Three-dimensional visualization technology converts engineering design drawings and data into graphics or images, realizes virtual reality perception of simulated users in future construction scene, enhances the inter...Three-dimensional visualization technology converts engineering design drawings and data into graphics or images, realizes virtual reality perception of simulated users in future construction scene, enhances the interaction between project management and technical personnel and engineering construction achievement, and provides intuitive, flexible and strong realistic experience for project management. It can effectively improve the level of project communication, and assist the needs of project construction planning management, training, exhibition, etc. As a tool to help improve project management skills, it has good application effect and prospects.展开更多
Control of self-assembly is significant to the preparation of supramolecular materials, but the control of hydration, responsiveness, dimension, catalysis of macrocyclic amphiphiles in an atom-economic manner is still...Control of self-assembly is significant to the preparation of supramolecular materials, but the control of hydration, responsiveness, dimension, catalysis of macrocyclic amphiphiles in an atom-economic manner is still a great challenge. The herein presented 527 Da low-molecular-weight macrocyclic amphiphile was fabricated by utilizing the selenium-containing crown ether as a hydrophobic motif together with guanidinium group as the hydrophilic moiety. The resulting benzo[21]crown-7 based macrocyclic amphiphile readily forms a redox-responsive solid nanoparticles in water, which can further interconnect into wrinkled pattern on-surface, as well as exhibits as a nanozyme for catalyzing disulfid bond formation. The present work highlights the great potential of guanidinium-and selenium-containing crown ethers for the control of functional assemblies.展开更多
Gallium-based liquid metal has gained significant attention in conformal flexible electronics due to its high electrical conductivity,intrinsic deformability,and biocompatibility.However,the fabrication of large-area ...Gallium-based liquid metal has gained significant attention in conformal flexible electronics due to its high electrical conductivity,intrinsic deformability,and biocompatibility.However,the fabrication of large-area and highly uniform conformal liquid metal films remains challenging.Interfacial self-assembly has emerged as a promising method,but traditional approaches face difficulties in assembling liquid metal particles.Here,we realized the multi-size universal self-assembly(MUS)for liquid metal particles with various diameters(<500μm).By implementing a z-axis undisturbed interfacial material releasing strategy,the interference of gravitational energy on the stability of floating particles is avoided,enabling the fabrication of ultra-conformable monolayer films with large areas(>100 cm^(2))and high floating yield(50–90%).Moreover,the films can be conformally transferred onto complex surfaces such as human skin,allowing for the fabrication of substrate-free flexible devices.This eliminates interference from traditional substrate mechanical responses,making the liquid metal e-tattoo more user-friendly.展开更多
Resistive switching (RS) behaviors have attracted great interest due to their promising potential for the data storage. Among various materials, oxide-based devices appear to be more advantageous considering their h...Resistive switching (RS) behaviors have attracted great interest due to their promising potential for the data storage. Among various materials, oxide-based devices appear to be more advantageous considering their handy fabrication and compatibility with CMOS technology, though the underlying mechanism is still controversial due to the diversity of RS behaviors. In this review, we focus on the oxide-based RS memories, in which the working mechanism can be understood basically according to a so-called filament model. The filaments formation/rupture processes, approaches developed to detect and characterize filaments, several effective attempts to improve the performances of RS and the quantum conductance behaviors in oxide-based resistive random access memory (RRAM) devices are addressed, respectively.展开更多
In this paper, a case of premature ovarian failure (POF), accompanied with amenorrhea for 2 years was reported. After 2 months of acupuncture, the patient's menstruation was resumed, and after 11 months of treatmen...In this paper, a case of premature ovarian failure (POF), accompanied with amenorrhea for 2 years was reported. After 2 months of acupuncture, the patient's menstruation was resumed, and after 11 months of treatment, the patient had a spontaneous pregnancy. It is suggested that acupuncture should be used for the patient with POF as early as possible, and if necessary, hormone replacement therapy is still needed, and it is still expected to obtain spontaneous pregnancy before completely exhausted of ovarian function.展开更多
