Experimental and Modeling Study of the Regular Polygon Angle-spiral Liner in Ball Mills

Load behavior is one of the most critical factors affecting mills＇ energy consumption and grinding efficiency, and is greatly affected by the liner profiles. Generally, as liner profiles vary, the ball mill performances are extremely different. In order to study the performance of the ball mill with regular polygon angle-spiral liners（RPASLs）, experimental and numerical studies on three types of RPASLs, including regular quadrilateral, pentagonal and hexagonal, are carried out. For the fine product of desired size, two critical parameters are analyzed： the energy input to the mill per unit mass of the fine product, E＊, and the rate of production of the fine product, F＊. Results show that the optimal structure of RPASLs is Quadrilateral ASL with an assembled angle of 50°. Under this condition, the specific energy consumption E＊ has the minimum value of 303 J per fine product and the production rate F＊ has the maximum value of 0.323. The production rate F＊ in the experimental result is consistent with the specific collision energy intensity to total collision energy intensity ratio Es/Et in the simulation. The relations between the production rate F＊ and the specific energy consumption E＊ with collision energy intensity Es and Et are obtained. The simulation result reveals the essential reason for the experimental phenomenon and correlates the mill performance parameter to the collision energy between balls, which could guide the practical application for Quadrilateral ASL.

单组元推力器固定床催化分解反应工程基础

自20世纪60年代肼类化学单组元推力器诞生以来,液体单组元推进技术在卫星轨控、火箭姿态调整和应急动力系统中得到了广泛应用。化学单组元推进技术关键是高能液体化学推进剂在颗粒固定床内催化分解反应过程。由于其化学反应过程的复杂性,目前该类推进技术开发不考虑化学反应工程本质,以热能和空气动力学工程理论为基础,通过大量耗时耗力推力器热实验完成。本工作从化学反应工程角度出发,论述了化工热力学、催化反应动力学、单颗粒催化剂内扩散?反应、催化剂纳微孔道内流体?反应以及在固定床宏观多孔介质中和颗粒堆积形成的介观复杂几何结构内流动?传递?反应的耦合理论,且在化学单组元推进系统中推进剂能量设计,催化剂结构和催化分解固定床设计中的应用。本工作给出了单组元推进技术中相关催化反应工程理论基础,有望为新型绿色化学单组元推进技术的开发提供推进剂配方,为催化剂合成以及分解固定床的设计提供理论基础。