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Germanium-Carbdiyne: A 3D Well-Defined sp-Hybridized Carbon-Based Material with Superhigh Li Storage Property 被引量:1
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作者 Ze Yang Xin Ren +6 位作者 Yuwei Song Xiaodong li Chunfang Zhang Xiuli Hu Jianjiang He jiazhu li Changshui Huang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第1期199-206,共8页
Carbyne delivers various excellent properties for the existence of the larger number of sp-hybridized carbon atoms.Here,a 3D well-defined porous carbon material germanium-carbdiyne(Ge-CDY)which is comprised of only sp... Carbyne delivers various excellent properties for the existence of the larger number of sp-hybridized carbon atoms.Here,a 3D well-defined porous carbon material germanium-carbdiyne(Ge-CDY)which is comprised of only sp-hybridized carbon atoms bridging by Ge atoms has been developed and investigated.The unique diamond-like structure constructed by linear butadiyne bonds and sp 3-hybridized Ge atoms ensures the stability of Ge-CDY.The large percentage of conjugated alkyne bonds composed of sp-C guarantees the good conductivity and the low band gap,which were further confirmed experimentally and theoretically,endowing Ge-CDY with the potential in electrochemical applications.The well-defined 3D carbon skeleton of Ge-CDY provides abundant uniform nanopores,which is suitable for metal ions storage and diffusion.Further half-cell evaluation also demonstrated Ge-CDY exhibited an excellent performance in lithium storage.All those indicating sp-hybridized carbon-based materials can exhibit great potential to possess excellent properties and be applied in the field of energy,electronic,and so on. 展开更多
关键词 3D porous material electrochemical energy storage germanium-carbdiyne lithium storage theoretical predictions
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Pharmacological Action and Molecular Mechanism of Lithospermoside
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作者 Anqi WANG jiazhu li +3 位作者 Jingjing WEN Changtao CAI Jundong GUAN Chenghao JIN 《Plant Diseases and Pests》 CAS 2023年第5期26-29,共4页
Lithospermoside is a kind of alkaloid compound existing in Semiaquilegia adoxoides,with anticancer,anti-inflammatory,antibacterial,hypoglycemic,antioxidant and other pharmacological effects.This paper reviews the phar... Lithospermoside is a kind of alkaloid compound existing in Semiaquilegia adoxoides,with anticancer,anti-inflammatory,antibacterial,hypoglycemic,antioxidant and other pharmacological effects.This paper reviews the pharmacological action and molecular mechanism of lithospermoside,in order to provide a theoretical basis for clinical application of lithospermoside. 展开更多
关键词 Lithospermoside ANTICANCER ANTI-INFLAMMATORY ANTIBACTERIAL HYPOGLYCEMIC ANTIOXIDANT
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经典肉桂酸合成实验的改进与拓展
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作者 高庆英 罗涛 +6 位作者 苏建源 俞超凡 李家柱 焉炳飞 李文佐 张震 刘义 《大学化学》 CAS 2024年第5期243-250,共8页
肉桂酸合成实验是高等学校现行《有机化学实验》教材中的一个重要单列基础实验。该实验在教学实施过程中暴露出残余苯甲醛气味难闻、原料对水敏感、购存困难、高温副产物多等问题。针对以上问题,本论文对经典肉桂酸合成实验进行了改进:... 肉桂酸合成实验是高等学校现行《有机化学实验》教材中的一个重要单列基础实验。该实验在教学实施过程中暴露出残余苯甲醛气味难闻、原料对水敏感、购存困难、高温副产物多等问题。针对以上问题,本论文对经典肉桂酸合成实验进行了改进:采用苯甲醛/丙二酸/三乙烯二胺的均相反应体系制备肉桂酸,采用亚硫酸氢钠洗涤、萃取的后处理方法去除残余苯甲醛,使其更符合现代实验教学和绿色化学的要求。改进后的实验不仅可有效去除难闻的残余苯甲醛,还具有原料稳定性好、价格低廉、后处理操作简单等优点。通过增加波谱学表征、柱色谱分离等环节,该实验可以拓展为以精细化学品阿魏酸为合成目标的8学时综合性创新实验,提高对学生化学综合素质的培养。 展开更多