Graphitic carbon nitride(g-C_(3)N_(4))as a metal-free candidate of photocatalyst has received worldwide attention because of its great potentials in solar light-induced degradation and hydrogen evolution,yet the indus...Graphitic carbon nitride(g-C_(3)N_(4))as a metal-free candidate of photocatalyst has received worldwide attention because of its great potentials in solar light-induced degradation and hydrogen evolution,yet the industrial application is seriously hindered by the small specific surface area and rapid recombination rate of carriers.Herein,we demonstrate that porous g-C_(3)N_(4)(HCl-CNU-X)can be prepared via the copolymerization of acidified melamine and a green bubble template(urea).Transmission electron microscopy and nitrogen sorption characterization results show that the prepared HCl-CNU-X possesses an in-plane porous structure and large specific surface area,enabling the exposure of more accessible active sites.As a result,HCl-CNU-X exhibits both enhanced photocatalytic tetracycline hydrochloride degradation and higher hydrogen evolution than bulk g-C_(3)N_(4).The boosted photocatalytic performance was ascribed to the formation of the porous structure,which dramatically promotes the separation of charge-carriers and facilitates the electron transfer.This work demonstrates that the acidification of nitrogen-rich precursors combined with a bubble-template can develop a new paradigm of highly porous photocatalysts for environmental remediation and water splitting.展开更多
Resistive switching memories based on ion transport and related electrochemical reactions have been extensively studied for years.To utilize the resistive switching memories for high-performance information storage ap...Resistive switching memories based on ion transport and related electrochemical reactions have been extensively studied for years.To utilize the resistive switching memories for high-performance information storage applications,a thorough understanding of the key information of ion transport process,including the mobile ion species,the ion transport paths,as well as the electrochemical reaction behaviors of these ions should be provided for material and device optimization.Moreover,ion transport is usually accompanied by processes of microstructure modification,phase transition,and energy band structure variation that lead to further modulation of other physical properties,e.g.,magnetism,optical emission/absorbance,etc.,in the resistive switching materials.Therefore,novel resistive switching memories that are controlled through additional means of magnetic or optical stimulus,or demonstrate extra functionalities beyond information storage,can be made possible via well-defined ion transportation in various switching materials and devices.In this contribution,the mechanism of ion transport and related resistive switching phenomena in thin film sandwich structures is discussed first,followed by a glanceat the recent progress in the development of high-performance and multifunctional resistive switching memories.A brief perspective of the ion transport-based resistive switching memories is addressed at the end of this review.展开更多
A novel diselenide-containing crown ether(BC7Se_(2))was fabricated,which can polymerize to form cyclic oligomers through intermolecular dynamic covalent reaction by irradiation of visible light.The size and distributi...A novel diselenide-containing crown ether(BC7Se_(2))was fabricated,which can polymerize to form cyclic oligomers through intermolecular dynamic covalent reaction by irradiation of visible light.The size and distribution of oligomers are related to the monomer concentration.The decomposition reaction of oligomers is controlled by topology and solvents.Furthermore,potassium cation can inhibit the polymerization of BC7Se_(2)and accelerate the decomposition of oligomers.展开更多
文摘Three-dimensional visualization technology converts engineering design drawings and data into graphics or images, realizes virtual reality perception of simulated users in future construction scene, enhances the interaction between project management and technical personnel and engineering construction achievement, and provides intuitive, flexible and strong realistic experience for project management. It can effectively improve the level of project communication, and assist the needs of project construction planning management, training, exhibition, etc. As a tool to help improve project management skills, it has good application effect and prospects.
