Under the irradiation of medium pressure mercury lamp (MPML) the photolysis of 2-methoxycytosine (MAP) in phosphate solution leads to the production of a novel compound C5H8N3O5P. The composition and structure of the ...Under the irradiation of medium pressure mercury lamp (MPML) the photolysis of 2-methoxycytosine (MAP) in phosphate solution leads to the production of a novel compound C5H8N3O5P. The composition and structure of the compound has been identified by elemental analysis. EI-MS, UV, IR, H-1, P-31-NMR.展开更多
Reductive debromination of anhydro-6-(R)-hydroxycthyl-6-(R) 7 by zinc in ammonium acetate gave 9 in 81% yield with high stcreosclectivity of 6-(α):6-(β)= 13: 1
文摘Under the irradiation of medium pressure mercury lamp (MPML) the photolysis of 2-methoxycytosine (MAP) in phosphate solution leads to the production of a novel compound C5H8N3O5P. The composition and structure of the compound has been identified by elemental analysis. EI-MS, UV, IR, H-1, P-31-NMR.
文摘Reductive debromination of anhydro-6-(R)-hydroxycthyl-6-(R) 7 by zinc in ammonium acetate gave 9 in 81% yield with high stcreosclectivity of 6-(α):6-(β)= 13: 1