关键词 肉桂酸 合成实验 亚硫酸氢钠 实验创新
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Pharmacologic Effects of Cannabidiol and Its Molecular Mechanism
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作者 Jundong GUAN Anqi WANG +3 位作者 jiazhu li Jingjing WEN Changtao CAI Chenghao JIN 《Plant Diseases and Pests》 2024年第4期43-46,共4页
Cannabidiol(CBD)is the active constituent of Cannabis sativa and exhibits a diverse range of pharmacologic effects,including anticancer,antibacterial,anti-inflammatory,antioxidant,and antiepileptic properties.The phar... Cannabidiol(CBD)is the active constituent of Cannabis sativa and exhibits a diverse range of pharmacologic effects,including anticancer,antibacterial,anti-inflammatory,antioxidant,and antiepileptic properties.The pharmacologic effects of CBD and its molecular mechanisms are reviewed with the objective of proposing novel approaches for basic research and clinical applications of CBD and related pharmaceuticals. 展开更多
关键词 CANNABIDIOL ANTICANCER ANTIBACTERIAL ANTI-INFLAMMATORY Antioxidant ANTIEPILEPTIC
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Pharmacological Effects and Mechanism of Esculentoside A
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作者 Anqi WANG Jundong GUAN +3 位作者 Changtao CAI jiazhu li Jingjing WEN Chenghao JIN 《Medicinal Plant》 2024年第4期26-28,共3页
Extensive studies have found that Esculentoside a(EsA)has a variety of pharmacological effects,such as anti-inflammatory,anti-bacterial,anti-tumor and the treatment of arthritis.In the present paper,the pharmacologica... Extensive studies have found that Esculentoside a(EsA)has a variety of pharmacological effects,such as anti-inflammatory,anti-bacterial,anti-tumor and the treatment of arthritis.In the present paper,the pharmacological effects and related mechanisms of EsA in recent years were reviewed,in order to provide a theoretical reference for further research and development of EsA. 展开更多
关键词 Esculentoside A(EsA) ANTI-INFLAMMATION Anti-bacterium ANTI-TUMOR ARTHRITIS
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Pharmacological Action and Mechanism of Dendrobine
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作者 Jingjing WEN Wenshuang HOU +5 位作者 Anqi WANG jiazhu li Jundong GUAN Zhe liU Changtao CAI Chenghao JIN 《Medicinal Plant》 2023年第6期88-90,98,共4页
Dendrobine,an alkaloid extracted from the stem of Dendrobium nobile Lindl.,has many biological activities such as anti-cancer effect,anti-inflammation effect,anti-influenza A virus effect,treatment of leukemia,treatme... Dendrobine,an alkaloid extracted from the stem of Dendrobium nobile Lindl.,has many biological activities such as anti-cancer effect,anti-inflammation effect,anti-influenza A virus effect,treatment of leukemia,treatment of Parkinson s disease,protection of internal organs and promotion of cell maturation.In this paper,the related research progress of pharmacological action and molecular mechanism of dendrobine will be reviewed in order to provide a theoretical basis for further research and drug development of dendrobine. 展开更多
关键词 DENDROBINE ANTI-CANCER ANTI-INFLAMMATION Anti-influenza A virus Leukemia treatment
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Anticancer,Anti-inflammatory and Antibacterial Effects of Aloin and Its Molecular Mechanism
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作者 Ting XU Wenshuang HOU +3 位作者 Yuhe CUI Anqi WANG jiazhu li Chenghao JIN 《Medicinal Plant》 2023年第6期81-83,87,共4页