基金financial support from the National Natural Science Foundation of China (Nos. 21901210,22071196, 22007078)Key R&D Program of Shaanxi Province (No.2021KWZ-18)+4 种基金Aeronautical Science Foundation of China (No. ASFC-2020Z061053001)Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University)(No. klpme2021-05-03)Student Innovation and Entrepreneurship Education Center of the Student Work Department of the Party Committee of NPU(No. 2021-cxcy-012)Fundamental Research Funds for the Central Universitiesand Fellowship from CSC Innovative Team Program(No. CXXM20190099)。
文摘Control of self-assembly is significant to the preparation of supramolecular materials, but the control of hydration, responsiveness, dimension, catalysis of macrocyclic amphiphiles in an atom-economic manner is still a great challenge. The herein presented 527 Da low-molecular-weight macrocyclic amphiphile was fabricated by utilizing the selenium-containing crown ether as a hydrophobic motif together with guanidinium group as the hydrophilic moiety. The resulting benzo[21]crown-7 based macrocyclic amphiphile readily forms a redox-responsive solid nanoparticles in water, which can further interconnect into wrinkled pattern on-surface, as well as exhibits as a nanozyme for catalyzing disulfid bond formation. The present work highlights the great potential of guanidinium-and selenium-containing crown ethers for the control of functional assemblies.
基金National Natural Science Foundation of China(552127803,51931011,51971233,62174165,M-0152,U20A6001,U1909215 and 52105286)External Cooperation Program of Chinese Academy of Sciences(174433KYSB20190038,174433KYSB20200013)+8 种基金K.C.Wong Education Foundation(GJTD-2020-11)the Instrument Developing Project of the Chinese Academy of Sciences(YJKYYQ20200030)Chinese Academy of Sciences Youth Innovation Promotion Association(2018334)“Pioneer”and“Leading Goose”R&D Program of Zhejiang(2022C01032)Zhejiang Provincial Key R&D Program(2021C01183)Natural Science Foundation of Zhejiang Province(LD22E010002)Ningbo Scientific and Technological Innovation 2025 Major Project(2019B10127,2020Z022)Zhejiang Provincial Basic Public Welfare Research Project(LGG20F010006)China Postdoctoral Science Foundation(2021M693249).
文摘Gallium-based liquid metal has gained significant attention in conformal flexible electronics due to its high electrical conductivity,intrinsic deformability,and biocompatibility.However,the fabrication of large-area and highly uniform conformal liquid metal films remains challenging.Interfacial self-assembly has emerged as a promising method,but traditional approaches face difficulties in assembling liquid metal particles.Here,we realized the multi-size universal self-assembly(MUS)for liquid metal particles with various diameters(<500μm).By implementing a z-axis undisturbed interfacial material releasing strategy,the interference of gravitational energy on the stability of floating particles is avoided,enabling the fabrication of ultra-conformable monolayer films with large areas(>100 cm^(2))and high floating yield(50–90%).Moreover,the films can be conformally transferred onto complex surfaces such as human skin,allowing for the fabrication of substrate-free flexible devices.This eliminates interference from traditional substrate mechanical responses,making the liquid metal e-tattoo more user-friendly.
文摘Resistive switching (RS) behaviors have attracted great interest due to their promising potential for the data storage. Among various materials, oxide-based devices appear to be more advantageous considering their handy fabrication and compatibility with CMOS technology, though the underlying mechanism is still controversial due to the diversity of RS behaviors. In this review, we focus on the oxide-based RS memories, in which the working mechanism can be understood basically according to a so-called filament model. The filaments formation/rupture processes, approaches developed to detect and characterize filaments, several effective attempts to improve the performances of RS and the quantum conductance behaviors in oxide-based resistive random access memory (RRAM) devices are addressed, respectively.
基金Supported by Natural Science Foundation of China under grant no.81674087~~
文摘In this paper, a case of premature ovarian failure (POF), accompanied with amenorrhea for 2 years was reported. After 2 months of acupuncture, the patient's menstruation was resumed, and after 11 months of treatment, the patient had a spontaneous pregnancy. It is suggested that acupuncture should be used for the patient with POF as early as possible, and if necessary, hormone replacement therapy is still needed, and it is still expected to obtain spontaneous pregnancy before completely exhausted of ovarian function.
