Three Eu（III） ternary complexes, Eu（hfa-H）3（Phen）, Eu（hfa-H）3（Bipy） and Eu（hfa-H）3（Bath） （hfa = hexafluoroacetylacetonate, Phen = 1,10-phenanthroline, Bipy = 2,2＇-bipyridine, Bath = bathophenanthroline...Three Eu（III） ternary complexes, Eu（hfa-H）3（Phen）, Eu（hfa-H）3（Bipy） and Eu（hfa-H）3（Bath） （hfa = hexafluoroacetylacetonate, Phen = 1,10-phenanthroline, Bipy = 2,2＇-bipyridine, Bath = bathophenanthroline）, were synthesized. Their luminescent properties were studied by incorporating deuterated Eu（III） complexes in a poly（methylmethacrylate） （PMMA） matrix, and the results indicated that luminescent PMMA including Eu（hfa-D）3（Bath） showed promising results for applications to novel organic Eu（III） devices, such as the high-power laser materials. Additionally, all the three Eu（III） complexes exhibited good thermostabilization.展开更多
文摘Three Eu（III） ternary complexes, Eu（hfa-H）3（Phen）, Eu（hfa-H）3（Bipy） and Eu（hfa-H）3（Bath） （hfa = hexafluoroacetylacetonate, Phen = 1,10-phenanthroline, Bipy = 2,2＇-bipyridine, Bath = bathophenanthroline）, were synthesized. Their luminescent properties were studied by incorporating deuterated Eu（III） complexes in a poly（methylmethacrylate） （PMMA） matrix, and the results indicated that luminescent PMMA including Eu（hfa-D）3（Bath） showed promising results for applications to novel organic Eu（III） devices, such as the high-power laser materials. Additionally, all the three Eu（III） complexes exhibited good thermostabilization.