Aloin is the main medicinal component extracted from Aloe vera.It is a natural anthraquinone compound,with anticancer,anti-inflammatory and antibacterial and other biological functions.This paper reviews the pharmacol... Aloin is the main medicinal component extracted from Aloe vera.It is a natural anthraquinone compound,with anticancer,anti-inflammatory and antibacterial and other biological functions.This paper reviews the pharmacological action and related mechanisms of aloin,in order to provide a theoretical basis for the development and utilization of aloin. 展开更多
关键词 ALOIN ANTICANCER ANTI-INFLAMMATORY ANTIBACTERIAL
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7-硝基苯并噻吩-2-甲酸乙酯合成实验的优化与改进 被引量:1
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作者 李家柱 洪莹莹 +3 位作者 满英秀 李英豪 李庆忠 何涛 《大学化学》 CAS 2022年第5期256-262,共7页
有机合成实验是化学专业学生重要单列实验课程,目前选用的有机合成实验项目多为单步骤合成操作,对学生多步合成的衔接、化合物的检测和鉴定等方面的训练存在不足。7-硝基苯并噻吩-2-甲酸乙酯的合成是本校应用化学专业学生有机合成实验... 有机合成实验是化学专业学生重要单列实验课程,目前选用的有机合成实验项目多为单步骤合成操作,对学生多步合成的衔接、化合物的检测和鉴定等方面的训练存在不足。7-硝基苯并噻吩-2-甲酸乙酯的合成是本校应用化学专业学生有机合成实验课程中的一个综合训练项目,但存在耗时较长、产率不稳定,后处理难度较大及使用有毒试剂等问题。本项目旨在改进苯并噻吩环系的合成方法和步骤,降低试剂用量,提高产率,优化后处理过程,减少有毒物使用和三废排放,使之更符合教学实验和绿色化学要求;同时,改进后的实验增加了有机波谱分析内容,训练学生通过红外光谱、核磁共振氢谱及质谱等方式对目标化合物进行表征,更有利于学生综合素质的培养。 展开更多
关键词 有机合成 多步合成 绿色化学 苯并噻吩
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The Hardness and Corrosion Properties of Trivalent Chromium Hard Chromium 被引量:6
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作者 jiazhu li Yanjing li +4 位作者 Xiaohua Tian ling Zou Xing Zhao Sanfeng Wang Shenggang Wang 《Materials Sciences and Applications》 2017年第13期1014-1026,共13页
The formulation of hard chromium plating from trivalent chromium electrolyte and its related process have been intensively studied in this work. Through optimized conditions, the coating hardness can achieve more than... The formulation of hard chromium plating from trivalent chromium electrolyte and its related process have been intensively studied in this work. Through optimized conditions, the coating hardness can achieve more than HV0.1900 without any treatment and HV0.11700 after heat treatment for five minutes at 300&deg;C, and the thickness of hard chromium coating was about 100 μm. The hard chromium coatings show good adhesion on the carbon steel and low alloy structural steel. The corrosion resistance of hard chromium coatings was enhanced by the adding nanometer materials into trivalent chromium plating coatings. More than 120 hours salt spray corrosion resistance can be achieved with 40 to 50 microns thickness of trivalent chromium plating coatings. 展开更多
关键词 CORROSION Resistance NANOMETER Materials HARD CHROMIUM TRIVALENT CHROMIUM
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Review of Pharmacological Effects and Mechanisms of Crotonoside
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作者 Anqi WANG Yannan li +5 位作者 Wenbo ZUO Yue TENG jiazhu li Qing ZHANG Xue ZHAO Chenghao JIN 《Medicinal Plant》 CAS 2021年第2期1-2,共2页
Crotonoside is an important alkaloid component in Croton tiglium.It has the effects of drastic purgation,expelling water and reducing swelling,eliminating phlegm and relieving pharynx.Studies have found that crotonosi... Crotonoside is an important alkaloid component in Croton tiglium.It has the effects of drastic purgation,expelling water and reducing swelling,eliminating phlegm and relieving pharynx.Studies have found that crotonoside can exert a variety of pharmacological effects such as anti-cancer,anti-inflammatory,anti-arrhythmic,and anti-acute myelogenous leukemia through a variety of ways.This paper reviewed the pharmacological effects and mechanisms of crotonoside. 展开更多