基金the National Science and Technology Major Project(No.2016ZX05040003)Shuaijun Wang thanks the China Scholarship Council Scholarship(No.201806450064)。
文摘Graphitic carbon nitride(g-C_(3)N_(4))as a metal-free candidate of photocatalyst has received worldwide attention because of its great potentials in solar light-induced degradation and hydrogen evolution,yet the industrial application is seriously hindered by the small specific surface area and rapid recombination rate of carriers.Herein,we demonstrate that porous g-C_(3)N_(4)(HCl-CNU-X)can be prepared via the copolymerization of acidified melamine and a green bubble template(urea).Transmission electron microscopy and nitrogen sorption characterization results show that the prepared HCl-CNU-X possesses an in-plane porous structure and large specific surface area,enabling the exposure of more accessible active sites.As a result,HCl-CNU-X exhibits both enhanced photocatalytic tetracycline hydrochloride degradation and higher hydrogen evolution than bulk g-C_(3)N_(4).The boosted photocatalytic performance was ascribed to the formation of the porous structure,which dramatically promotes the separation of charge-carriers and facilitates the electron transfer.This work demonstrates that the acidification of nitrogen-rich precursors combined with a bubble-template can develop a new paradigm of highly porous photocatalysts for environmental remediation and water splitting.
基金supported by the National Basic Research Program of China(2009CB933004,2012CB933004)the National Natural Science Foundation of China(51172250,51303194,61328402,61306152)+1 种基金Zhejiang and Ningbo Natural Science Foundations(2013A610031)Science and Technology Innovative Research Team of Ningbo Municipality(2009B21005,2011B82004)
文摘Resistive switching memories based on ion transport and related electrochemical reactions have been extensively studied for years.To utilize the resistive switching memories for high-performance information storage applications,a thorough understanding of the key information of ion transport process,including the mobile ion species,the ion transport paths,as well as the electrochemical reaction behaviors of these ions should be provided for material and device optimization.Moreover,ion transport is usually accompanied by processes of microstructure modification,phase transition,and energy band structure variation that lead to further modulation of other physical properties,e.g.,magnetism,optical emission/absorbance,etc.,in the resistive switching materials.Therefore,novel resistive switching memories that are controlled through additional means of magnetic or optical stimulus,or demonstrate extra functionalities beyond information storage,can be made possible via well-defined ion transportation in various switching materials and devices.In this contribution,the mechanism of ion transport and related resistive switching phenomena in thin film sandwich structures is discussed first,followed by a glanceat the recent progress in the development of high-performance and multifunctional resistive switching memories.A brief perspective of the ion transport-based resistive switching memories is addressed at the end of this review.
基金financial support from the National Natural Science Foundation of China(Nos.21901210,21901209,22071196,22007078)Natural Science Foundation of Shaanxi Province of China(No.2019JQ-626)+3 种基金Postdoctoral Innovative Talents Supporting Project of China(No.BX20180255)Key R&D Program of Shaanxi Province(Nos.2019KW-031,2019KW-038)Fundamental Research Funds for the Central Universities(Nos.3102019smxy001,3102018zy051,3102018jcc007,3102017OQD045,3102017OQD040,3102017OQD115,3102019ghxm005)State Key Laboratory of Solidification Processing in NPU(No.SKLSP201817)。
文摘A novel diselenide-containing crown ether(BC7Se_(2))was fabricated,which can polymerize to form cyclic oligomers through intermolecular dynamic covalent reaction by irradiation of visible light.The size and distribution of oligomers are related to the monomer concentration.The decomposition reaction of oligomers is controlled by topology and solvents.Furthermore,potassium cation can inhibit the polymerization of BC7Se_(2)and accelerate the decomposition of oligomers.