the conception of history,combining with the actual conditions,it tentatively proposes corresponding solutions to promote the deepening development of the history teaching of art students and the construction of the conception of history,carry out the educational requirements of“strengthening moral education and cultivating people”in the teaching process.