关键词 Crotonoside ANTI-CANCER ANTI-INFLAMMATION Anti-arrhythmia Anti-acute myeloid leukemia
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Research Progress on Pharmacological Action of 5-O-methylvisammioside
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作者 jiazhu li Anqi WANG +3 位作者 Yue TENG Yuwei WANG Yinghua LUO Chenghao JIN 《Medicinal Plant》 CAS 2021年第4期96-97,共2页
5-O-methylvisammioside is a chemical derived from the dry root of Saposhnikovia divaricata,which has the functions of expelling pathogenic wind from body surface,removing dampness to relieve pain,and relieving convuls... 5-O-methylvisammioside is a chemical derived from the dry root of Saposhnikovia divaricata,which has the functions of expelling pathogenic wind from body surface,removing dampness to relieve pain,and relieving convulsion.Recent studies have found that 5-O-methylvisammioside can play a variety of pharmacological effects such as anti-tumor,anti-inflammation,anti-virus and anti-depression through a variety of ways.The paper reviews the pharmacological action and mechanism of 5-O-methylvisammioside in recent years. 展开更多
关键词 5-O-METHYLVISAMMIOSIDE ANTI-TUMOR ANTI-INFLAMMATION ANTI-VIRUS Anti-depression
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Study on Pharmacological Effects of Harmine Hydrochloride
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作者 Yue TENG Anqi WANG +4 位作者 jiazhu li Qing ZHANG Xue ZHAO Yuwei WANG Chenghao JIN 《Medicinal Plant》 CAS 2021年第3期4-6,共3页
Harmaine hydrochloride is an important alkaloid compound and mainly exists in the roots,stems,leaves and seeds of the plant Peganum harmala L.(family Zygophyllaceae).Harmaine hydrochloride not only has good anti-bacte... Harmaine hydrochloride is an important alkaloid compound and mainly exists in the roots,stems,leaves and seeds of the plant Peganum harmala L.(family Zygophyllaceae).Harmaine hydrochloride not only has good anti-bacterial,anti-plasmodium,anti-Parkinson's disease,anti-fungal,anti-oxidation and anti-tumor activities,but also has the characteristics of small adverse reactions and low toxicity,thus it has attracted wide attention from scholars and researchers.This paper reviews the pharmacological effects and mechanisms of harmine hydrochloride in recent years,and is intended to provide a theoretical basis for the clinical application of harmine hydrochloride. 展开更多
关键词 Harmaine hydrochloride Pharmacological effects Anti-Parkinson's disease Antibacterial activity Anti-tumor activity
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苯并噻吩稠合双硼荧光染料的手性光学性质及组装手性放大研究
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作者 孙营柱 于长江 +4 位作者 焦莉娟 徐瑞明 郝二红 李家柱 刘鸣华 《中国科学:化学》 CAS CSCD 北大核心 2024年第8期1352-1360,共9页
近年来,基于有机硼的手性发光材料因具有其独特结构和性质备受关注.本研究在吡咯吡啶腙肼双硼荧光团(BOPPY)上同时引入了苯并噻吩和手性胺侧链,成功构建了一种新型苯并噻吩稠环手性BOPPY.相对于手性母体,苯并噻吩稠环的导入实现了其圆二... 近年来,基于有机硼的手性发光材料因具有其独特结构和性质备受关注.本研究在吡咯吡啶腙肼双硼荧光团(BOPPY)上同时引入了苯并噻吩和手性胺侧链,成功构建了一种新型苯并噻吩稠环手性BOPPY.相对于手性母体,苯并噻吩稠环的导入实现了其圆二色(CD)和圆偏振发光(CPL)光谱分别红移50和70 nm,同时伴随手性旋向的反转.此外,手性BOPPY分子在有机溶剂中展现出镜像的CD、明亮的黄绿色CPL(Φ_(F)=0.37,540 nm,g_(lum)=1×10^(-4))、高摩尔吸光系数、大斯托克斯位移、良好的热稳定性,以及荧光量子产率高达25%的强薄膜固态发射(538 nm,g_(lum)=7.4×10^(-4)).更有趣的是,手性BOPPY分子在水中表现出聚集诱导荧光增强活性,其在表面活性剂作用下进行共组装的超分子体系显示出手性放大行为,得到的聚集体表现出显著增强的圆偏振发光性质(566 nm,g_(lum)=0.069),组装体g_(lum)相比于其分子态提升了690倍.推测手性放大机制可能是手性BOPPY分子和表面活性剂在弱相互作用协同驱动进行各向异性调节,从而构建了有序的手性纳米结构. 展开更多
