Laboratory simulation of CO_(2) immiscible gas flooding and characterization of seepage resistance

CO_(2) flooding can significantly improve the recovery rate, effectively recover crude oil, and has the advantages of energy saving and emission reduction. At present, most domestic researches on CO_(2) flooding seepage experiments are field tests in actual reservoirs or simulations with reservoir numerical simulators. Although targeted, the promotion is poor. For the characterization of seepage resistance, there are few studies on the variation law of seepage resistance caused by the combined action in the reservoir. To solve this problem, based on the mechanism of CO_(2), a physical simulation experiment device for CO_(2) non-miscible flooding production manner is designed. The device adopts two displacement schemes, gas-displacing water and gas-displacing oil, it mainly studies the immiscible gas flooding mechanism and oil displacement characteristics based on factors such as formation dip angle, gas injection position, and gas injection rate. It can provide a more accurate development simulation for the actual field application. By studying the variation law of crude oil viscosity and start-up pressure gradient, the characterization method of seepage resistance gradient affected by these two factors in the seepage process is proposed. The field test is carried out for the natural core of the S oilfield, and the seepage resistance is described more accurately. The results show that the advancing front of the gas drive is an arc, and the advancing speed of the gas drive oil front is slower than that of gas drive water;the greater the dip angle, the higher the displacement efficiency;the higher the gas injection rate is, the higher the early recovery rate is, and the lower the later recovery rate is;oil displacement efficiency is lower than water displacement efficiency;taking the actual core of S oilfield as an example, the mathematical representation method of core start-up pressure gradient in low permeability reservoir is established.

A novel numerical simulation of CO_(2) immiscible flooding coupled with viscosity and starting pressure gradient modeling in ultra-low permeability reservoir

CO_(2) immiscible flooding is an environmentally-friendly and effective method to enhance oil recovery in ultra-low permeability reservoirs.A mathematical model of CO_(2) immiscible flooding was developed,considering the variation in crude oil viscosity and starting pressure gradient in ultra-low permeability reservoirs based on the non-Darcy percolation theory.The mathematical model and numerical simulator were developed in the C++language to simulate the effects of fluid viscosity,starting pressure gradient,and other physical parameters on the distribution of the oil pressure field,oil saturation field,gas saturation field,oil viscosity field,and oil production.The results showed that the formation pressure and pressure propagation velocity in CO_(2) immiscible flooding were lower than the findings without considering the starting pressure gradient.The formation oil content saturation and the crude oil formation viscosity were higher after the consideration of the starting pressure gradient.The viscosity of crude oil considering the initiation pressure gradient during the formation was higher than that without this gradient,but the yield was lower than that condition.Our novel mathematical models helped the characterization of seepage resistance,revealed the influence of fluid property changes on seepage,improved the mathematical model of oil seepage in immiscible flooding processes,and guided the improvement of crude oil recovery in immiscible flooding processes.

Characteristics of plankton Hg bioaccumulations based on a global data set and the implications for aquatic systems with aggravating nutrient imbalance

The bioaccumulation of mercury(Hg)in aquatic ecosystem poses a potential health risk to human being and aquatic organism.Bioaccumulations by plankton represent a crucial process of Hg transfer from water to aquatic food chain.However,the current understanding of major factors affecting Hg accumulation by plankton is inadequate.In this study,a data set of 89 aquatic ecosystems worldwide,including inland water,nearshore water and open sea,was established.Key factors influencing plankton Hg bioaccumulation(i.e.,plankton species,cell sizes and biomasses)were discussed.The results indicated that total Hg(THg)and methylmercury(MeHg)concentrations in plankton in inland waters were significantly higher than those in nearshore waters and open seas.Bioaccumulation factors for the logarithm of THg and MeHg of phytoplankton were 2.4–6.0 and 2.6–6.7 L/kg,respectively,in all aquatic ecosystems.They could be further biomagnified by a factor of 2.1–15.1 and 5.3–28.2 from phytoplankton to zooplankton.Higher MeHg concentrations were observed with the increases of cell size for both phyto-and zooplankton.A contrasting trend was observed between the plankton biomasses and BAF_(MeHg),with a positive relationship for zooplankton and a negative relationship for phytoplankton.Plankton physiologic traits impose constraints on the rates of nutrients and contaminants obtaining process from water.Nowadays,many aquatic ecosystems are facing rapid shifts in nutrient compositions.We suggested that these potential influences on the growth and composition of plankton should be incorporated in future aquatic Hg modeling and ecological risk assessments.