A facile encapsulation strategy for the preparation of metal layer/metal-organic framework （metal/MOF） hybrid thin films, by alternately growing MOF thin films and sputter-coating metal layers, is reported. The cont...A facile encapsulation strategy for the preparation of metal layer/metal-organic framework （metal/MOF） hybrid thin films, by alternately growing MOF thin films and sputter-coating metal layers, is reported. The controlled species of the MOF thin films and metal layers, as well as the designed thickness of MOF thin films, endow the resulting hybrid thin films with improved functional and design flexibility. Importantly, the metaL/MOF hybrid thin films, with well-defined sandwich structures, exhibit excellent selective catalytic activity, derived from MOFs acting as molecular sieves and the metal layers providing active sites.展开更多
Two electron-deficient azaacenes including di-and tetra-cyanodiazafluorene(DCAF and TCAF)with the advantages of deep lowest unoccupied molecular orbital(LUMO),green-synthesis,low-cost,simply purification method,excell...Two electron-deficient azaacenes including di-and tetra-cyanodiazafluorene(DCAF and TCAF)with the advantages of deep lowest unoccupied molecular orbital(LUMO),green-synthesis,low-cost,simply purification method,excellent yields have been obtained,characterized and used as electron injection materials(EIMs)in three groups of electroluminescence devices.Device B with TCAF as EIM exhibited the best performance including turn-on voltage of 5.0 V,stronger maximum luminance intensity of 31,549 cd/m2,higher luminance efficiency of 62.34 cd/A and larger power efficiency of 21.74 lm/W which are 0.53,6.7,9.3 and 15.3 times than that of device A with DCAF as EIMs,respectively.The enhanced interfacial electron injection ability of TCAF than that of DCAF is supported by its better electron mobility in electron-only device,deeper LUMO(-4.52 eV),and stronger electronic affinity.Best external quantum efficiency of 16.56%was achieved with optimized thicknesses of TCAF as EIM and TPBi as electron transporting layer.As a new comer of acceptor family,TCAF would push forward organic electronics with more fascinating and significant applications.展开更多
基金The project was supported by the Jiangsu Provincial Founds for Distringuished Young Scholars （No. 55135011）, start-up fund at Nanjing Tech University and the National Natural Science Foundation （Nos. 21574065 and 21504043）.
文摘A facile encapsulation strategy for the preparation of metal layer/metal-organic framework （metal/MOF） hybrid thin films, by alternately growing MOF thin films and sputter-coating metal layers, is reported. The controlled species of the MOF thin films and metal layers, as well as the designed thickness of MOF thin films, endow the resulting hybrid thin films with improved functional and design flexibility. Importantly, the metaL/MOF hybrid thin films, with well-defined sandwich structures, exhibit excellent selective catalytic activity, derived from MOFs acting as molecular sieves and the metal layers providing active sites.
基金the National Natural Science Foundation of China(Nos.21975126,51673095,21875104,21875191,21603104)the Natural Science Foundation of Jiangsu Province(Nos.BK20171470,BK20160991,BK20150064,BK20130912)+1 种基金973 Program(No.2015CB932200)Ministry of Education and Synergetic Innovation Center for Organic Electronics and Information Displays for financial support
文摘Two electron-deficient azaacenes including di-and tetra-cyanodiazafluorene(DCAF and TCAF)with the advantages of deep lowest unoccupied molecular orbital(LUMO),green-synthesis,low-cost,simply purification method,excellent yields have been obtained,characterized and used as electron injection materials(EIMs)in three groups of electroluminescence devices.Device B with TCAF as EIM exhibited the best performance including turn-on voltage of 5.0 V,stronger maximum luminance intensity of 31,549 cd/m2,higher luminance efficiency of 62.34 cd/A and larger power efficiency of 21.74 lm/W which are 0.53,6.7,9.3 and 15.3 times than that of device A with DCAF as EIMs,respectively.The enhanced interfacial electron injection ability of TCAF than that of DCAF is supported by its better electron mobility in electron-only device,deeper LUMO(-4.52 eV),and stronger electronic affinity.Best external quantum efficiency of 16.56%was achieved with optimized thicknesses of TCAF as EIM and TPBi as electron transporting layer.As a new comer of acceptor family,TCAF would push forward organic electronics with more fascinating and significant applications.