关键词 圆偏振发光 双硼荧光染料 聚集诱导发光 超分子组装 手性放大
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具有芳并咪唑结构单元的叶绿素类二氢卟吩衍生物的合成 被引量:4
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作者 张珠 赵雨 +2 位作者 王欣悦 李家柱 王进军 《有机化学》 SCIE CAS CSCD 北大核心 2021年第3期1177-1186,共10页
以脱镁叶绿酸-a甲酯为起始原料,利用其外接环的结构转换,在N^(21)-N^(23)轴水溶性端向的不同位置上构建了甲酰基和邻位二酮结构;通过连有活性官能团的叶绿素类二氢卟吩与多种芳香邻位二胺进行类Phillps-Ladenburg反应,以连接和并合的方... 以脱镁叶绿酸-a甲酯为起始原料,利用其外接环的结构转换,在N^(21)-N^(23)轴水溶性端向的不同位置上构建了甲酰基和邻位二酮结构;通过连有活性官能团的叶绿素类二氢卟吩与多种芳香邻位二胺进行类Phillps-Ladenburg反应,以连接和并合的方式在其周环上引进了芳并咪唑结构单元;完成了一系列未见报道的具有芳并咪唑结构单元的叶绿素类二氢卟吩衍生物的合成,讨论了相应的反应机理和咪唑化产物的紫外-可见光谱性质.所有新合成化合物的结构均经UV-Vis、IR、^(1)H NMR、MS及元素分析予以证实. 展开更多
关键词 叶绿素 脱镁叶绿酸 二氢卟吩 芳并咪唑化 合成
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An integrated micromachined flexible ultrasonicinductive sensor for pipe contaminant multiparameter detection
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作者 Zheng Yuan Xiaoyu Wu +12 位作者 Zhikang li Jiawei Yuan Yihe Zhao Zixuan li Shaohui Qin Qi Ma Xuan Shi Zilong Zhao jiazhu li Shiwang Zhang Weixuan Jing Xiaozhang Wang libo Zhao 《Microsystems & Nanoengineering》 SCIE EI 2024年第4期271-283,共13页
Pipe contaminant detection holds considerable importance within various industries,such as the aviation,maritime,medicine,and other pertinent fields.This capability is beneficial for forecasting equipment potential fa... Pipe contaminant detection holds considerable importance within various industries,such as the aviation,maritime,medicine,and other pertinent fields.This capability is beneficial for forecasting equipment potential failures,ascertaining operational situations,timely maintenance,and lifespan prediction.However,the majority of existing methods operate offline,and the detectable parameters online are relatively singular.This constraint hampers real-time on-site detection and comprehensive assessments of equipment status.To address these challenges,this paper proposes a sensing method that integrates an ultrasonic unit and an electromagnetic inductive unit for the real-time detection of diverse contaminants and flow rates within a pipeline.The ultrasonic unit comprises a flexible transducer patch fabricated through micromachining technology,which can not only make installation easier but also focus the sound field.Moreover,the sensing unit incorporates three symmetrical solenoid coils.Through a comprehensive analysis of ultrasonic and induction signals,the proposed method can be used to effectively discriminate magnetic metal particles(e.g.,iron),nonmagnetic metal particles(e.g.,copper),nonmetallic particles(e.g.,ceramics),and bubbles.This inclusive categorization encompasses nearly all types of contaminants that may be present in a pipeline.Furthermore,the fluid velocity can be determined through the ultrasonic Doppler frequency shift.The efficacy of the proposed detection principle has been validated by mathematical models and finite element simulations.Various contaminants with diverse velocities were systematically tested within a 14mm diameter pipe.The experimental results demonstrate that the proposed sensor can effectively detect contaminants within the 0.5−3mm range,accurately distinguish contaminant types,and measure flow velocity. 展开更多
关键词 inductive holds ultrasonic
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