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Effect of Chamber Conditions and Substrate Type on PECVD of SiGeSn Films
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作者 Venkat Hariharan jignesh vanjaria +2 位作者 Arul Chakkaravarthi Arjunan Gary S. Tompa Hongbin Yu 《Crystal Structure Theory and Applications》 2021年第3期39-56,共18页
In the past studies have shown that the addition of Ge and Sn into Si lattice to form SiGeSn enhances its carrier mobility and band-gap properties. Conventionally SiGeSn epitaxial films are grown using Ultra-High Vacu... In the past studies have shown that the addition of Ge and Sn into Si lattice to form SiGeSn enhances its carrier mobility and band-gap properties. Conventionally SiGeSn epitaxial films are grown using Ultra-High Vacuum (UHV) conditions with pressures ranging from 10<sup>-8</sup> torr to 10<sup>-10</sup> torr which makes high volume manufacturing very expensive. On the contrary, the use of low-pressure CVD processes (vacuum levels of 10<sup>-2</sup> torr to 10<sup>-4</sup> torr) is economically more viable and yields faster deposition of SiGeSn films. This study outlines the use of a cost-effective Plasma Enhanced Chemical Vapor Deposition (PECVD) reactor to study the impact of substrate temperature and substrate type on the growth and properties of polycrystalline SiGeSn films. The onset of polycrystallinity in the films is attributed to the oxygen-rich PECVD chamber conditions explained using the Volmer-Weber (3D island) mechanism. The properties of the films were characterized using varied techniques to understand the impact of the substrate on film composition, thickness, crystallinity, and strain. 展开更多
关键词 Thin Film Growth Volmer-Weber Mechanism Plasma Enhanced Chemical Vapor Deposition Silicon Photonics Carrier Mobility Band-Gap Engineering Semimetal Alloys
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